• Title/Summary/Keyword: nitrogen ($N_2$)

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A Study on Nitrogen and Phosphorus Concentration in Chung Ju Intake Reservoir (淸州取水源의 窒素 및 燐濃度에 관한 調査硏究)

  • Lee, Yeoung Shin;Lee, Hong Keun
    • Journal of Environmental Health Sciences
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    • v.12 no.2
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    • pp.27-37
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    • 1986
  • This study was carried out to investigate inflow stream of Chungju intake reservoir and in catchment area, run-off loading amount, distribution of Nitrogen and phosphorus, N/P ratio, correlationship between T-N and chlorophyll a, correlationship between T-P and chlorophyll a, and study of trophic state. Field survey was carried out from June to August, 1985, for the purpose of finding out the nitrogen and phosphorus concentration in Chungju intake reservoir.

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Effects of Nitrogen Defect on Magnetism of Cu-doped InN: First-principles Calculations

  • Kang, Byung-Sub;Chae, Kwang-Pyo;Lee, Haeng-Ki
    • Journal of Magnetics
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    • v.18 no.2
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    • pp.81-85
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    • 2013
  • We investigate the electronic and magnetic properties in Cu-doped InN with the N vacancy ($V_N$) from first principles calculations. There is the long-range ferromagnetic order between two Cu atoms, attributed to the hole-mediated double exchange through the strong p-d interaction between the Cu atom and neighboring N atom. The system of $V_N$ defect in Cu-doped InN has the lowest formation energy. Due to the hybridization between the Cu-3d and $V_N$ states, the spin-polarization on the Cu atoms in the InN lattice is reduced by $V_N$ defect. So, it shows a weak ferromagnetic behavior.

Synthesis and $^1$H-nmr of N-Arylated Nitrogen-Containing Aromatic Heterocycles

  • Koh Park, Kwang-Hee;Lee, Jae-Bong;Han, Du-Hee
    • Bulletin of the Korean Chemical Society
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    • v.6 no.3
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    • pp.141-144
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    • 1985
  • N-Arylation reaction of nitrogen-containing heterocycles such as pyridine, nicotinamide and 4,4'-bipyridine was studied. We prepared N-2,4-dinitrophenyl derivatives initially by reacting the above heterocycles with 2,4-dinitrochlorobenzene in ethanol, and then treated the N-2,4-dinitrophenylated heterocycles with various aniline derivatives, $XC_6H_4NH_2$(X = -H, p-$CH_3$, p-$C_2H_5$, p-Cl, p-CN, p-OH, p-$OCH_3$, o-Cl, m-$CH_3$) to yield the corresponding N-arylated compounds in fairly good yields. $H^1$-nmr patterns and peak assignments of the N-arylated products were described.

Nitrogen Adsorption Characteristics of Chemical-treated and Metal Ion-exchanged Natural Zeolite (화학처리 및 금속이온 교환된 천연 제올라이트의 질소 흡착특성)

  • Lee, Jae-Young;Shim, Mi-Ja;Kim, Sang-Wook
    • Applied Chemistry for Engineering
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    • v.5 no.6
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    • pp.1024-1029
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    • 1994
  • The characteristics of the nitrogen adsorption with natural zeolite produced in Kampo area according to the chemical treatment by HCl and/or NaOH or the exchanging metal ion were investigated in the pressure range of 100~760torr at $25^{\circ}C$. The amount of nitrogen adsorption was followed at increment in the order of NaOH treatment>nontreatment>HCl treatment. Adsorption amount on natural zeolite treated with 0.5N-HCl/NaOH was improved about 200%, whereas that on natural zeolite treated with 0.5N-NaOH/HCl was decreased. When metal ion of natural zeolite was exchanged with $Na^+$, $K^+$ and $Cs^+$, adsorption amount of nitrogen was decreased as the size of cation was increased. But metal ion of natural zeolite was exchanged with $Mg^{2+}$, $Ca^{2+}$ and $Ba^{2+}$, the amount of nitrogen adsorption was increased.

