• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3641-3648
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• 2013

Energy transfer and bond dissociation of $C-H_{methyl}$ and $C-H_{ring}$ in excited toluene in the collision with $H_2$ and $D_2$ have been studied by use of classical trajectory procedures at 300 K. Energy lost by the vibrationally excited toluene to the ground-state $H_2/D_2$ is not large, but the amount increases with increasing vibrational excitation from 5000 and $40,000cm^{-1}$. The principal energy transfer pathway is vibration to translation (V-T) in both systems. The vibration to vibration (V-V) step is important in toluene + $D_2$, but plays a minor role in toluene + $H_2$. When the incident molecule is also vibrationally excited, toluene loses energy to $D_2$, whereas it gains energy from $H_2$ instead. The overall extent of energy loss is greater in toluene + $D_2$ than that in toluene + $H_2$. The different efficiency of the energy transfer pathways in two collisions is mainly due to the near-resonant condition between $D_2$ and C-H vibrations. Collision-induced dissociation of $C-H_{methyl}$ and $C-H_{ring}$ bonds occurs when highly excited toluene ($55,000-70,400cm^{-1}$) interacts with the ground-state $H_2/D_2$. Dissociation probabilities are low ($10^{-5}{\sim}10^{-2}$) but increase exponentially with rising vibrational excitation. Intramolecular energy flow between the excited C-H bonds occurring on a subpicosecond timescale is responsible for the bond dissociation.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2002.10a
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• pp.81-84
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• 2002

The Sea dike tidal closure works has traditionally ended in the failure. Therefore, the success of the tidal closure in Hwaong in the sea near Inchon where has the greatest tidal gap in our country deserves to consider its meaning. While its process was going on, we had the difficulty like bad weather, unexpected ground settlement, flow velocity beyond the imagine, etc. Moreover, environment group's rush was so fierce that the works could have been delayed. This works showed that not only technical aspects but also social problems(environment group's rush and public discontents) were important factors in accomplishing the works. Finally, all of the difficulties were overcome and the tidal closure works were successful. So, This success is the best example in a kind of the another works in itself.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.09a
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• pp.203-206
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• 2004

To analysis the electrokinetic phenomena in the ground dependent on the way of applied electric power, such as constant current and constant voltage, the governing equations are derived considering advection, diffusion, ionmigration, and then they were formulated using by finite difference method. The developed program is verified by comparing the tested and predicted results reported in present papers. The results indicate that the slightly small electrical potential is predicted for constant current and for constant voltage pH near to the cathode was small than the test results. But the other predictions including the final suction, pH of electrolyte and cumulative flow are similar to the test results and predictions.

• Proceedings of the Korean Geotechical Society Conference
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• 2008.10a
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• pp.1063-1068
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• 2008

When construction of high pressure jet-grouting is to be performed, it has been reported that applied cement slurry which hasn't got dried out can cause severe environmental pollution, and can flow into near streams and fish farms. Several laboratory tests were performed in this study in order to verify safety of paste-like grouting material that was developed newly to be applied to void in the ground. According to experimental test results, it is proved to be so safe that application of the newly developed flowable grouting material can prevent the materials from spilling into surrounding areas and is not harmful to fishes.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2007.11a
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• pp.1476-1481
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• 2007

Numerical investigation on radiation characteristics of discrete frequency noise from asymmetry aero-intakes was carried out. The near-field predictions were obtained by solving the linearized Euler equations with computational aeroacoustic techniques consisting of high order finite difference scheme, non-reflecting boundary conditions, oversetgrid techniques. For the prediction of far-field directivity pattern, the Kirchhoff integral method was applied. By comparing the directivities of noise radiating from the scarf and the scoop aero-intakes with that from an axisymmetric aero-intake, it is shown that noise reduction at downward peak radiation angle can be achieved. The scattering of the radiating acoustic wave by background mean flow shifts the peak lobe radiation angle toward ground and increases the amplitude of the acoustic pressure compared with the cases without mean flow effect.

• The Journal of Engineering Geology
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• v.12 no.1
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• pp.75-88
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• 2002

When unsymmetrical surcharge is worked on polluted soft soils, large plastic shearing deformation such as settlements, lateral displacement, upheavals and shearing failure occured in the soils and they have often done considerable damages to the soils and structures. Accordingly, this study conducts laboratory pilots test to investigate the determination method of lateral flow pressure of polluted soft soils by comparing it to existing equations. The model test is performed that a model stock device is made and polluted soils are filled in a container which fires the soils. Then the displacement is observed as surcharge load is increased by regular intervals at untrained condition. The result shows that test the lateral flow pressure is adequately calculated by the equation (P=K$_{0}$YH) and the maximum value of lateral flow pressure Is found near 0.3H of layer thickness(H) and is higher to ground surface than synthesis pattern, Poulos distribution pattern and soft clay soils(CL, CH) which is not polluted.

