• 제목/요약/키워드: new particle formation

검색결과 103건 처리시간 0.03초

Scale effect of mechanical properties of jointed rock mass: A numerical study based on particle flow code

  • Wang, Xiao;Yuan, Wei;Yan, Yatao;Zhang, Xue
    • Geomechanics and Engineering
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    • 제21권3호
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    • pp.259-268
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    • 2020
  • The synthetic rock mass (SRM) were used to investigate the influence of specimen size on the mechanical properties of jointed rock mass. The SRM were established based on parallel bond model (PBM) and smooth joint model (SJM) and the scaled rock specimens were sampled in two SRMs considering three sampling locations. The research results show that the smaller the initial fracture density is, the greater the uniaxial compressive strength (UCS), elastic modulus (E) is when compared with the same sampling location. The mechanical properties of rock specimens obtained by different sampling methods in different SRMs have different scale effects. The strength of rock specimens with more new cracks is not necessarily less than that of rock specimens with fewer new cracks and the failure of rock is caused by the formation of macro-fracture surface.

한반도 서부유입권역에서 대기 중 에어로졸 성분의 물리·화학적 특성 연구 III. 화학적 거동 및 장거리 이동 (Physico-chemical Characteristics of Submicron Aerosol at West Inflow Regions in the Korean Peninsula III. Physical-Chemical Behavior and Long-range Transport of PM1)

  • 박태현;안준영;최진수;임용재;박진수;김정호;오준;이용환;홍유덕;홍지형;최용주;이태형
    • 한국대기환경학회지
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    • 제33권2호
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    • pp.124-138
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    • 2017
  • Physico-chemical measurement of non-refractory submicron particles($NR-PM_1$) was conducted in Baengnyeong Island, Korea using Aerodyne High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS) from 2012 to 2014. Organics and ammoniated sulfate were dominant species in $NR-PM_1$. The organics was found to have similar fractions(approximate 40%) of $NR-PM_1$ during the summer and winter, while the sulfate fractions of $NR-PM_1$ were calculated to be approximately 47% and 31% for the summer and winter, respectively, suggesting the possibility that particles provide non-acidic surfaces for condensation of nitric acid in the winter. The nitrate fractions of approximate 4% and 20% of $NR-PM_1$ were observed in August (summer) and November (winter), respectively, resulting that the relatively low concentration of sulfate in $NR-PM_1$ provided a non-acidic surface for nitric acid condensation and formation of particulate ammoniated nitrate is favored thermodynamically in winter. The new particle formation (NPF) event and particle growth rate were analyzed for each month in 2014 using Scanning Mobility Particle Sizer(SMPS). The Percent of NPF events was the highest in winter, but NPF event was not observed during summer due to relatively high temperature and frequent rainfall. The average particle growth rate was 3.5 nm/h and the highest particle growth rate was 5.5 nm/h in May. We observed the long-range transport of the anthropogenic sulfate from the East Asia during the intensive monitoring period of November between Qingdao and Baengnyeong Island in 2013. The relatively high concentrations of m/z 60 measured in HR-ToF-AMS was observed in May and June at Baengnyeong Island, suggesting the possibility of the influence of biomass burning from the East Asia to the Korean Peninsula.

유화중합에 의한 Methyl Methacrylate-Styrene계 Core-Shell 라텍스 입자 제조에 관한 연구 (Preparation of Methyl Methacrylate-Styrene System Core-Shell Latex by Emulsion Polymerization)

  • 김남석;김덕술;이석희;박근호
    • 한국응용과학기술학회지
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    • 제22권2호
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    • pp.96-105
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    • 2005
  • Core-shell polymers of methyl methacrylate-styrene system were prepared by sequential emulsion polymerization in the presence of sodium dodecyl benzene sulfonate(SDBS) as an emulsifier using ammonium persulfate(APS) in an initiator and the characteristics of these core-shell polymers were evaluated. Core-shell composite latex has the both properties of core and shell components in a particle, whereas polymer blends or copolymers show a combined physical properties of two homopolymers. This unique behavior of core-shell composite latex can be used in various industrial fields. However, in preparation of core-shell composite latex, several unexpected matters are observed, for examples, particle coagulation, low degree of polymerization, and formation of new particles during shell polymerization. To solve this matters, we study the effects of surfactant concentrations, initiator concentrations, and reaction temperature on the core-shell structure of PMMA-PSt and PSt-PMMA. Particle size and particles distribution were measured by using particle size analyzer, and the morphology of the core-shell composite latex was observed by using transmission electron microscope. Glass temperature was also measured by using differential scanning calorimeter. To identify the core-shell structure, pH of the composite latex solutions was measured.