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Effect of Nitrogen Fertilization on Oxalate Content in Rhodesgrass, Guineagrass and Sudangrass

  • Rahman, M.M.;Yamamoto, M.;Niimi, M.;Kawamura, O.
    • Asian-Australasian Journal of Animal Sciences
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    • v.21 no.2
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    • pp.214-219
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    • 2008
  • An experiment was conducted to evaluate the effects of nitrogen (N) level on the dry matter (DM) yield, N concentration and oxalate content of some tropical grasses, namely Rhodesgrass (Chloris gayana), Guineagrass (Panicum maximum) and Sudangrass (Sorghum vulgare). Three levels of N as urea were applied (Standard- 260, $Standard{\times}2$- 540 and$Standard{\times}4$- 1,060 kg N/ha for Rhodesgrass; Standard- 380, $Standard{\times}2$- 770 and $Standard{\times}4$- 1,570 kg N/ha for Guineagrass and Sudangrass) in a completely randomized design and grasses were harvested twice at approximately two-month intervals. Dry matter yield tended to be higher with increased rate of N fertilizer in all species, while further additional N ($Standard{\times}2$ or $Standard{\times}4$) did not significantly (p>0.05) further increase DM yield, when compared with the Standard level of N fertilizer application. There was also a trend towards higher N concentration in plants as N fertilization increased in all species and it was increased significantly in Rhodesgrass and Sudangrass (p<0.05 or p<0.01, respectively). Further additional N ($Standard{\times}2$ or $Standard{\times}4$) application showed no significant (p>0.05) differences on oxalate content in plant tissue within species, when compared with the Standard level of N. The Rhodesgrass contained 0.11, 0.13 and 0.15% soluble oxalate and 0.23, 0.25 and 0.27% total oxalate with Standard, $Standard{\times}2$ and $Standard{\times}4$ level of N application, respectively. The Guineagrass contained 0.54, 0.50 and 0.42% soluble oxalate and 1.60, 1.56 and 1.45% total oxalate with Standard, $Standard{\times}2$ and $Standard{\times}4$ level of N application, respectively. The Sudangrass contained 0.06, 0.15 and 0.12% soluble oxalate and 0.22, 0.22 and 0.21% total oxalate with Standard, $Standard{\times}2$ and $Standard{\times}4$ level of N application, respectively The results from this study suggest that these grasses do not use further addition of N fertilizer ($Standard{\times}2$ or $Standard{\times}4$) to form high content of oxalate salts, when compared with the Standard level of N. In addition, the levels of oxalate present with these grasses are quite low as far as toxicity to animals is concerned.

Study for Biological Denitrification of High-Strength Nitrate and Nitrite Industrial Wastewater (고농도 질산 및 아질산성 질소 함유 폐수의 생물학적 탈질에 관한 연구)

  • Lee, Byong Hee
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.4
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    • pp.446-454
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    • 2005
  • An economic treatment method to remove oxidized nitrogen from wastewater is biological denitrification with organic matters. Several organics can be used, however, methanol is commonly used. When methanol is provided, M:N (Methanol to Nitrogen) ratio is used to define methanol demand for denitrification. In this study, two artificial wastewaters were provided to a biological system to evaluate denitrification performance. Differences of influent total CODcr from effluent soluble CODcr were converted to methanol equivalent and oxidized nitrogen difference between influent and effluent were converted to nitrate equivalent to define M:N ratios. Modes I, II, III, I-1 and IV showed 5.1, 2.7, 3.3, 2.3 and 2.6 of M:N ratios, respectively. Since denitrifying microorganisms had to build a new metabolic system for methanol and influent organics, initial operation mode, Mode I, required more methanol and this resulted in high M:N ratios compared with later operation mode, Mode I-1. Salt in influent did not show inhibitory effects on denitrfication, although this was believed to increase effluent SS and soluble CODcr concentrations in Mode III, I-1 and IV, respectively. The concentrations of effluent soluble $COD_{Mn}$ did not changed much with influent salt.

