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Influence of TiO2 Nanoparticle Filler on the Properties of PET and PLA Nanocomposites (이산화티탄 나노입자 필러가 PET와 PLA 나노복합체의 특성에 미치는 영향)

  • Farhoodi, Mehdi;Dadashi, Saeed;Mousavi, Seyed Mohammad Ali;Sotudeh-Gharebagh, Rahmat;Emam-Djomeh, Zahra;Oromiehie, Abdolrasul;Hemmati, Farkhondeh
    • Polymer(Korea)
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    • v.36 no.6
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    • pp.745-755
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    • 2012
  • Two types of polymers were tested in this study; poly(ethylene terephthalate) (PET) as a synthetic example and poly(lactic acid) (PLA) as a natural polymer. DSC analyses showed that the use of nanofiller increased the degree of crystallinity ($X_c$) of both PET and PLA polymers, but the effect was more noticeable on PET nanocomposites. The crystallization of PLA and PET nanocomposites occurred at higher temperatures in comparison to neat polymers. According to dynamic mechanical-thermal analysis (DMTA), the damping factor of PET/$TiO_2$ nanoparticles decreased compared to the neat matrix, but for PLA nanocomposites the opposite trend was observed. Results of the mechanical test showed that for both PET and PLA nanocomposites, the most successful toughening effect was observed at 3 wt% loading of $TiO_2$ nanoparticles. SEM micrographs revealed uniform distribution of $TiO_2$ nanoparticles at 1 and 3 wt% loading levels. The results of WAXD spectra explained that the polymorphs of PLA and PET was not affected by $TiO_2$ nanoparticles. UV-visible spectra showed that $TiO_2$ nanocomposite films had high ultraviolet shielding compared to neat polymer, but there was significant reduction in transparency.

Far-ultraviolet Observations of the Comet C/2001 Q4 (NEAT)

  • Lim, Yeo-Myeong;Min, Kyoung-Wook;Seon, K.I.;Han, W.;Edelstein, J.
    • Bulletin of the Korean Space Science Society
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    • 2011.04a
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    • pp.20.1-20.1
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    • 2011
  • We present the results of far-ultraviolet (FUV) observations of comet C/2001 Q4 (NEAT) obtained with Far-ultraviolet Imaging Spectrograph (FIMS) on board the Korean microsatellite STSAT-1, which operated at an altitude of 700 km in a sun-synchronous orbit. FIMS is a dual-channel imaging spectrograph (S channel 900-1150 ${\AA}$, L channel 1350-1750 ${\AA}$, ${\lambda}/{\Box}{\lambda}$ ~ 550) with large image fields of view (S: $4^{\circ}.0{\times}4'.6$, L: $7^{\circ}.5{\times}4'.3$, angular resolution 5'-10') optimized for the observation of diffuse emission of astrophysical radiation. Comet C/2001 Q4 (NEAT) was observed with a scanning survey mode when it was located around the perihelion between 8 and 15 May 2004. Several important emission lines were detected including S I (1425, 1474 ${\AA}$), C I (1561, 1657 ${\AA}$) and several emission lines of CO $A1{\cap}-X1{\sum}+$ system in the L channel. We estimated QCO = ($2.58\;{\pm}\;0.64)\;{\times}\;1028$ s-1 from the production rate of CO 1510 ${\AA}$. We obtained L-channel image which have map size of $5^{\circ}{\times}5^{\circ}$. The image was constructed for the wavelength band of L-channel (1350-1750 ${\AA}$).We also obtained radial profile of S I, C I, CO with line fitting from central coma.

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The preparation and characterization of poly(ethylene terephthalate)(PET)/layered silicate nanocomposite (PET 나노복합재료의 제조 및 특성분석)

