• Title/Summary/Keyword: nitrogen management

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A Study on the Prediction of Nitrogen Oxide Emissions in Rotary Kiln Process using Machine Learning (머신러닝 기법을 이용한 로터리 킬른 공정의 질소산화물 배출예측에 관한 연구)

  • Je-Hyeung Yoo;Cheong-Yeul Park;Jae Kwon Bae
    • Journal of Industrial Convergence
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    • v.21 no.7
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    • pp.19-27
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    • 2023
  • As the secondary battery market expands, the process of producing laterite ore using the rotary kiln and electric furnace method is expanding worldwide. As ESG management expands, the management of air pollutants such as nitrogen oxides in exhaust gases is strengthened. The rotary kiln, one of the main facilities of the pyrometallurgy process, is a facility for drying and preliminary reduction of ore, and it generate nitrogen oxides, thus prediction of nitrogen oxide is important. In this study, LSTM for regression prediction and LightGBM for classification prediction were used to predict and then model optimization was performed using AutoML. When applying LSTM, the predicted value after 5 minutes was 0.86, MAE 5.13ppm, and after 40 minutes, the predicted value was 0.38 and MAE 10.84ppm. As a result of applying LightGBM for classification prediction, the test accuracy rose from 0.75 after 5 minutes to 0.61 after 40 minutes, to a level that can be used for actual operation, and as a result of model optimization through AutoML, the accuracy of the prediction after 5 minutes improved from 0.75 to 0.80 and from 0.61 to 0.70. Through this study, nitrogen oxide prediction values can be applied to actual operations to contribute to compliance with air pollutant emission regulations and ESG management.

Regional Application of the OECD Nitrogen Budget Considering Livestock Manure Compost (국내 가축분뇨 자원화 특성을 고려한 OECD 질소수지 산정법의 지역단위 적용 연구)

  • Lim, Do Young;Ryu, Hong-Duck;Chung, Eu Gene;Kim, Yongseok;Lee, Jae Kwan
    • Journal of Korean Society on Water Environment
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    • v.33 no.5
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    • pp.546-555
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    • 2017
  • The Nutrient budget is one of the agricultural-environment indicators of OECD. A nutrient budget measures the surplus as the differential between the inputs and the outputs of within a certain boundary and within a specified period of time (i.e. one year). According to OECD, the annual nitrogen budget for Korea was $245kg\;N\;ha^{-1}$ in 2014, which corresponds to the first position among OECD countries. In Korea in 2014, about 90 % of livestock excreta was composted as solid and liquid manure, which are usually and customarily spread on agricultural land. The objectives of this study are intended to suggest methodology of the regional nitrogen budget as a nitrogen management tool, which considers conversion from raw excreta to composted manures based on the methodology of OECD/Eurostat, and application of the new method in an agricultural region of Korea. As a result, the calculated excess rate of hydrospheric nitrogen surplus was $251kg\;N\;ha^{-1}$ (in the region in 2014), which indicates the presence of potential risks emanating from excessive nitrogen, with regard to both export water and soil environments. The findings also assert that this was shown to be one of the most important elements in the nitrogen budget, which translates to the actual amounts of nitrogen lost during the solid composting process. To better understand the process and the reliability of the method, it is necessary to analyze the sensitivity of the relevant co-efficients used in the method in the near future.

Effect of 16 different (N, P combination) fertilizer treatments on the growth of Liriodendron tulipifera seedlings and soil chemical properties in the Nursery Station

  • Jung Won Park;Woo Bin Youn;Byung Bae Park;Min Seok Cho
    • Korean Journal of Agricultural Science
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    • v.50 no.2
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    • pp.223-234
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    • 2023
  • Appropriate fertilization methods are required according to species to supply necessary nutrients to plants and prevent soil environmental contamination in nurseries. In this study, the effects of nitrogen and phosphorus fertilization on the growth of Liriodendron tulipifera and soil characteristics were investigated. After 16 fertilization treatments (4 levels of nitrogen × 4 levels of phosphorus) were applied to one-year-old L. tulipifera seedlings at the Yongmun Nursery Station of the Korea Forest Service, height, root collar diameter (RCD), biomass, leaf nutrients, and soil characteristics were investigated. The height increased as the amount of nitrogen and phosphorus fertilization increased, and the RCD was the highest in the ×2 treatment. Biomass growth was on average 40.0% higher for the treatment with high nitrogen fertilization compared to the low nitrogen treatment. The seedling quality index was the highest with nitrogen and phosphorus ×2 treatment. Leaf phosphorus and magnesium concentrations decreased when nitrogen fertilization was applied, and leaf potassium concentrations decreased as nitrogen fertilization increased. Soil pH and exchangeable potassium decreased as the amount of phosphorus application increased, and exchangeable magnesium decreased as the amount of nitrogen application increased and increased as the amount of phosphorus application increased. Considering the growth of L. tulipifera seedlings and changes in the soil characteristics at the nursery stage, twice the standard fertilization amount is the appropriate fertilization amount for nursery of the Yongmun Nursery Station. It is expected that this study will contribute to improving nursery soil fertilization management technology for healthy seedling production.

