• Title/Summary/Keyword: nitric acid

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Effect of Sacchromyces cerevisiae-Fermented Artemisiae Argi Folium on Nitric oxide Production of Macrophage Treated with Toxicants

  • Park, Wan-Su
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.23 no.4
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    • pp.883-887
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    • 2009
  • The effects of Sacchromyces cerevisiae-Fermented Artemisiae Argi Folium Water extract (AFS) on Nitric oxide production from mouse macrophage Raw 264.7 cells treated with EtOH, gallic acid, Nicotine, Acetaminophen, and Acetaldehyde were investigated through this study. AFS (0, 10, 50, 100, 200, 400 ug/mL) was simultaneously treated with EtOH (100 uM), gallic acid (100 uM), Nicotine (1 mM), Acetaminophen (2 mM), and Acetaldehyde (200 uM). And Nitric oxide production from Raw 264.7 cells was measured by Griess reagent method. AFS restorated the cellular production of Nitric oxide reduced by EtOH, gallic acid, Nicotine, and Acetaminophen in Raw 264.7 cells. AFS could be supposed to have the immuno-modulating activity concerned with macrophage's production of Nitric oxide.

A study on the Separation of Acetic Acid, Nitric Acid and Hydrofluoric Acid from Waste Etching Solution of Si Wafer Manufacturing Process (Silicon wafer 에칭공정시 발생(發生)되는 폐(廢)에칭액 으로부터 초산(醋酸), 질산(窒酸) 및 불산(弗酸)의 분리.회수(分離.回收)에 관한 연구(硏究))

  • Kim, Jun-Young;Lee, Hyang-Sook;Shin, Chang-Hoon;Kim, Ju-Yup;Kim, Hyun-Sang;Ahn, Jae-Woo
    • Resources Recycling
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    • v.16 no.1 s.75
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    • pp.59-67
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    • 2007
  • Recovery of acids from the waste etching solution of containing acetic, nitric and hydrofluoric acid discharged from silicon wafer manufacturing process has been attempted by using solvent extraction method. EHA(2-Ethylhexlalcohol) for acetic acid and TBP(Tri-butly Phosphate) for nitric and hydrofluoric acid as a extraction agent was used to the experiment to obtain the process design data in separation procedure. From the experimental data and McCabe-Thiele diagram analysis, we obtained the optimum conditions of phase ratio(O/A) and stages to separate each acid sequently from the mixed acids. The recovery yield was obtained above 90% for acetic acid from the acid mixtures, 90% for nitric acid from acetic acid extraction raffinate and then above 67% for hydrofluoric acid from final extraction raffinate.

Isolation of the Constituent Inhibiting Nitric Oxide formation from Lycopus lucidus in LPS-induced Macrophage Cells (LPS로 유도한 대식세포에서 Nitric Oxide 생성을 저해하는 쉽싸리 성분의 분리)

  • Park, Hee-Juhn
    • Korean Journal of Plant Resources
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    • v.32 no.4
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    • pp.264-269
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    • 2019
  • This research was performed to identify the anti-inflammatory constituent from the herb of Lycorus lucidus (Lamiaceae). The MeOH extract of this plant material and its two fractions, the lipophilic- ($CHCl_3$ fraction) and the hydrophilic fraction (BuOH fraction), were prepared to test anti-inflammatory activity. For this purpose, the inhibition rate on inducible nitric oxide synthase (iNOS) activity was assessed by determining nitric oxide (NO) formation in lipopolysaccharide (LPS)-induced macrophage 264.7 cells. The $CHCl_3$ fraction that greatly inhibited nitric NO formation was chromatographed to lead the isolation of ursolic acid. Since ursolic acid inhibited NO formation dose dependently in this study, this compound was considered as one of the active constituent responsible for anti-inflammation. However, the activity of rosmarinic acid isolated from the BuOH fraction was weak.