  • 천상욱;손세범;곽승엽
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.21-24
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    • 2003
  • In general, to enhance physical properties of PET-layered silicate nanocomposites $(P_{et}LSNs)$, it has been well known that the organic modifiers should introduce into gallery regions. However, the organic modifiers in$(P_{et}LSNs)$ may result in thermal decomposition by melt processing at high temperature, and it necessarily lead to deteriorate various physical properties of final products. Therefore, in this study, $(P_{et}LSNs)$ excluding and including organic modifiers were prepared by solution method $(S-P_{et}LSNs_{eom} and S-P_{et}LSNs_{iom})$ and we (focused on the effects of the organic modifiers in $P_{et}$ LSNs with exfoliation structure on the crystallization behaviors, the optical transparency, the thermal stability and the mechanical property. The absence and existence of organic modifiers in $S-P_{et}LSNs_{eom} and S-P_{et}LSNs_{iom}$ were investigated by EA and TGA, and nano-structure of silicate layers in $S-P_{et}LSNs$ was evaluated by using WXRD, SAXS and TEM. $S-P_{et}LSNs_{eom} and S-P_{et}LSNs_{iom}$ were mixed with neat PET as masterbatches by melt method $(M-P_{et}LSNs_{eom} and M-P_{et}LSNs_{iom})$, and also neat PET was mixed with organically modified layered silicates (OLS) by conventional direct melt method $(D-P_{et}LSNs) at 270^{\circ}C$. As results, it was found that $M-P_{et}LSNs_{eom}, M-P_{et}LSNs_{iom}, and D-P_{et}LSN$ showed a exfoliated structure and exhibited faster crystallization rate, better thermal stability and mechanical property than those of neat PET due to the dispersed and detaminated silicate layers in PET matrix. Whereas, considering organic modifiers effect, $M-P_{et}LSNs_{eom} and D-P_{et}LSN$ exhibited slower crystallization rate, poorer optical, thermal and mechanical properties, in comparison to $M-P_{et}LSNs_{eom}> due to the thermal decomposition of organic modifier in $D-P_{et}LSNs$ during melt method.

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An Analytical Evaluation on the flue Gas and Combustion Efficiency of Emulsion Fuel (에멀죤 연료의 연소 배출가스특성 및 연소 효율에 관한 분석평가)

  • Park, Hyun-Mee;Eo, Yun-Woo;Baig, Seung-Woo;Park, Il Yong;Paeng, Ki Jung;Kim, Young-Man;Lee, Kang-Bong
    • Analytical Science and Technology
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    • v.15 no.5
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    • pp.427-432
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    • 2002
  • The combustion behavior of heavy oil and its emulsion with water was evaluated. The concentration of $SO_x$ in the combustion gas of emulsion oil was reduced to 57% with respect to that of the combustion gas from neat heavy oil. Also, the concentration of $NO_x$ in the combustion gas of emulsion oil was reduced to 67% with respect to that of the combustion gas of neat heavy oil. These reductions of $SO_x$ in the combustion gas of emulsion oil seems to be due to the reaction with salts included in surfactant of emulsion oil. Also, the combustion efficiency of emulsion oil is evaluated to be about 6% higher than that of neat heavy oil.

FUV observation of the comet C/2001 Q4 (NEAT) with FIMS

  • Lim, Yeo-Myeong;Min, Kyoung Wook;Feldman, Paul D.;Han, Wonyong;Edelstein, Jerry
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.107.1-107.1
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    • 2012
  • We present the results of far-ultraviolet (FUV) observations of comet C/2001 Q4 (NEAT) obtained with Far-ultraviolet Imaging Spectrograph (FIMS) on board the Korean microsatellite STSAT-1, which operated at an altitude of 700 km in a sun-synchronous orbit. FIMS is a dual-channel imaging spectrograph (S channel 900-1150 ${\AA}$, L channel 1350-1750 ${\AA}$, ${\lambda}/{\Delta}{\lambda}$ ~ 550) with large image fields of view (S: $4^{\circ}.0{\times}4^{\prime}.6$, L: $7^{\circ}.5{\times}4^{\prime}.3$, angular resolution 5'-10') optimized for the observation of diffuse emission of astrophysical radiation. Comet C/2001 Q4 (NEAT) was observed with a scanning survey mode when it was located around the perihelion between 8 and 15 May 2004. Several important emission lines were detected including S I (1425, 1474 ${\AA}$), C I (1561, 1657 ${\AA}$) and several emission lines of CO $A^1{\Pi}-X^1{\Sigma}^+$ system in the L channel. Production rates of the notable molecules, such as C I, S I and CO, were estimated from the photon fluxes of these spectral lines and compared with previous observations. We compare the flux and the production rates in the radius of $3{\times}10^5$ km with $20{\times}10^5$ km from the central coma. We obtained L-channel image which have map size $5^{\circ}{\times}5^{\circ}$ The image was constructed for the wavelength band of L-channel (1350 - 1710 ${\AA}$. We also present the radial profiles of S I, C I, CO obtained from the spectral images of the central coma. The radial profiles of $2{\times}10^6$ km region are compared with the Haser model.