Main-stream Partial Nitritation - Anammox (PN/A) Processes for Energy-efficient Short-cut Nitrogen Removal (주공정에서 아질산화-혐기성 암모늄 산화법에 의한 단축질소제거공정 연구동향)

  • Park, Hongkeun;Rhu, Daehwan
    • Journal of Korean Society on Water Environment
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    • v.34 no.1
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    • pp.96-108
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    • 2018
  • Large efforts have recently been made on research and development of sustainable and energy-efficient short-cut nitrogen removal processes owing to strong attention to the energy neutral/positive wastewater treatment system. Anaerobic ammonium oxidizing bacteria (anammox bacteria) have been highlighted since 1990's due to their unique advantages including 60% less energy consumption, nearly 100% reduction for carbon source requirement, and 80% less sludge production. Side-stream short-cut nitrogen removal using anammox bacteria and partial nitritation anammox (PN/A) has been well established, whereas substantial challenges remain to be addressed mainly due to undesired main-stream conditions for anammox bacteria. These include low temperature, low concentrations of ammonia, nitrite, free ammonia, free nitrous acid or a combination of those. In addition, an anammox side-stream nitrogen management is insufficient to reduce overall energy consumption for energy-neutral or energy positive water resource recovery facility (WRRF) and at the same time to comply with nitrogen discharge regulation. This implies the development of the successful main-stream anammox based technology will accelerate a conversion of current wastewater treatment plants to sustainable water and energy recovery facility. This study discusses the status of the research, key mechanisms & interactions of the protagonists in the main-stream PN/A, and control parameters and major challenges in process development.

Effect of Nitrogen Split Application Methods on Development of Vascular Bundle and Yield Components of Rice Cultivars

  • Lee, Dong-Jin;Chae, Je-Cheon
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.45 no.4
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    • pp.237-240
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    • 2000
  • This experiment was conducted to evaluate the effect of split application of nitrogen(N) on development of vascular bundle(VB) and yield components of rice. Two cultivars were used in this study; IR58, an indica type and Shinunbongbyeim a japonica type. The number and total cross sectional area of the VB in the peduncle and leaf blade were more and bigger in N split application than 100 percent basal fertilizer. Nitrogen split application at necknode differentiation stage increased the number and size of the VB. Nitrogen split application resulted in increased panicle number with application of N before transplanting and at tillering stage; increased spikelets number with N application at necknode differentiation stage; and increased spikelet fertility and 1000 grain weight with N application at necknode differentiation and heading stages. Grain yield increased 7-10% in N split as compared to all basal application. The total cross sectional area of VB in peduncle closely correlated with the number of spikelets per panicle. Nitrogen management can have an impact on spikelet differentiation through more and bigger VB and increase grain yield potential.

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Comparison of Nitrogen Application Methods at the 4th Leaf Stage in Direct-Seeded Rice Field

  • Chun, Nam-Jin;Kang, Yang-Soon;Park, Jeong-Hwa;Yoon, Yong-Hwan;Kim, Chung-Kon
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.46 no.2
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    • pp.84-88
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    • 2001
  • Two methods of nitrogen application at the 4th leaf stage were evaluated in direct-seeding rice cultivation on dry paddy soil: one was the top dressing of nitrogen on dry paddy condition before irrigation (TNDP) for labor saving, and the other was the top dressing of nitrogen on dry paddy with mechanical rotavation of the inter-row space (TNDPIR) for increasing the efficiency of nitrogen. To evaluate these two application methods, leaf chlorophyll contents, growth characteristics and yields were compared with two conventional methods, basal application (BA) and top dressing on flooded paddy condition at the 4th leaf stage (TNFP). The SPAD value of rice in TNDP was similar with that in TNFP throughout the whole growth stage of rice. Also, there were no differences in rice growth and yield between the two methods. However, in TNDPIR, the SPAD value was the highest during tillering stage among the four application methods, and the tiller number, LAI at heading stage and the panicle number were higher than the two conventional methods.