Effect of Pre-treatments on the Content of Heavy Metals in Packaging Paper

  • Jo, Byoung-Muk;Jeong, Myung-Joon
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.465-469
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    • 2006
  • Pre-treatment methods to determine various heavy metal contents in packaging papers were investigated by ICP-ES (Inductively Coupled Plasma Emission Spectrometry) analysis. Pre-treatment methods utilized in this study include dry ashing and decomposition methods ($HNO_{3-}HClO_{4-}HF,\;HNO_{3},\;and\;H_{2}SO_{4-}HNO_{3}$). They were compared with the conventional extraction (water) and migration (3% acetic acid) methods. The five representative heavy metals (Cd, As, Pb, Cr and Hg) were analyzed. For Cd, Hg, and As, the results were below detection limit of the instrument. In case of Cr and Pb, the migration test is considered to be a better method compared to the extraction test, but all pretreated methods showed much higher detection efficiency than the extraction or migration test. However, the detection ratio between the migration test and decomposition methods was different. Among all decomposition methods, the nitric acid - perchloric acid - hydrofluoric acid treatment brought a slightly higher detection value than others, but there was no significant difference among them except sulfuric acid - nitric acid method. Concerning Pb, the sulfuric acid - nitric acid method showed a low detection efficiency compared to other decomposition methods. The sulfuric acid - nitric acid method is, thus, not considered to be a suitable analysis method for Pb in packaging papers.

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Effect of Simulated Acid Rain on the Growth and Nitrogen fixation of melilotus suaveolens (산성비가 전동싸리의 생장과 질소 고정 활성에 미치는 영향)

  • 송승달;서봉보;박재홍;박태규;정화숙;송종석;노광수;김인선
    • The Korean Journal of Ecology
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    • v.21 no.1
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    • pp.65-72
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    • 1998
  • Various effects of simulated acid rain by $HNO_3$ and $H_2SO_4$ with pH 3.2, 4.2 and 5.6 were investigated in Melilotus suaveolens Ledeb, a biennial legume dominating the disturbed and poor soil vegetations. The nitric acid treatment of pH 3.2 resulted in 121% increase of the plant height compared to that of pH 5.6 during early growth, although 17% decrease was detected with the sulfuric acids. During 14 days of treatment, leaf biomass and chlorophyll content increased 168% and 133% with pH 3.2 nitric acid rain but decreased 20% and 38%, respectively, with sulfuric acid rain. Nitrogen content in various organs was also determined after 42 days of nitric acid treatment. It increased 480% and 387% by pH 3.2 and 4.2 in leaves, 212% and 214% in stems and 247% and 249% in roots. However, the same treatment with the sulfuric acid showed a considerable reduction in this content, indicating that the nitric acid was a nitrogen source. Nodule formation assayed revealed 15% decrease with pH 3.2 in contrast to 157% increase in pH 4.2, further suggesting an enhancement effect by the additional nitrogen source. Contrary to this, the nodule formation was reduced up to 43-71% by sulfuric acid rains. Specific nitrogen fixation activities of nodules estimated at pH 3.2, 4.2 and 5.6 nitric acid rain were 36.7, 42.8 and 47.3 ${\mu}mol\;C_2H_4{\cdot}g^{-1}\;fw\;nodule{\cdot}h^{-1}$, while those of sulfuric acid rain exhibited 1 nmol $C_2H_4{\cdot}plant^{-1}{\cdot}h^{-1}$ with pH 3.2, 177 with pH 4.2 and 179 with pH 5.6, yet it increased 2, 115 and 286 respectively corresponding to the three sulfuric acid concentrations. Further implications of the simulated acied rain were also discussed in the study.

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A Study on the Recovery of Phosphoric acid from Waste acid containing Acetic acid, Nitric acid and phosphoric acid (초산(醋酸), 질산(窒酸), 인산(燐酸)을 함유한 삼원계(三元系) 폐혼산(廢混酸)으로부터 인산(燐酸) 회수(回收)에 관한 기초 연구(硏究))

  • Lee, Hyang-Sook;Lee, Chang-Hoon;Shin, June-Young;Kim, Ju-Yup;Ahn, Jae-Woo
    • Resources Recycling
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    • v.14 no.5 s.67
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    • pp.18-23
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    • 2005
  • Recovery of phosphoric acid from waste acid mixture of acetic, nitric and phosphoric acid has been attempted by using solvent extraction method. In this work, organic phosphate was used as an extraction agent. The effect of phosphate concentration, agitation speed and time on the solvent extraction of acetic and nitric acids has been investigated. The optimum concentration of phosphate for preferential extraction of acetic and nitric acids from waste acid was found to be about 50% irrespective of agitation speed and time. Purified phophoric acid was recovered from extraction residue at 1/3 of A/O ratio and 6th stage of extraction stage, which is well consistent with the value calculated by using McCabe-Thiele diagram.