Growth of Rice Plant and Chemical Properties of Soil as Affected by Nitrogen Fertilization Level in Milk Vetch(Astragalus sinicus L.) Cultivation in Paddy Field

  • Lee, Yeen;Shin, Hae-Ryong;Kim, Suk-Wean;Kwon, Oh-Do;Park, Heung-Gyu;Kim, Yong-Jae
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.44 no.1
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    • pp.1-3
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    • 1999
  • This study was carried out to determine the effects on rice growth, yields and soil improvement under the different nitrogen levels in machine-transplanted rice after plowing at the fruiting stage of milk vetch. The fresh weight of milk vetch at plowing time was 20.95 ton/ha. In dry weight, T-N and C/N were 1.58%, 21.8%, respectively. Organic matter, total nitrogen and exchangeable calcium of soil after the experiment in the plot of milk vetch were higher than those before the experiment. Leaf area and dry weight of rice plants at heading date increased as nitrogen level increased. The number of panicle and spikelets per $\textrm{m}^2$were not different except for the 110 kg/ha nitrogen level plot with milk vetch. Brown rice yield ranged from 5.45 to 6.08 ton/ha, in creasing with increased nitrogen level. So the yield increased by 1% at 77 kg/ha nitrogen level, 7% at 110 kg/ha nitrogen level plot with milk vetch compared with conventional level (rice straw 5.4 ton/ha and nitrogen 110 kg/ha).

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A Study on the Removal of Nitrogen and Phosphorus of Municipal Wastewater with Biological Coated Media (미생물 코팅 담체를 이용한 하수의 질소$\cdot$인 제거에 관한 연구)

  • Kim Young-Gyu;Cho Il-Hyoung
    • Journal of Environmental Health Sciences
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    • v.32 no.1 s.88
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    • pp.27-35
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    • 2006
  • This study was carried out to investigate the removal of nitrogen and phosphorus in municipal sewage depending on existence of biological coated media in BCM reactor. The reactor with biological coated media is the process combining $A_2/O$ process. The removal efficiencies for $COD_{Mn},\; BOD_5,\;SS$, T-N and T-P were $78\%,\;90.5\%,\;92.3\%,\;61.9\%,\;60.2\%$, respectively. The specific nitrification rate$(mgNO_3-N/gMLSS{\cdot}d)$ of Contact aeration basin was 52.2 and the specific denitrification rate$(mgNO_3N/gMLSS{\cdot}d)$ in anoxic basin was 95.1. Also, phosphorus release$(mgPO_4-P/gMLSS{\cdot}d)$ in Anaerobic basin was 71.8 and Phosphorus uptake$(mgPO_4-P/gMLSS{\cdot}d)$ in contact aeration was 27.1.

Automatic Addition Control of the External Carbon Source by the Measurement of ORP in Biological Nitrogen Removal Process (생물학적 질소 제거공정에서 ORP 측정을 통한 외부탄소원의 자동 주입 제어)

  • Shin, Choon-Hwan
    • Journal of Environmental Science International
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    • v.21 no.3
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    • pp.383-390
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    • 2012
  • For the cost-effective biological nitrogen removal (BNR) process whose characteristics of influent have low COD/N ratios, the automatic control system for the addition of external carbon based on oxidation-reduction potential (ORP) data in an anoxic reactor has been developed. In this study, it was carried out with a pilot-scale Bardenpho process which was consisted of anoxic 1, aerobic 1, aerobic 2, anoxic 2, aerobic 3 tank and clarifier. Firstly, the correlation coefficient ($R^2$) of the dosage of external carbon source and ORP value was about 0.97. Consequently, the automatic control system using ORP showed that the dosage of external carbon source was decreased by about 20% compared with a stable dosage of 75 mg/L based on the COD/N ratio of the anoxic influent.

Effect of Annealing on Carbon Nitride Films Prepared by High Voltage Discharge Plasma (고전압 방전 플라즈마에 의해 합성한 질화탄소 박막의 열처리 효과)

  • 김종일
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.5
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    • pp.455-459
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    • 2002
  • I have investigated the effects of annealing on a polymeric $\alpha-C_3N_{4.2}$ at high pressure and temperature in the presence of seeds of crystalline carbon nitride films prepared by a high voltage discharge plasma. The samples were evaluated by x-ray photoelectron spectroscopy (XPS), infrared spectroscopy, Auger electron spectroscopy and x-ray diffraction(XRD). Notably, XPS studies of the film composition before and after annealing demonstrate that the nitrogen composition in $\alpha-C_3N_{4.2}$ material initially containing more than 58% nitrogen decreases during the annealing process and reaches a common, stable composition of ~43%. XPS analysis also shows that the nitrogen composition in the annealed films without polymeric $\alpha-C_3N_{4.2}$ was reduced from 35% to 17%. Furthermore the concentration of the sp$^3$bonded phase increased with the increment of the annealing temperature.