• Journal of Advanced Marine Engineering and Technology
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• v.36 no.8
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• pp.1091-1096
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• 2012

The aerodynamic characteristics of circular cylinder in a channel are studied to make clear the flow feature by solving the Navier-Stokes equation based on the finite volume method with unstructured grids. Reviews are made on with the vorticity, velocity, dynamic pressure, residual and drag, where the Reynolds numbers are 50 and 100. The flows for $Re{\succeq}50$ shows the vortex shedding in the wake, and the result is the same as the case of moving cylinder. The ground effect of flat bottom results in the growth of vortex, being generated in the upper side of the cylinder and elongated in the rear. As the cylinder approaches to wall, for example 0.6, the cylinder plays as a role of blockage to obstruct the flow between the cylinder and wall. The drag coefficients are compared with others' results to confirm the validity of the present numerical simulation.

• Asian Journal of Atmospheric Environment
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• v.2 no.1
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• pp.1-13
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• 2008

A numerical simulation method has been developed to predict atmospheric flow and stack gas diffusion using a calculation domain of several km around a stack under complex terrain conditions containing buildings. The turbulence closure technique using a modified k-$\varepsilon$-type model under a non hydrostatic assumption was used for the flow calculation, and some of the calculation grids near the ground were treated as buildings using a terrain-following coordinate system. Stack gas diffusion was predicted using the Lagrangian particle model, that is, the stack gas was represented by the trajectories of released particles. The numerical model was applied separately to the flow and stack gas diffusion around a cubical building and to a two-dimensional ridge in this study, before being applied to an actual terrain containing buildings in our next study. The calculated flow and stack gas diffusion results were compared with those obtained by wind tunnel experiments, and the features of flow and stack gas diffusion, such as the increase in turbulent kinetic energy and the plume spreads of the stack gas behind the building and ridge, were reproduced by both calculations and wind tunnel experiments. Furthermore, the calculated profiles of the mean velocity, turbulent kinetic energy and concentration of the stack gas around the cubical building and the ridge showed good agreement with those of wind tunnel experiments.

• Journal of Korean Tunnelling and Underground Space Association
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• v.18 no.2
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• pp.143-154
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• 2016

This study investigated the occurrences, causes, and mitigation of the recent ground subsidence and underground cavity generation events in Korea. Two main causes of ground subsidence are (1) the soil erosion by seepage during tunneling and earth excavation and (2) the damage of underground pipes. The main cause of the soil erosion during tunneling was the uncontrolled groundwater flow. Especially, when excavating soft grounds using a tunnel boring machine (TBM), the ground near TBM operation halt points were found to be the most vulnerable to failure. The damage of underground pipes was mainly caused by poor construction, material deterioration, and differential settlement in soft soils. The ground subsidence during tunneling and earth excavation can be managed by monitoring the outflow of groundwater and eroded soils in construction sites. It is expected that the ground subsidence by the underground pipe damage can be managed or mitigated by life cycle analysis and maintenance of the buried pipes, and by controlling the earth pressure distribution or increasing the bearing capacity at the upper ground of the buried pipes.

• The Journal of Engineering Geology
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• v.11 no.2
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• pp.175-190
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• 2001

This study investigates the existing theoretical backgrounds in order to examine the behavior of lateral flow according to the plasticity of soils when unsymmetrical surcharge is worked on polluted soft soils by comparing and analyzing the results measured through model tests. Model tests are canied out as follows soil tank, bearing frame and bearing plate are made. By increasing unsymmetrical surcharge to the ground soils with the consistent water content and with gradually increased polluted materials at intervals, the amounts of settlement, lateral displacement and upheaval were respectively observed. In conclusion, the value of critical surcharge was expressed as q$_{cr}$=2.78$_{cu}$ which was similar to those Tschebotarioff(q$_{cr}$=3.0$_{cu}$) and Meyerhof(q$_{cr}$=(B/2H+$\pi$/2)$_{cu}$) had been proposed. The value of ultimate capacity was expressed as q$_{ult}$=4.84$_{cu}$ which was similar to that of Prandtl. The lateral flow pressure is adeQuately calculated by the eQuation(P$_{max}$=K$_o$ r H) and the maximum value of lateral flow pressure is found near O.3H of layer thickness(H) and is higher to ground surface than the ones in composition pattern, Poulos distribution pattern and softclay soils (CL, CH) which is not polluted. The stability control method used in this research followed the management diagram of Tominaga.Hashimoto, Shibata.Sekiguchi, Matsuo.Kawamura who use the amounts of plasticity displacement by lateral flow. As a result, the ultimate capacity values in the diagram {S$_v$-(Y$_m$/S$_v$)} of Matsuo.Kawamura and in the diagram {(q/Y$_m$)-q} of Shibata. Sekiguchi were smaller than in the ones of load-settlement curve (q-S$_v$).