• Title/Summary/Keyword: natural materials

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Synthesis of Heterocyclic Chalcone Derivatives and Their Radical Scavenging Ability Toward 2,2-Diphenyl-1-Picrylhydrazyl (DPPH) Free Radicals

  • Hwang, Ki-Jun;Kim, Ho-Seok;Han, In-Cheol;Kim, Beom-Tae
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2585-2591
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    • 2012
  • A series of heterocyclic chalcone derivatives bearing heterocycles such as thiophene or furan ring as an isostere of benzene ring were carefully prepared, and the influence of heterocycles on 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging activities was systematically investigated. Structure-activity relationships (SAR) analysis showed that the activities of thiophene ring-containing chalcones were higher than those of furan ring-containing chalcones, and the presence of methyl substituent of heterocyclic ring distinctly affected the activities compared with non-substituted heterocycles in an opposite manner, with the 4'-methyl group of thiophene ring increasing activity and the 3'-methyl group of the furan ring decreasing activity. The distinct isosteric effect of heterocycles (i.e., thiophene or furan ring) on radical scavenging activities of heterocyclic chalones was distinctly demonstrated in our work.

Development of Modified Selective Media to Differentiate Cryptococcus Species Complex and its Serotypes using Natural Materials

  • Park, Gyu-Nam;Kim, Hye-Ran;An, Dong-Jun;Chae, Hee-Sun;Chang, Kyung-Soo
    • Biomedical Science Letters
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    • v.23 no.2
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    • pp.64-72
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    • 2017
  • The formation of brown colonies due to phenol oxidase activity on classic agar media containing natural material extracts of Helianthus annuus or on medium containing L-3,4-dihydroxyphenylalanine has been used to identify Cryptococcus species complex. In this study, various natural materials were used to develop a modified medium and to identify five major serotypes of Cryptococcus species complex. Serotypes A, D, and A/D were pigmented on medium using Perilla frutescens var. japonica Hara (PerJ agar) after a three-day incubation. Serotypes B and C were pigmented on PerJ agar after four- and five-day incubations, respectively. Growth time and pigmentation of the five serotypes occurred more rapidly on PerJ agar than on the other media. In addition, colony morphology, size, and pigmentation were specific by serotype. In conclusion, PerJ agar should be used in clinic settings to identify Cryptococcus species complex and its serotypes rapidly.

Manufacturing Regenerated Woody Dyed Fiber from Waste MDF Using Natural Dyes

  • JU, Seon-Gyeong;ROH, JeongKwan
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.2
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    • pp.154-165
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    • 2020
  • To assign the functionality of the regenerated fiber from waste MDF(wMDF) made of pitch pine, we examined the dyeing characteristics of natural dyes, sappan wood as a polychromatic natural red series, monochromatic gardenia as a yellow series, and indigo blue series. For nonemordanting dye, the colors of regenerated fiber dyed by sappan wood and gardenia were reddish yellow (YR) and yellow (Y) series, respectively, and dyeing conditions were appropriate a 30 ~ 50 g/L of dyeing materials at 60 ℃ for 60minutes of dyeing time. We obtained regenerated woody dyed fibers (Re-WDF), YR to the red (R) series by premordanting with Al and Cu mordant for sappan wood and the purplish red (RP) series by Fe premordanting. In the case of gardenia, only Y series colors were developed in nonemordanting dye or all three mordants. Indigo dye produced Re-WDF with greenish yellow (GY) tone at 1%, green (G) tone at 3%, and blue (B) tone at 5% concentration or more. Re-WDF with indigo showed the best light fastness followed by sappan wood and gardenia. In particular, the light fastness of Re-WDF with gardenia was very poor. The light fastness was somewhat improved by premordanting(Fe>Cu>Al) both sappan wood and gardenia dyes.

Theoretical Studies on 2-Hexylthieno[3,2-b]thiophene End-Capped Oligomers for Organic Semiconductor Materials

  • Park, Young-Hee;Kim, Yun-Hi;Kwon, Soon-Ki;Koo, In-Sun;Yang, Ki-Yull
    • Bulletin of the Korean Chemical Society
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    • v.33 no.4
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    • pp.1213-1219
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    • 2012
  • The reorganization energy and the spectroscopic properties of 2,6-bis(5'-hexyl-thieno[3,2-b]thiophene-2'- yl)naphthalene (DH-TNT) and 2,6-bis(5'-hexyl-thieno[3,2-b]thiophene-2'-yl)anthracene (DH-TAT), which are composed of an acene unit and alkylated thienothiophene on both sides, as organic materials for display devices were calculated and the results were compared with experimental values. The lower reorganization energy of the DH-TAT over the DH-TNT calculated by the density functional theory is attributed to a smaller vibrational distortion because of the heavier building block of DH-TAT, and it shows a good field effect performance over the DH-TNT. The calculated spectra and the other spectroscopic characteristic of the compounds are well consistent with those of observed results.