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Nutrient Behavior in an Upland Field of Cabbage Adjacent to the River (하천변 양배추 밭에서의 영양물질의 거동)

  • Song, Chul-Min;Kim, Jin-Soo;Jang, Hoon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.52 no.3
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    • pp.65-71
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    • 2010
  • This study was conducted to investigate the dynamics of nutrients such as total nitrogen (TN), nitrate nitrogen ($NO_3$-N) total phosphorous (TP), and phosphate phosphorous ($PO_4$-P) in outflow from a cabbage farmland in a mixed land-use watershed. The TN concentrations in groundwater showed twice peaks in late July 2006 and late March 2007 (3.8, 4.7 mg/L, respectively), when it rained shortly after fertilizer application, indicating that nitrogen leaching is greatly influenced by fertilization and rainfall. The mean concentrations of TN and $NO_3$-N in surface water were not significantly higher than those in groundwater, while the mean concentrations of TP and $PO_4$-P in surface water were significantly (p < 0.05) were higher than those in groundwater. The TN concentrations in groundwater were generally higher than those in surface water during fertilization and early growing season due to the effect of fertilization, but vice versa in the other periods. In contrast, the TP concentrations in groundwater were always lower than those in surface water due to the sorption of particulate phosphorous by soil. The ratio of TN load in baseflow to that in total TN load (39 %) was much greater than the TP ratio (7 %), suggesting that baseflow contribute to nitrogen export. Therefore, proper fertilization management should be taken to reduce nitrogen load through baseflow.

Behaviour of $NO_3-N$ in Soil and Groundwater Quality (토양(土壤)중 질산태질소(窒酸態窒素)의 행동(行動)과 지하수질(地下水質))

  • Yun, Sun-Gang;Yoo, Sun-Ho
    • Korean Journal of Environmental Agriculture
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    • v.12 no.3
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    • pp.281-297
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    • 1993
  • Nitrogen is an element required to meet optimal plant growth. However, when it was applied (as chemical fertilizer or animal waste) more than the demand of plant and managed it unreasonably can be accumulated in subsoil and leached from soil system. Nitrogen also can be act as an pollutant to soil and water through water contamination if its concentration exceed the critical level. The concentration and downward movement of nitrate in soil is influenced by cultural practices and soil properties. High level of nitrate nitrogen in drinking water is harzadrous for animal and human health, especially for infants and the restoration of the quality of groundwater is impossible by now. Therefore it is the only way to prevent from leaching of nitrate nitrogen to keep the quality of groundwater as vital water resource. The aims of the presentation of this review paper are to understand the relationship between agricultural practices and the concentration of nitrate nitrogen in groundwater and to suggest further informations for the rational management methods to reduce the leaching of nitrate nitrogen in soil.

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Comparison of the Total Nitrogen Determination Methods (총질소 분석방법의 비교)

  • Joung, Kwang-Wook;Yoon, Chun-Gyeong;Ham, Jong-Hwa
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2001.10a
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    • pp.421-425
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    • 2001
  • Among the many parameters describing water quality, total nitrogen content(TN) is regarded as important one in relation to water quality management of the waterbodies for its role in eutrophication process. This study evaluated for accuracy, convenience and promptness of nitrogen analysis methods : (1)UV spectrophotometric method, (2)summation method, (3)cadmium reduction method. And, the detection limit of each method was calculated using EPA method. The UV spectrophotometric method after oxidation appears to be more convenient and accurate in determination of the TN contents than the summation method and cadmium reduction method. The summation method is necessary to separate determinations of the organic nitrogen, ammonia, nitrite, and nitrate. And, because summation method has many other methods for each contents, it can be detected for wide range of concentration.

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Study on characteristic of mycelial culture in ear mushroom (목이의 균사생육 특성에 관한 연구)

  • Yu, Young-Jin;Choi, Kyu-Hwan;Jeong, Jong-Seong;Lee, Gi-Kwon;Choi, So-Ra
    • Journal of Mushroom
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    • v.11 no.1
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    • pp.15-20
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    • 2013
  • This study was performed to obtain the scientific data an artificial culture of ear mushroom(Auricularia auricula). Liquid cultural of Auricularia auricula. mycelium was characterized with respect to temperature, pH, compositions of inorganic, carbon and nitrogen. The its optimum temperature and media pH were at $25^{\circ}C$ and pH 5.0~6.0 on the mycelial growth, respectively. The optimum inorganic compositions and concentration for mycelial growth were $MgSO_4$ 0.05%(w/v) and $KH_2PO_4$ 0.1%(w/v), respectively. The optimum carbon sources and nitrogen sources were black-sugar 2%(w/v) and soybean powder at 0.3~0.5%(w/v) with7 days optimum culture time.