• Title/Summary/Keyword: neutron activation analysis

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Characteristics of Respirable Particulate Matter from the Third and Fourth Industrial Complex Area of Daejeon City Using Instrumental Neutron Activation Analysis (기기중성자방사화분석을 이용한 대전 3, 4 공단지역의 호흡성입자의 특성)

  • Lim, Joung-Myoung;Lee, Jin-Hong
    • Journal of Environmental Impact Assessment
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    • v.15 no.6
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    • pp.425-433
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    • 2006
  • Instrumental neutron activation analysis was used to measure the concentrations of 27 elements associated with respirable particulate matter (PM10) that were collected from the Third and Fourth Industrial Complex Area of Daejeon City. The distribution patterns of elements were clearly distinguished with their concentrations varying across more than four orders of magnitude. The mean for Al were recorded to be the highest value of 1,527 $ng/m^3$, while that for In showed the lowest value of 0.1 $ng/m^3$. If compared in terms of enrichment factors, it was found that certain elements (e.g., As, Br, Cl, Cr, I, In, Sb, Se, and Zn) are enriched in PM10 samples of the study site. The results of factor analysis indicated six factors with statistical significance, which may exert dominant controls on regulating the elemental concentration levels in the study area.

Comparison of General Concrete and Low-radiation Concrete as Shielding Materials for Medical Linear Accelerators (의료용 선형가속기 차폐 재질로써 일반 콘크리트와 저 방사화 콘크리트 비교)

  • Lee, Dong Yeon;Kim, Jung Hoon
    • Journal of the Korean Society of Radiology
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    • v.13 no.1
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    • pp.45-53
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    • 2019
  • This study is a neutron activation for concrete that shields medical linear accelerator facilities. Comparison of general concrete and low activation concrete. The simulation method was simulated using MCNPX (Ver. 2.5.0) and FISPACT-2010, and the shielding ability for photon and neutron beams was calculated and neutron activation evaluation was carried out. As a result, the shielding capacity was 20 ~ 50 cm efficient in general concrete, and activate evaluation in low activation concrete was calculated to be low in radioactivity concrete, but all were estimated to not exceed their own allowable concentration in self - disposal. As a result of the comprehensive analysis, it is considered effective to use ordinary concrete.

Copper Salts in the Post-metallization of Non-genotoxic Direct Dyes

  • Bae, Jin-Seok;Freeman, Harold S.
    • Fibers and Polymers
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    • v.3 no.4
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    • pp.147-152
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    • 2002
  • Copper (II) salts are used as metallizing agents in the synthesis of new non-genotoxic direct dyes for cotton. Specifically, cotton fabric is dyed with non-genotoxic disazo direct dyes and then treated with copper salts. The complexes are characterized by neutron activation analysis, absorption spectrometry and standard Salmonella mammalian mutagenicity assay, and the after-treated fabrics are evaluated for lightfastness and washfastness. Direct dyes possessing ortho-propoxy and ortho'-hydroxy substituted systems formed the corresponding nonmutagenic 1:2 dye:metal complex and undergo significant improvement in lightfastness following metallization.

A Classification of Korean Ancient Coins by Neutron Activation Analysis (중성자 방사화분석에 의한 한국산 고전(古錢)의 분류)

  • Chun, Kwon Soo;Lee, Chul;Kang, Hyung Tae;Lee, Jong Du
    • Analytical Science and Technology
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    • v.7 no.3
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    • pp.293-299
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    • 1994
  • Fifty ancient Korean coins originated in Choson period have been determined for 11 elements such as Sn, Fe, As, Au, Co, Sb, Ir, Os, Ru and Ni by destructive and non-destructive neutron activation analysis as well as for 3 elements such as Cu, Pb and Zn by atomic absorption spectroscopy. The multivariate data have been analyzed by principal component mapping method. The spread of sample points in the eigenvector polt has been attributed to common origins of some elements.

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The Determination of Gold in Assay Process by Thermal Neutron Activation Analysis (試金工程中의 金의 熱中性子에 依한 放射化分析)

  • J.I. Kim;Chong Kuk Kim;W.P. Chang
    • Journal of the Korean Chemical Society
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    • v.7 no.2
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    • pp.165-169
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    • 1963
  • 12 samples from an assay process chain were submitted to qualitative and quantitative neutron activation analysis for the determination of gold. Gold was detected and quantitatively determined in three samples after a chemical separation consisting of solvent extraction and precipitation steps. Recoveries ranged between 81.0 and 93.6% and results of duplicated determinations were reproducible. Quantitative data were obtained from gamma-spectrometric photopeak-area counting. Interference from fast neutron reactions was negligible.

