• 제목/요약/키워드: nickel plating

검색결과 266건 처리시간 0.025초

도금업 근로자의 혈청과 공기중 크롬 및 니켈 농도 (Chromium and nickel concentrations in air and in serum of workers in chromium and nickel electroplating plants)

  • 최호춘;김해정;정호근
    • 한국산업보건학회지
    • /
    • 제1권2호
    • /
    • pp.117-127
    • /
    • 1991
  • The exposure level of chromium and nickel for chrome and nickel plating workers were evaluated. Chromium and nickel concentrations in serum from 82 exposed workers and 66 controls, who were not exposed occupationally to metals, were analyzed by flameless atomic absorption spectrophotometry. The results were as follows : 1. The recovery percent of chromium and nickel concentrations in personal air samples were 95-108.2%, 88.0-107.7%, precisions (C.V., %) were 2.7-3.1%, 2.1-4.4%. respectively. 2. The recovery percent of chromium and nickel concentrations in serum were 93.6-106.4%, 91.3-107.9% and precisions (C.V. %) were 1.1-7.6%, 2.4-5.4% respectively. 3. The exposure level of chromium and nickel concentrations in the place of preparation process were $2.0{\pm}2.00{\mu}g/m^3$, chromplating were $35.7{\pm}53.07{\mu}g/m^3$, $2.8{\pm}3.42{\mu}g/m^3$, nickelplating were $4.6.0{\pm}5.8{\mu}g/m^3$, $18.62{\pm}4.41{\mu}g/m^3$, and covering were $2.9{\pm}2.02{\mu}g/m^3$, $1.1{\pm}0.47{\mu}g/m^3$ respectively. There were significant difference of concentrations for chromium and nickel in workplaces by groups statistically. 4. Chromium concentrations in serum of exposed group and control were $0.68{\pm}0.399{\mu}g/l$, $1.41{\pm}0.748{\mu}g/l$, respectively. There were significant difference of concentrations for chromium and nickel in serum by groups statistically. 5. Chromium and nickel concentrations in serum of exposed group were not significant by workplaces.

  • PDF

유기첨가제에 의한 전기도금 니켈-구리 박막의 물성변화 (Property Change by Organic Additives in Electroplated Nickel-copper Thin Films)

  • 이정주;홍기민
    • 한국자기학회지
    • /
    • 제15권3호
    • /
    • pp.198-201
    • /
    • 2005
  • 전기도금 방법으로 제작된 니켈과 니켈-구리 합금박막에 미치는 유기첨가제(organic additive)의 영향을 조사하였다. 유기첨가제를 가하여 도금하는 니켈 박막의 경우 순수한 전해액만을 이용하여 도금한 박막과는 다른 결정성을 갖는다 도금조건을 일정하게 한 후 니켈-구리의 합금 박막용 전해액에 유기첨가제를 가하면 구리와 니켈의 조성비율이 변화하는데 유기첨가제의 성분과 농도에 따라 니켈의 함유율이 $65\~95\%$ 영역에서 조절이 가능하다. 유기첨가제에 의한 이러한 물성의 변화는 자성의 변화를 유도하여 도금 박막의 자기저항의 증가와 감소에도 기여하는 것으로 나타났다.

알루미늄에 니켈-질화붕소-인과 니켈-질화붕소-붕소의 3원계 복합도금 (Composite Coating of Nickel-Boron Nitride-Phosphours and Nickel-Boron Nitride-Boron Ternary System on Aluminum)

  • 곽우섭;윤병하;김대용
    • 한국표면공학회지
    • /
    • 제19권3호
    • /
    • pp.83-91
    • /
    • 1986
  • Codeposited of boron nitride(BN) particle dispersed into electroless nickel-phosphours (Ni-P) and nickel-boron(Ni-B) platings were studied for the purpose of developing the wear resistance and lubricity. BN can be codeposited from electroless nickel plating bath with $NaH_2PO_2$ and $NaBH_4$ as the reducing agents. Most dispersolids were distributed uniformly in the Ni-P and Ni-B matrix. Abrasion loss decreased with increasing amount of codeposits and reached a constant value 2.4 percent by volume percent of BN particle. The wear resistance and the friction coefficient of the heat treated BN composite coatings were improved about three times than that of as-coatings. The BN composite coatings were more wear resistance than hard chromium. Ni-B-BN composite coatings showed lower wear resistance and friction coefficient than Ni-P-BN. The BN content of the deposite was found to be 2.4 v/o for these optium conditions.

  • PDF

무전해 금속 도금된 폴리에스테르 섬유의 전자파 차폐성 (Electromagnetic Wave Shielding Effect of Polyester Fabrics Chemically Plated with Copper and Nickel)

  • 손지현;천태일
    • 한국염색가공학회:학술대회논문집
    • /
    • 한국염색가공학회 2004년도 추계학술발표회 논문집
    • /
    • pp.238-244
    • /
    • 2004
  • In this study we have examined Copper and Nickel double metal layer on the synthetic fabrics by electroless chemical plating. We have focused on the shielding effect of the four kinds of woven and none-woven structure against electromagnetic fields. The shielding effectiveness of Copper and Nickel double metal layer showed between 90dB and 70dB, which are closely related to the fabric structure, that is cover factor and density. The more dense, The better shielding effect.

