• Title/Summary/Keyword: nitrogen compound

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Evidence for Nitrogen-Bonded Acrylonitrile to Iridium (Ⅰ) in Acrylonitrilecarbonylbis(triphenylphosphine)iridium (Ⅰ) perchlorate

  • Park, Soon-Heum;Park, Hwa-Kun;Chin, Chong-Shik
    • Bulletin of the Korean Chemical Society
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    • v.5 no.4
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    • pp.167-169
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    • 1984
  • Analyses of $_1$H-NMR, infrared and electronic spectral data for $[Ir(CH_2 = CHCN)(CO)(P(C_6H_5)_3)_2]ClO_4 (1)$prepared by the reaction of $Ir(OClO_3)(CO)(P(C_6H_5)_3)_2$ with $CH_2 = CHCN$, agree with the suggestion that 1 is a mixture of the nitrogen-bonded acrylonitrile complex, $[(CO)(P(C_6H_5)_3)_2Ir-NCCH = CH_2]ClO_4$ and other compound which may be the C = C ${\Pi}$ -system-bonded acrylonitrile complex, "[(CO)(P(C6H5)3)2Ir-CHCN = CH2]ClO4.

Effects of pH on the growth, total nitrogen, total phosphorus and organic compound removal in heterotrophic culture of Chlorella sorokiniana applied wastewater treatment (pH와 탄소원이 Chlorella sorokiniana의 heterotrophic 배양 및 하폐수고도처리능에 미치는 영향)

  • Park, Jeong-Eun;Cho, Yong-Beom;Zhang, Shan;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.6
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    • pp.703-709
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    • 2013
  • Among many microalgae cultivation types, heterotrophic culture with low cost carbon sources and energy saving culture method is crucial. A result of estimating the effects of pH on wastewater treatment using heterotrophic growing microalgae Chlorella sorokiniana shows that there was no difference in microalgae growth amount and nitrogen, phosphorus removal rate by wide range of pH(5 ~ 9). From pH 5 to 9, total nitrogen, phosphorous and glucose removal rates were 10.5 mg-N/L/d, 2 mg-P/L/d, 800 ~ 1000 mg/L respectively. This study reveals that C. sorokiniana cannot metabolite glycerol heterotrophically, however, glucose and acetate were proper carbon sources for growth and T-N, T-P and TOC removal. This research highlights the potential of heterotrophic microalgal growth with wastewater treatment plant with wide range of pH and carbon sources.

A Study of Benzene Desorption Characteristics Using Steam on Activated Carbon (벤젠이 흡착된 활성탄의 수증기에 의한 탈착특성 연구)

  • Kwon, Jun Ho;Min, Byong Hoon;Suh, Sung-Sup
    • Clean Technology
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    • v.12 no.4
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    • pp.217-223
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    • 2006
  • The operating variables of a desorption step were experimentally investigated tor the cycle of the process made up of benzene adsorption, steam desorption, and drying step. The effect of adsorbent regeneration depending on existence and nonexistence of drying step was studied by breakthrough curves obtained in the adsorption step of the second cycle. The duration of drying step was determined by the experimental results. In case that the amount of nitrogen gas was fixed, the regeneration efficiency increased with the amount of steam. However, the effect of steam decreased as the amount of nitrogen increased. Therefore, it would be possible to predict the optimum amount of steam comparing the amount of nitrogen gas with amount of steam in economic view.

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A Study on Nitrification in tim Main Stream of the Naktong River (낙동강 본류에 대한 질화작용의 조사연구)

  • 김형섭;이홍근
    • Journal of Environmental Health Sciences
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    • v.9 no.1
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    • pp.1-13
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    • 1983
  • This study was carried out to investigate nitrification in the main stream of the Naktong river for two times, 12-13 August and 23-26 September 1982. The results of this study were as follows : 1. The increase of nitrogen concentration was due to inflow of Geumho river, which was polluted by the municipal and industrial wastewater of Daegu city. 2. The rate constant of ammonia calculated for three reaches was high according to the stream flow and was eminently low in the reach from Goroung to Gangjung. (0.068-0.116 $day^{-1}$). This phenomena might be attributed to the sublethal or even lethal effect upon aquatic life by relatively low DO concentration and high heavy metal concentration. 3. DO consumption rate by nitrification was highest for the reach from Goroung to Daeam where was affected by Geumho river. (56.7-147.8%). This phenomena might be attributed to low DO concentration and high nitrogen concentration. Especially, the less stream flow was, the higher DO consumption was. And so, nitrification in the station where is low DO concentration, especially under the low flow condition, might cause more serious water quality management problem. Therefore, for the purpose of effective conservation of water quality in the Naktong river, it was suggested that We have more concern about the nitrogen compound, and more study on the nitrification phenomena.

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전기기기절연물중의 void pulse와 그 검출에 관한 연구

  • 성영권
    • 전기의세계
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    • v.16 no.3
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    • pp.21-27
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    • 1967
  • We meet with the fact that a majority of electric machinery have been insulated to the state of solids & liquids or solids & gases, that is, with compound dielectrics. And also we can find voids caused by undesirbble structure, long-used material and so on. When it is discharged in a void or in the parts of gases of insulating material, the insulation of the machinery is gradually and finally destroyed through the effect of ozone, nitrogen-oxide, electronic pulses and so on. So we maybe conculded that it is necessary and important to detected void pulse and void corona in order to prevent sudden break down of electric machinery.