점도변화와 흡착현상을 고려한 시멘트계 그라우트재의 새로운 침투 기준 (A New Groutability Criterion of Cement-based Grout with Consideration of Viscosity and Filtration Phenomenon)

  • 김종선;이인모;이문선;최항석
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2009년도 춘계 학술발표회
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    • pp.154-163
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    • 2009
  • The groutability depends on the properties of the grout, its injection processes, and on the mechanical properties of the soil formation. During the process of pouring cement-based grouting into a porous medium, a variation with time occurs in the viscosity of grout suspension. In addition the particle filtration phenomenon will limit the expansion of the grouted zone because cement particles are progressively stagnant within the soil matrix. In this paper, a closed-form solution was derived by implementing the mass balance equations and the generalized phenomenological filtration law, which can be used to evaluate the deposition of cement-based grout in the soil matrix. The closed-form solution relevant to a particular spherical flow was modified by a step-wise numerical calculation, considering the variable viscosity caused by a chemical reaction, and the decrease in porosity resulting from grout particle deposition in the soil pores. A series of pilot-scale chamber injection tests was performed to verify that the developed step-wise numerical calculation is able to evaluate the injectable volume of grout and the deposition of grout particles. The results of the chamber injection tests concurred well with that of the step-wise numerical calculation. Based on the filtration phenomenon, a new groutability criterion of cement-based grout in a porous medium was proposed, which might facilitate a new insight in the design of the grouting process.

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CFD-DEM modeling of snowdrifts on stepped flat roofs

  • Zhao, Lei;Yu, Zhixiang;Zhu, Fu;Qi, Xin;Zhao, Shichun
    • Wind and Structures
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    • 제23권6호
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    • pp.523-542
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    • 2016
  • Snowdrift formation on roofs should be considered in snowy and windy areas to ensure the safety of buildings. Presently, the prediction of snowdrifts on roofs relies heavily on field measurements, wind tunnel tests and numerical simulations. In this paper, a new snowdrift modeling method by using CFD (Computational Fluid Dynamics) coupled with DEM (Discrete Element Method) is presented, including material parameters and particle size, collision parameters, particle numbers and input modes, boundary conditions of CFD, simulation time and inlet velocity, and coupling calculation process. Not only is the two-way coupling between wind and snow particles which includes the transient changes in snow surface topography, but also the cohesion and collision between snow particles are taken into account. The numerical method is applied to simulate the snowdrift on a typical stepped flat roof. The feasibility of using coupled CFD with DEM to study snowdrift is verified by comparing the simulation results with field measurement results on the snow depth distribution of the lower roof.

해안지역별 준설점토의 침강 및 토질특성 (Comparative Study on Sedimentation and Soil Characteristic of Dredged Marine Clays at Coastal Areas)

  • 이광열;황재홍;장삼식;구태곤
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2004년도 춘계학술발표회
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    • pp.922-929
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    • 2004
  • In some port construction, a case of reclamation with dredged soil for land use can be found. Even though this is not a new technology, there are some problems on the test method and analysis. The design parameters are still remained to be solved to get accurate prediction. Sedimentation of particle and self-weight consolidation are the most important design parameters in reclamation by dredged soils. The design parameters are influenced by properties of the physical and sedimentation of dredged soils. This influencing factors can be determined depend on the history of long term sedimentation and particle characteristics. Thus, properties of the sedimentation and consolidation are varies depend on the regional geologic formation. In this paper, three different sites with different regional soil properties will be compared in design parameters of sedimentation and self-weight consolidation.

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Soil water retention and vegetation survivability improvement using microbial biopolymers in drylands

  • Tran, An Thi Phuong;Chang, Ilhan;Cho, Gye-Chun
    • Geomechanics and Engineering
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    • 제17권5호
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    • pp.475-483
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    • 2019
  • Vegetation cover plays a vital role in stabilizing the soil structure, thereby contributing to surface erosion control. Surface vegetation acts as a shelterbelt that controls the flow velocity and reduces the kinetic energy of the water near the soil surface, whereas vegetation roots reinforce the soil via the formation of root-particle interactions that reduce particle detachment. In this study, two vegetation-testing trials were conducted. The first trial was held on cool-season turfgrasses seeded in a biopolymer-treated site soil in an open greenhouse. At the end of the test, the most suitable grass type was suggested for the second vegetation test, which was conducted in an environmental control chamber. In the second test, biopolymers, namely, starch and xanthan gum hydrogels (pure starch, pure xanthan gum, and xanthan gum-starch mixtures), were tested as soil conditioners for improving the water-holding capacity and vegetation growth in sandy soils. The results support the possibility that biopolymer treatments may enhance the survival rate of vegetation under severe drought environments, which could be applicable for soil stabilization in arid and semiarid regions.