  • PDF

미세 입자 조작 기구의 제작 및 실험 (Fabrication and Experiment of Micro Particle Manipulator)

  • 박재형;김용권
    • 대한전기학회논문지:전기물성ㆍ응용부문C
    • /
    • 제50권3호
    • /
    • pp.136-143
    • /
    • 2001
  • A micro particle manipulator, which is devised for trapping particles at fixed positions by negative dielectrophoretic force (DEP force), has been fabricated and experimented. It is composed of square type electrode arrays fabricated by nickel electroplating with the height of 28 ${\mu}m$. To improve the quality of electroplated nickel electrodes, plating conditions have been optimized. Micro particles used in this study are polystyrene spheres and their to the specific position and trapped. The DEP force along the moving path of the particles has been estimated by the motion equation of a single particle. The displacement of a particle with an elapsed time was measured using a high-speed camera (1000 frames/sec). The velocity and acceleration of the particle were calculated from the measured data. The DEP force acting on the particle was estimated.

  • PDF

결정의 발생속도식과 송장속도식의 해석에 지초한 광택니켈도금의 새로운 메카니즘 (A New Mechanish of Bright Plating on the Ground of Analysis of Rate Nucleafion and Growth)

  • 박병각;송재설;김창진
    • 한국표면공학회지
    • /
    • 제21권2호
    • /
    • pp.76-82
    • /
    • 1988
  • The bright nickel electroplatings were carried out the Watt bath containg a solobel saccharin as class I brightner and para substituted benzaldehydes as class II one. Extended Huckel MO calculation was done and polarization was measured to examine between $\pi$-electron density and the brightness. The correlation is also investigated between $\pi$-electron density of oxygen atom of aldehyde group and slope of polarization curve. As a result of the analysis of rate equation of nucleation, the surface energy of the deposited particle was obtained from the slope of the plot of $\ell$nI against 1/η2, and also the reat equation of nucleation found to influnced on the leveling on the basis of adsorption theory. We have proposed the general electroplating mechanism that is applied other to all other electroplating but nickel one. The above elucidated mechanism can be extended can be extended to the all electroplating other than bright nickel electroplating.

  • PDF

電析니켈에 있어서 電着條件이 內部應力에 미치는 影響 (Effect of Plating Conditions on Internal Stress of Nickel Electrodeposits)

  • 고석수
    • 한국표면공학회지
    • /
    • 제13권4호
    • /
    • pp.211-220
    • /
    • 1980
  • Internal stress of electrodeposited metals affect physical and mechanical characteristics of deposits. Internal stress of nickel deposits was reviewed intensively. Important outcomes are as follows. Substrate have an important effect on internal stress of electrodeposit. Origin of its internal stress could be explained mismatch of crystal lattice and coalescence of crystallites. When surface cleaning is not satisfying, instantaneous stress is low but the electrodeposited layer being thickened increasingly stress become to high and peeling phenomenon occurs. Effect of current density and temperature on internal stress is variable. Internal stress increases rapidly at pH 5 and above because of codepositing colloidal materials caused hydrolysis. Concentrations of nickel ion and $H_3BO_3$ ion affect little on internal stress and solution which contains impurities tend to increase stress. Especially impurities of $H_2O_2$ and iron ion have a great effect on internal stress. Additives are divided in two kind. One is increasing tensile stress another is increasing compressive stress. Concentrations of additives have a great effect on internal stress.

  • PDF

스퍼터 증착 방식으로 제조된 Pd-Ni 합금 수소 분리막 연구 (A Study on the Pd-Ni Alloy Hydrogen Membrane Using the Sputter Deposition)

  • 김동원;박정원;김상호;박종수
    • 한국표면공학회지
    • /
    • 제37권5호
    • /
    • pp.243-248
    • /
    • 2004
  • A palladium-nikel(Pd-Ni) alloy composite membrane has been fabricated on microporous nickel support formed with nickel powder. Plasma surface treatment process is introduced as pre-treatment process instead of HCI activation. Pd coating layer was prepared by dc magnetron sputtering deposition after $H_2$ plasma surface treatment. Palladium-nickel alloy composite layer had a fairly uniform and dense surface morphology. The membrane was characterized by permeation experiments with hydrogen and nitrogen gases at temperature of 773 K and pressure of 2.2psi. The hydrogen permeance was 6 ml/minㆍ$\textrm{cm}^2$ㆍatm and the selectivity was 120 for hydrogen/nitrogen($H_2$/$N_2$) mixing gases at 773 K.