Decomposition of Oxalic Acid in Nitric Acid by UV Radiation (질산매질에서 UV 조사에 의한 옥살산 분해)

  • Kim, Eung-Ho;Kim, Young-Hwan;Chung, Dong-Yong;Yoo, Jae-Hyung
    • Applied Chemistry for Engineering
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    • v.8 no.1
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    • pp.108-113
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    • 1997
  • Decomposition of oxalic acid was studied in nitric acid media by using UV radiations. The UV source is Hg-lamp, emitting $2537{\AA}$ wavelength. Oxalic acid was not decomposed by itself in spite of UV radiation, but in the presence of nitric acid decomposed easily under UV radiation. It is believed that oxygen radical generated from nitrate ion by UV radiation results in the decomposition of oxalic acid. Decomposition rate of oxalic acid reached a maximum in around 0.5M $HNO_3$ and then gradually decreased with nitric acid concentration. The decrease can be also explained to be due to the reaction between oxygen radical and $NO_3{^-}$.

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Recovery of Nitric acid and Copper from Plating Waste of Automobile Wheel (자동차 휠 도금박리폐액으로부터 질산 및 구리의 회수)

  • Ha, Yonghwang;Gang, Ryun-Ji;Son, Seong-Ho;Lee, Wonsik;Ahn, Jong-Gwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.11
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    • pp.6015-6022
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    • 2013
  • It has been known that there are large amount of nitric acid and valuable metals, copper in the plating waste solution of automobile wheel. As nitric acid and valuable metals are high price and toxic, they should be recovered for economics and environment. Plating waste was extracted with TBP diluted with kerosene. The concentration of nitric acid in aqueous phase was analyzed by titration method by NaOH solution (0.1~1.0N) and the amount of metals by ICP-MS and ICP-AES. The concentration of copper in plating waste were 76,850 mg/L. The concentration of nitric acid in plating waste was 1.02 M. After three step extraction was performed with 50% TBP, each organic phase was stripped three times with distilled water to obtain 48.1% of nitric acid. Purity of final nitric acid was over 99.9% by ICP analysis. After recovery of nitric acid, copper was extracted with various solvent extractors like PC 88A, D2EPHA, LIX 84 and ISE 106. Among these extractors, 92% of copper was recovered by ISE 106 after 1st extraction and 30% $H_2SO_4$ stripping. Copper ion was reduced with $N_2H_4$ to make metal powders, respectively.

Effects on Lethal Concentration 50%, Hematological Parameters and Plasma Components of Mirror carp, Cyprinus carpio nudus Exposed to Waterborne Nitrate (수인성 질산 급성 노출에 의한 향어, Cyprinus carpio nudus의 반수치사농도, 혈액학적 성상 및 혈장성분에 미치는 독성 영향)

  • Yun-A Ryu;Seul-Gi-Na-Ra Park;Jun-Hwan Kim
    • Journal of Marine Life Science
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    • v.8 no.2
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    • pp.150-159
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    • 2023
  • To determine the toxic effects of the mirror carp, Cyprinus carpio nudus on waterborne nitric acid exposure, they were exposed to waterborne nitric acid at 0, 4, 20, 100, 500, and 2,500 mg NO3-/L for 96 h. The semi-lethal concentration (LC50) of the scented fish by 96 hours of acute exposure to nitric acid was 1,433.54 mg NO3-/L. The physiological changes of waterborne nitric acid exposure on mirror carp were evaluated through hematologic properties, and RBC count showed a significantly decreased (p < 0.05). The change in the ion control ability of the mirror carp according to exposure to waterborne nitric acid was evaluated through the plasma inorganic component, and calcium and magnesium were significantly decreased (p < 0.05) in the plasma inorganic component. The health and stress status of the mirror carp due to exposure to waterborne nitric acid were evaluated through plasma organic ingredients, and the plasma organic component glucose showed a significantly increase (p < 0.05). Changes in liver damage and enzyme activity due to waterborne nitric acid exposure were evaluated through plasma enzyme components, the enzymatic activities of plasma AST, ALT, and ALP were significantly decreased (p < 0.05) in high levels of waterborne nitric acid exposure. The results of the present study suggest that waterborne nitric acid exposure to C. carpio nudus can toxicly affect survival, hematologic properties, and plasma components.

The Effect of pH on the Ettringite Formation (Ettringite의 생성에 미치는 pH의 영향)

  • 이의학;정찬일;송명신;이경희
    • Journal of the Korean Ceramic Society
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    • v.39 no.7
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    • pp.699-703
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    • 2002
  • In order to see the effect of pH on the formation of ettringite, pH was controlled with addition of boric acid, hydrochloric acid, nitric acid and potassium hydroxide during the formation of ettringite. The behavior of ettringite formation was discussed with XRD, SEM analysis. The result was that ettringite was unstablely formed with stabilization of aluminate gel and gypsum at below PH 10.