• Journal of the Korean Chemical Society
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• v.40 no.6
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• pp.457-461
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• 1996

• Bulletin of the Korean Chemical Society
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• v.33 no.10
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• pp.3373-3377
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• 2012

A series of polystyrene-supported 1-(propyl-3-sulfonate)-3-methyl-imidazolium hydrosulfate acidic ionic liquid (PS-$[SO_3H-PMIM][HSO_4]$) catalysts were prepared and tested for mononitration of simple aromatics compounds with nitric acid. It was found that the reactivity of the catalysts increased with increasing $[SO_3H-PMIM][HSO_4]$ content. The para-selectivity was not only related to the $[SO_3H-PMIM][HSO_4]$ content but also the substituent groups in aromatics. A reaction mechanism of nitration over this new catalyst was proposed. The catalytic activity of this catalyst decreased slightly after fifth runs in the synthesis of nitrotoluene.

• Journal of Ocean Engineering and Technology
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• v.23 no.3
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• pp.30-34
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• 2009

Oil hydraulic piston pumps are being extensively used in the world, because of simple design, light weight and effective cost etc. An oil hydraulic pump is likely to have serious problems of high leakage, friction and low energy efficiency according to large time use. In the oil hydraulic piston pumps the clearance between the valve block and piston plays an important role for volumetric and overall efficiency. In this paper, the wear property of the SACM645 material used the hydraulic piston pump has been work out by experimentation with variable heat treatment. To investigate the effect according to the piston surface condition, seven different types specimen were prepared. From the wear test results, induction hardening and nitration were definitely superior to the others. On the whole, nitration was estimated for high strength material to wear resistance.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.12 no.4
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• pp.294-301
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• 2002

Vibration control of a plate using an optical fiber sensor and a piezoelectric actuator is considered in the present study, An aluminum plate with attached Extrinsic Fabry-Perot Interferometer (EFPI) and piezoelectric actuator is prepared for experimental investigation. Vibration level of EFPI that can represent the mechanical strain without severe distortion Is validated by forced nitration experiment. A linear time invariant system model is constructed based on the experimentally obtained frequency responses, and an optimal controller is designed for the multi-modal vibration suppression. Control performance is presented in frequency and time domains. It is found that the nitration level of the first three modes can be greatly reduced. The effect of low-pass filtering used to eliminate high frequency noise on the stability and control performance is also considered.

• Journal of KSNVE
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• v.11 no.2
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• pp.336-345
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• 2001

This research presents a nonlinear model to analyze the ball bearing nitration due to the waviness in a rigid rotor supported by multi-row ball bearings. The waviness of a ball and each races is modeled by the superposition of sinusoidal function, and the position vectors of inner and outer groove radius center are defined with respect to the mass center of the rotor in order to consider five degrees of freedom of a general rotor-bearing system. The waviness of a ball bearing is introduced to these position vectors to use the Hertzian contact theory in order to calculate the elastic deflection and nonlinear contact force resulting from the waviness while the rotor has translational and angular motion. They can be determined by solving the nonlinear equations of motion with five degrees of freedom by using the Runge-Kutta-Fehlberg algorithm. Numerical results of this research are validated with those of prior researchers. The proposed model can calculate the translational displacement as well as the angular displacement of the rotor supported by the multi-row ball bearings with waviness. It also characterizes the nitration frequencies resulting from the various kinds of waviness in rolling elements, the harmonic frequencies resulting from the nonlinear load-deflection characteristics of ball bearing. and the sideband frequencies resulting from the waviness interaction.

• BMB Reports
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• v.38 no.5
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• pp.577-583
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• 2005

Subtilisin QK, which is newly identified as a fibrinolytic enzyme from Bacillus subtilis QK02, has the ability of preventing nitrotyrosine formation in bovine serum albumin induced by nitrite, hydrogen peroxide and hemoglobin in vitro verified by ELISA, Western-blot and spectrophotometer assay. Subtilisin QK also attenuates the fluorescence emission spectra of bovine serum albumin in the course of oxidation caused by nitrite, hydrogen peroxide and hemoglobin. Furthermore, subtilisin QK could suppress the transformation of oxy-hemoglobin to met-hemoglobin caused by sodium nitrite, but not the heat-treated subtilisn QK. Compared with some other fibrinolytic enzymes and inactivated subtilisin QK treated by phenylmethylsulfonylfluoride, the ability of inhibiting met-hemoglobin formation of subtilisin QK reveals that the anti-oxidative ability of subtilisin QK is not concerned with its fibrinolytic function. Additionally, nitrotyrosine formation in proteins from brain, heart, liver, kidney, and muscle of mice that is intramuscular injected the mixture of nitrite, hydrogen peroxide and hemoglobin is attenuated by subtilisin QK. Subtilisin QK can also protect Human umbilical vein endothelial cell (ECV-304) from the damage caused by nitrite and hydrogen peroxide.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.12 no.12
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• pp.921-928
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• 2002

Main sources of the nitration of a gear-pair system are backlash and transmission error, the difference between required and actual rotation during gear meshing. This paper presents the nonlinear dynamic characteristics of gear motions due to the existence of backlash and periodic variation of meshing stiffness, which is assumed as a one-term harmonic component. Gear motions are classified as three types with the consideration of backlash. Each response is calculated using the harmonic balance method and confirmed by numerical integration. The responses with the increase of the rotating speed show abrupt changes in its magnitude for the variation of the preload, exciting force, and damping coefficient. The result also shows that there is a chaotic motion with some specific design parameters and operating conditions In gear diving system. Consequently the design of gear driving system with low nitration and noise requires the study on the effects of nonlinear dynamic characteristics due to stiffness variation and backlash.

• Analytical Science and Technology
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• v.12 no.1
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• pp.34-39
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• 1999

Estrone such as estriol and estradiol can not be determined by votammetric methods, because these are electrochemically inactive in the potential windows for mercury drop electrode. Nitro-derivatives of estrone are electro active and nitration of estrone is accomplished by heating the solution involving estrone and sodium nitrite in a water-bath at $100^{\circ}C$ for 30 min. Such nitro-derivatives are determined directly by voltammetry. The electrochemical behavior for nitrated estrone was investigated by cyclic voltammetry. The trace estrone was determinated by differential pulse adsorptive cathodic stripping voltammetry. Nitrated estrone gives a well defined voltammetric wave at ca. - 0.61 V (vs. Ag/AgCl electrode). The electrochemical reaction was irreversible process in sodium borate buffer at pH 11 and nitrated estrone was strongly adsorbed on the surface of mercury electrode. The optimal experimental conditions for the determination of nitrated esterone were found to be 0.05 M sodium nitrate, 0.01 M sodium borate, pH 11.0, and an accumlation potential of 0.10 V (vs. Ag/AgCl). The detection limit was as low as $1{\times}10^{-9}M$ for estrone with 2 min accumulation time.

• Journal of the Korea Institute of Military Science and Technology
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• v.5 no.4
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• pp.49-56
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• 2002

For the purpose of the increase in the performance and thermal stability of PBX's, the mixed formal consisting of BDNPF, DNPBF and BDNBF were synthesized. In order to find out the optimal condition for the synthesis of energetic plasticizer, BDNPF, DNPBF and BDNBF, the synthetic procedures have been investigated. We synthesized DNP-OH and DNB-OH through oxidative nitration and controlled various composition of mixed formal by $H_{2}SO_{4}$ and s-trioxane to investigate optimal composition, and then characterized its thermo-physical properties.

• Proceedings of the Zoological Society Korea Conference
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• 2001.10a
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• pp.265.2-265
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• 2001

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