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Advances and Problems of Embryo Transfer in Swine (돼지 수정란이식의 현황과 문제점)

  • 박창식
    • Journal of Embryo Transfer
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    • v.5 no.2
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    • pp.11-22
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    • 1990
  • Remarkable progress has recently been made in embryo transfer technology, resulting in the birth of IVF and nuclear transfer offsprings in swine. However, further progress of the technology to (I) make a safe, effective and economic estrual-cycle synchronization compound, (2) regulate each step of sperm capacitation (3) induce monospermic fertilization, (4) in vitro grow and mature oocytes, (5) fertilize the oocytes efficently, (6) culture the oocytes to the blastocyst stage in defined media, (7) produce multiply copies of embryos with superior genetic merit, (8) preselect the sex of these superior offsprings, and (9) preserve embryos by freezing and storage in liquid nitrogen is required before this promising technology is applied routinely to swine for practical use.

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The Effects of Fertilization Level on the Growth and Oil Quality in Sesame (Sesamum indicum L.) (참깨의 생육 및 함유율에 미치는 시비량의 영향)

  • 서관석;조재성;최창열
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.31 no.1
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    • pp.24-29
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    • 1986
  • Experiments were conducted to know the inorganic compound absorption of leaf, and the organic component, oil content, fatty acid composition of seeds by different fertilizer levels and growth stage of Pungn-yeonggage. Ripening rate and seed yield were highest under the standard of nitrogen fertilizer level. Nitrogen and potassium amount of leaves were highest at 20 days after seedlings, but there was no difference in phosphate between growth stages. Absorptions of nitrogen and potassium were increased by applying double amount of nitrogen fertilizer. Oleic fatty acid content was found highest under the double amount of nitrogen, phosphate and potassium fertilizer level, and linoleic fatty acid content was increased with double amount of phosphate fertilizer level.

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Development of Slow-Release Compound Fertilizer Used Urea-Resin for Upland Crop I. Manufacture of Slow-Release Compound Fertilizer (요소수지(尿素樹脂)를 이용(利用)한 전작용(田作用) 완효성(緩效性) 복비(複肥) 개발(開發) I. 제조시험(製造試驗))

  • Seong, Ki-Seog;Kim, Bok-Jin;Shin, Jae-Sung
    • Korean Journal of Soil Science and Fertilizer
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    • v.23 no.3
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    • pp.193-198
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    • 1990
  • In order to develop the slow-release compound fertilizer fur upland crops, trial products were made with ammonium sulfate, diammonium phosphate, and potassium chloride with filler of calcium sulfate, and hinder of additional material of urea resin Nine trial slow-release compound fertilizers were manufactured by varying urea/formaldehyde mole ratios(U/F mole ratio : 0.5, 1.0, and 1.5 ) and the proportions of urea resin (3.3. 6.7. and 10%) and the proportions of urea resin (3.3. 6.7 and 10%). The aimed percentage of $N-P_2O_5-K_2O$ in the trial product was 12.5-10.0-14.0%, which was appropriate for Chinese cabbage. The N dissolution of the trial products in water was slower with lower U/F ratio and in creased to the proportion of urea resin. The dissolved nitrogen in water after 24hrs ranged from 69 to 83 percent of total nitrogen in the trial products.

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Behaviors of Pollutants and Microorganisms in an Anaerobic Digestion of Propionate Containing High Ammonia Nitrogen Level (고농도 암모니아성 질소를 함유한 프로피온산의 혐기성 분해시 오염물질 및 미생물 거동)

  • Lee, Chae-Young;Kim, Dae-Sung;Ahn, Won-Sik;Shin, Hang-Sik
    • Journal of the Korea Organic Resources Recycling Association
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    • v.14 no.3
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    • pp.126-137
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    • 2006
  • Behaviors of simple organic compound and granular sludge in an upflow anaerobic sludge blanket (UASB) reactor treating propionate at high ammonia nitrogen levels were investigated for 12 months. The UASB reactor achieved about 80% removal of chemical oxygen demand (COD) at ammonia nitrogen concentration up to 6000 mg-N/L. At higher concentration of ammonia nitrogen, the propionate in the effluent increased whereas the acetate was very low. At ammonia nitrogen concentration of 8000 mg-N/L, the volatile suspended solids (VSS) increased sharply due probably to the decrease of the content of extracellular polymer (ECP) although methane production was very low. The specific methanogenic activity (SMA) using formate, acetate, and propionate as substrate to granules decreased as ammonia nitrogen concentration increased. The ammonia nitrogen concentration $I^{50}$, causing 50% inhibition of SMA were 2666, 4778 and 5572 mg-N/L, respectively. The kinetic coefficients of ammonia inhibition using formate, acetate, and propionate as substrate were 3.279, 0.999 and 0.609, respectively. The SMA using formate was severely affected by ammonia nitrogen than those using acetate and propionate. This result indicated that the hydrogenotrophic methanogens was most affected by ammonia nitrogen. Granules were mainly composed of microcolonies of methanothrix-like bacteria resembling bamboo-shape, and several other microcolonies including propionate degrader with juxtapositioned syntrophic associations between the hydrogen-producing acetogens and hydrogen-consuming methanogens.

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