Reduced ion mass effects and parametric study of electron flat-top distribution formation

  • 홍진희;이은상;;민경욱
    • 천문학회보
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    • 제37권2호
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    • pp.118.2-118.2
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    • 2012
  • In particle-in-cell (PIC) simulation studies related to ion-ion two-stream instability, a reduced ion-to-electron mass ratio is often employed to save computation time. But it was not clearly verified how electrons dynamics are coupled with the slower evolution of ion-ion interactions under the external electric field. We have studied the ion beam driven instability using a 1D electrostatic PIC code by comparing different rescaling of parameter with real ion mass from the reference simulation with reduced ion mass. As the external electric field is stronger, the excited unstable mode range was more sensitively affected by the system size with the real mass ratio than the reduced ion mass. The results show that the reduced mass ratio should be used cautiously in PIC code as the electron dynamics can modify the ion instabilities. Additionally we found the formation of electron flat-top distribution in the final saturation stage. Simulation results show that in the early phase electrostatic solitary waves are quasi-periodically formed, but later they are fully dissipated resulting in heated, flat-top distributions. New electron beam components are occasionally formed. These are a consequence of the interaction with solitary wave structures. We parametrically investigate the development of electron phase space distributions for various drift speeds of ion beams and temperature ratios between ions and electrons

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모델링을 통한 Ar 플라즈마 중의 미립자 운동에 관한 연구 (Modeling and Analysis of Fine Particle Behavior in Ar Plasma)

  • 임장섭;소순열
    • 조명전기설비학회논문지
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    • 제18권1호
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    • pp.52-59
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    • 2004
  • 미립자 플라즈마란 입경이 수[$\mu\textrm{m}$]이하의 거의 일정한 크기를 가진 미립자가 다수로 생성 및 유지되면서, 정 또는 부외 전하를 가지고 기체 플라즈마 중에 부유하는 상태를 말한다. 플라즈마 프로세스에서는 이러한 미립자가 집적회로에 중착되어 막의 열화, 회로 배선의 불량 및 단선 등의 약영향을 끼치는 것으로 인식되고 있으며, 이러한 부분에 대한 억제나 제어에 관한 연구가 진행되고 있다. 본 연구에서는 유체 모델을 이용한 시뮬레이션으로부터 방전 챔버내의 Ar 플라즈마의 현상을 이해하고, Ar 플리즈마 중에 미립자를 투입하여 그 움직임을 분석하여, 플라즈마 중의 미립자 운동의 핵석 결과로서는, 하부 전극 면위에 비교적 규칙성을 갖는 미립자가 배열하는 것을 확인할 수 있었다. 또한, 약 전리 플라즈마에서는 전지의 이동로가 크기 때문에 미립자의 대전량은 평균 전자 에너지에 크게 의존하는 것을 알 수 있었다.

Reaction Behavior of Li4+xTi5O12 Anode Material as Depth of Discharge

  • Cho, Woo-Suk;Song, Jun-Ho;Park, Min-Sik;Kim, Jae-Hun;Kim, Jeom-Soo;Kim, Young-Jun
    • Journal of Electrochemical Science and Technology
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    • 제1권2호
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    • pp.85-91
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    • 2010
  • We have studied the origin of an additional plateau of $Li_{4+x}Ti_5O_{12}$ (LTO) observed at 0.7 V (vs. Li/$Li^+$). Some LTO has to be discharged down to below 1.0 V forming two-stage plateau (1.5 V and 0.7 V) in order to obtain most of capacity while others could achieve the same level of capacity at higher potential (1.0 V vs. Li/$Li^+$) forming one plateau (1.5 V). The particle size effect has been investigated as a possible reason of this. The 0.7 V plateau was gradually elongated with increasing the particle size. The structural variations and kinetic behaviors during discharge were carefully examined by in-situ XRD technique and OCV measurement. According to structural and electrochemical verifications, the kinetic limitation of $Li^+$ insertion is responsible primarily for the two-stage plateau which is related to the particle size of LTO rather than the formation of new intermediate phase during discharge. Herein, we propose a possible reaction model to elucidate this abnormal behavior of LTO below 1.0 V (Li/$Li^+$).