Abatement of Methane Production from Ruminants: Trends in the Manipulation of Rumen Fermentation

  • Kobayashi, Yasuo
    • Asian-Australasian Journal of Animal Sciences
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    • v.23 no.3
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    • pp.410-416
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    • 2010
  • Methane emitted from ruminant livestock is regarded as a loss of feed energy and also a contributor to global warming. Methane is synthesized in the rumen as one of the hydrogen sink products that are unavoidable for efficient succession of anaerobic microbial fermentation. Various attempts have been made to reduce methane emission, mainly through rumen microbial manipulation, by the use of agents including chemicals, antibiotics and natural products such as oils, fatty acids and plant extracts. A newer approach is the development of vaccines against methanogenic bacteria. While ionophore antibiotics have been widely used due to their efficacy and affordable prices, the use of alternative natural materials is becoming more attractive due to health concerns regarding antibiotics. An important feature of a natural material that constitutes a possible alternative methane inhibitor is that the material does not reduce feed intake or digestibility but does enhance propionate that is the major hydrogen sink alternative to methane. Some implications of these approaches, as well as an introduction to antibiotic-alternative natural materials and novel approaches, are provided.

Small group velocity in two dimensional photonic crystal line defect (2 차원 광결정 선결함의 낮은 군속도)

  • Lee, Myotmg-Rae;Hong, Chin-Soo;Kim, Kyoung-Rae;Shin, Won-Chin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.04a
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    • pp.49-51
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    • 2009
  • Photonic crystal is a dielectric materials or a set of different dielectric materials with periodic structure of refractive index. Line defect obtained by leaving out a row of rod along the $\Gamma$-X direction. We showed the change of group velocity in waveguide mode and found a small group velocity. Characteristic of the small group velocity described by electric field distribution. As the phase variation, small group velocity confirmed from positive to negative.

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Skin Permeation Characteristics of Antihyperlipoproteinemic Agent using Natural Polymer Bases in Rats (천연고분자 기재에 의한 수용성 항고지단백혈증제의 흰쥐 피부투과 특성)

  • Kong, Seung-Dae;Hwang, Sung-Kwy;Jung, Duck-Chae
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.2
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    • pp.126-131
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    • 2000
  • Transdermal therapeutic system(TTS) is often used as the method of drug dosage into the epidermic skin. Natural polymer were selected as ointment material of TTS. We investigated the permeation of natural polymer ointment containing drug in rat skin using horizontal membrane cell model. Permeation properties of materials were investigated for water-soluble drug such as oxiniacic acid in vitro. These results showed that skin permeation rate of drug across the composite was mainly dependent on the property of ointment base and drug. Proper selection of the polymeric materials which resemble and enhance properties of the delivering drug was found to be important in controlling the skin permeation rate. This result suggests a possible use of natural polymer ointment base as TTS of antihyperlipoproteinemic agent.

Behaviour of self compacting repair mortars based on natural pozzolana in hot climate

  • Benyahia, A.;Ghrici, M.
    • Advances in concrete construction
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    • v.6 no.3
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    • pp.285-296
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    • 2018
  • In the present paper, the results of an experimental study of the bond between repair materials and mortar substrate subjected to hot climate is presented. Half-prisms of size $40{\times}40{\times}80mm$, serving as a substrate mortar samples (SUBM) were manufactured in the laboratory and then stored at an ambient temperature for 6 months. Five self compacting mortar mixes (SCMs) incorporating 0%, 10%, 20%, 30%, and 40% of natural pozzolana as white cement replacement were used as repair materials. Repaired composite samples (SCMs/SUBM) were cured at hot climate for different lengths of time (28 and 56-days). During the first week of curing, the composite samples were watered twice a day. The test carried out to assess the bond between SCMs and SUBM was based on three-point bending (3 PB) test. The obtained results have proved that it was feasible to produce compatible repair materals in this curing environment by using up to 30% natural pozzolana as white cement replacement.

Characteristics of Blue Costumes in Contemporary Fashion (현대패션에 나타난 블루의상의 특성)

  • Kim, Sun-Young
    • Journal of the Korean Home Economics Association
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    • v.49 no.8
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    • pp.13-24
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    • 2011
  • This paper purports to find the characteristics of blue costumes as expressed in modern fashion. As such, we made an empirical analysis, using 436 works from 2006 S/S through 2010 F/W collections. Result indicated that modernness was emphasized by applying a minimum expressive technique to items of a simple form, and an image of simplicity was emphasized by placing focus on the rational color image of blue. Second, images of blue, such as trust, stability, and success were expressed as refined elegance through the combination of tight silhouettes, glossy and translucent materials, and indirect exposure. Third, natural image was expressed through natural silhouettes, soft or natural materials, gradation of various tones, and natural motif decorations as well as the color itself. Fourth, dynamic image was expressed by introducing fashion items, mostly worn by men only, to simple and tight forms or through the inspiration of a masculine fashion image. Fifth, abstinent image was expressed by using an image of religious apparel or symbols, covering up the body, minimizing details, and using a dark blue tone.