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Early Emergency Responses of the Japan Atomic Energy Agency against the Fukushima Daiichi Nuclear Power Station Accident in 2011

  • Okuno, Hiroshi;Sato, Sohei;Kawakami, Takeshi;Yamamoto, Kazuya;Tanaka, Tadao
    • Journal of Radiation Protection and Research
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    • v.46 no.2
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    • pp.66-79
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    • 2021
  • Background: The Japan Atomic Energy Agency (JAEA) is specified in the Disaster Counter-measures Basic Act as a designated public corporation for dealing with nuclear disasters. Materials and Methods: The Nuclear Emergency Assistance and Training Center (NEAT) was established in 2002 as the activity base providing technical assistance to both national and local governments during nuclear emergencies. The NEAT has a robust structure and utilities and special installations, and it organizes training and exercises. Results and Discussion: Due to an offshore earthquake that caused a devastating tsunami in March 2011, a nuclear accident occurred at the Tokyo Electric Power Company's Fukushima Daiichi Nuclear Power Station. The NEAT responded by conducting off-site environmental radiation monitoring and contamination screening, dispatching special vehicles, offering telephone consultations, and calculating the dispersion of radioactive materials. An examination of the emergency response activities revealed that the organization was prepared for these types of disasters and was able to plan long-term response. Conclusion: As a designated public corporation, the JAEA technically supports the national government, the Fukushima prefectural government, and the Ibaraki prefectural government, all of which responded to the off-site emergencies resulting from the March 2011 Fukushima Daiichi accident

A Study on the Failure Modes of Neat Kevlar Fabric and Kevlar Liquid Armor Impregnated with Shear Thickening Fluid (케블라 직물과 전단농화유체로 함침된 케블라 액체 방탄재의 파단모드 연구)

  • Yoon, Byung-Il;Song, Heung-Sub;Paik, Jong-Gyu
    • Composites Research
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    • v.20 no.3
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    • pp.17-24
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    • 2007
  • In this study, the failure modes by ballistic impacts were studied both for a neat Kevlar woven fabric and a Kevlar liquid armor impregnated with shear thickening fluid (STF) containing silica particles. These two materials showed quite different failure modes macroscopically in ballistic impacts tests used by Cal.22 FSP and 9mm FMJ bullet. Yarn pull-out for the neat Kevlar woven fabric and yarn fracture occurred partially through all plies from 1st ply to last one for the STF-Kevlar are an important energy absorption mechanisms. The results observed by S.E.M showed commonly fiber damage which are torn skin in the longitudinal fiber direction, fiber split axially and fiber fracture for two materials. The reasons why STF-kevlar liquid armor material exhibits excellent ballistic performance are as follow: firstly the increased friction forces between yarn-yarn and fabric-fabric covered with silica particles and secondary the evolution of shear thickening phenomenmon resulting in suppression of yarn mobility.

Ballistic Resistance Performance of Kevlar Fabric Impregnated with Shear Thickening Fluid (전단농화유체가 함침된 Kevlar 재료의 방탄특성)

  • Song, Heung-Sub;Yoon, Byung-Il;Kim, Chang-Yun;Park, Jong-Lyul;Kang, Tae-Tin
    • Composites Research
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    • v.20 no.3
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    • pp.1-7
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    • 2007
  • Manufacturing process of the shear thickening fluid(STF) and evaluation of the ballistic penetration resistance performance of the Kevlar-STF composites were studied. STF was made from silica and ethylene glycol, and the Kevlar-STF composite was made by impregnating the STF into the Kevlar fabric. Specimens including neat Kevlar woven fabrics and Kevlar-STF composites with two types of silica were prepared and carried out the ballistic tests. From the results STFs represented shear thickening behavior irrespective of the silica type, and Kevlar-STF composite with spherical silica showed best ballistic penetration resistance performance among them. Especially the specimens of Kevlar-STF composites with spherical silica showed radial fiber deformation by the projectile during the tests, that was somewhat different deformation behavior from those of the neat Kevlar fabrics shown fiber pull-out phenomena or fracture.

THE AGING EFFECT Of K3B/IM7 IN $80^{\circ}C$ WATER

  • Kim Hyungwon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • v.y2005m4
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    • pp.31-34
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    • 2005
  • Hygrothermal aging of the laminates of $Avimid^{R}$ K3B/IM7 in $80^{\circ}C$ water was studied as a function of immersion time prior to forming microcracks. The factors causing the $80^{\circ}C$ water to degradation of the laminates could be the degradation of the matrix toughness, change in residual stresses or interfacial damage between the fiber and matrix. The times to saturation in $80^{\circ}C$ water for the laminates and the neat resin are 100 hours and 500 hours. After 500 hours aging of the neat resin in $80^{\circ}C$ water, the glass transition temperature was changed less than $1\%$ by DSC test and the weight gain was $1.55\%$ increase. After 500 hours aging, the fracture toughness of the neat resin was decreased about $37\%$ by 3-point bending test. After 100 hours aging of the [+45/0/-45/90]s K3B/IM7 laminates in $80^{\circ}C$ water, the weight gain was $0.41\%$ increase. The $80^{\circ}C$ water diffusion rate into the neat resin was faster than into the laminates. In 100 hours, the loss of the microcracking toughness of the laminates was $28\%$ of the original toughness by our own microcracking fracture toughness criterion.

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