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Activation-Analysis of trace Thallium in Meteorites, Rocks, Minerals, Alloys, and Biological Samples using 4.2-Minute Thallium-206 (4.2分의 短壽命 Thallium-206의 放射化分析)

  • Kim, Chong-Kuk
    • Journal of the Korean Chemical Society
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    • v.5 no.1
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    • pp.26-28
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    • 1961
  • Microgram quantities of thallirum in meteorites, rocks, minerals, alloys and biological samples have been analyzed by rapid neutron activation analysis. A l0-minute radiochemical separation procedure coupled with a gas-flow proportional detector for 4.2-minute half life measurement and a gamma or beta scintillation detector placed in close proximity to the sample permitted detection of the 4.2-min Tl206. Samples were irradiated for 10-minutes at a thermal neutron flux of approximately $0.95{\times}10^{11}$ neutron-$cm^{-2}-sec^{-1}.$ The low limits of detection was about $10^{-7}$ gm of thallium.

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Determination of Trace Elements in Airborne Particulates by Instrumental Neutron Activation Analysis (중성자 방사화분석법을 이용한 대기분진시료의 정량)

  • Chung, Yong-Sam;Chung, Young-Ju;Jeong, Eui-Sik;Cho, Seung-Yeon
    • Nuclear Engineering and Technology
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    • v.27 no.2
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    • pp.234-247
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    • 1995
  • Trace elements in airborne particulates were analyzed by instrumental neutron activation analysis (INAA) under the optimum analytical condition. Neutron irradiation for sample was done at the irradiation hole(neutron flux 1$\times$10$^{13}$ n/$\textrm{cm}^2$.s) of TRIGA MARK-III research reactor in the Korea Atomic Energy Research Institute. For the verification of the analytical method, NIST SRM-1648 and NIES CRM No.8 ore chosen and analyzed. The accuracy and precision of the analysis of 40 and 24 trace elements in the samples were compared with the certified and reported values, respectively. The analytical method was found to be reliable enough when the analytical data of NIES sample were compared with those of different counties. In the analytical result of two or both of standard reference materials, relative standard deviation wes within the 15% except a few elements and the relative error was within the 10%. We used this method to analyze 30 trace elements in airborne particulates collected with the high volume air sampler(PM-10) at too different locations and also confirmed the possibility to use this method as a routine monitoring tool to find out environmental pollution sources.

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Determining PGAA collimator plug design using Monte Carlo simulation

  • Jalil, A.;Chetaine, A.;Amsil, H.;Embarch, K.;Benchrif, A.;Laraki, K.;Marah, H.
    • Nuclear Engineering and Technology
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    • v.53 no.3
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    • pp.942-948
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    • 2021
  • The aim of this work is to help inform the decision for choosing a convenient material for the PGAA (Prompt Gamma Activation Analysis) collimator plug to be installed at the tangential channel of the Moroccan Triga Mark II Research Reactor. Two families of materials are usually used for collimator construction: a mixture of high-density polyethylene (HDPE) with boron, which is commonly used to moderate and absorb neutrons, and heavy materials, either for gamma absorption or for fast neutron absorption. An investigation of two different collimator designs was performed using N-Particle Monte Carlo MCNP6.2 code with the ENDF/B-VII.1 and MCLIP84 libraries. For each design, carbon steel and lead materials were used separately as collimator heavy materials. The performed study focused on both the impact on neutron beam quality and the neutron-gamma background at the exit of the collimator beam tube. An analysis and assessment of the principal findings is presented in this paper, as well as recommendations.

Measurement of the Elemental Composition in Airborne Particulate Matter Using Instrumental Neutron Activation Analys

  • Chung, Yong-Sam;Lim, Jong-Myoung;Moon, Jong-Hwa;Kim, Sun-Ha;Cho, Hyun-Je;Kim, Young-Jin
    • Nuclear Engineering and Technology
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    • v.36 no.5
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    • pp.450-459
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    • 2004
  • For the evaluation of emission sources by air sampling, airborne particulate matter for fine (<2.5 ${\mu}m2$ EAD : $PM_{2.5}$) and coarse partical (2.5-10 ${\mu}m2$ EAD : $PM_{2.5-10}$ fractions were collected using a Gent stacked filter unit low volume sampler and two types of polycarbonate filters. Air samples were collected twice monthly at two regions in and around Daejeon city in the Republic of Korea from January to December 2002. Monthly mass concentration of $PM_{2.5}$ and $PM_{2.5-10}$ were measured and the concentrations of 10 marker elements (Al, Sc, Ti ; Na, Cl ; As, V. Sb, Br, Se) were determined by an instrumental neutron activation analysis. Analytical quality control was corried out using certified reference materials. Enrichment factors were also calculated from the monitoring data to classify the anthropogenic and crustal origins.