• Title/Summary/Keyword: natural emission

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Methane Gas Emission from an Artificial Reservoir under Asian Monsoon Climate Conditions, with a Focus on the Ebullition Pathway (아시아 몬순 기후지역에 위치한 대형 인공호에서 기포형태로의 메탄 (CH4) 가스 배출량)

  • Kim, Kiyong;Jung, Sungmin;Choi, Youngsoon;Peiffer, Stefan;Knorr, Klaus-Holger;Kim, Bomchul
    • Korean Journal of Ecology and Environment
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    • v.51 no.2
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    • pp.160-167
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    • 2018
  • The role played by reservoirs in the biogeochemical cycles of elements is a subject of ongoing debate. Recent research has revealed that reservoirs emit significant levels of greenhouse gases. To assess the importance of reservoirs in monsoon climate areas as a source of methane gas into the atmosphere, we investigated variations in organic carbon (OC) input into the reservoir, oxic state changes, and finally the amount of methane emitted (focusing on the ebullition pathway) in Lake Soyang, which is the largest reservoir in South Korea. Total organic carbon (TOC) concentrations were higher during summer after two years of heavy rainfall. The sedimentation rates of particulate organic carbon (POC) and particulate organic nitrogen (PON) were higher in the epilimnion and hypolimnion than the metalimnioin, indicating that autochthonous and allochthonous carbon made separate contributions to the TOC. During stratification, oxygen depletion occurred in the hypolimnion due to the decomposition of organic matter. Under these conditions, $H_2S$ and $CH_4$ can be released from sediment. The methane emissions from the reservoir were much higher than from other natural lakes. However, the temporal and spatial variations of methane ebullition were huge, and were clearly dependent on many factors. Therefore, more research via a well-organized field campaign is needed to investigate methane emissions.

Development of Primary Standard Gas Mixtures for Monitoring Monoterpenes (α-pinene, 3-carene, R-(+)-limonene, 1,8-cineole) Ambient Levels (at 2 nmol/mol) (대기 중 모노테르펜 (α-피넨, 3-카렌, R-리모넨, 1,8-시네올) 측정을 위한 혼합표준가스개발)

  • Kang, Ji Hwan;Kim, Mi Eon;Kim, Young Doo;Rhee, Young Woo;Lee, Sangil
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.3
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    • pp.320-328
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    • 2016
  • Among biogenic volatile organic compounds (BVOCs) in the natural ecosystem, monoterpenes, along with isoprene, play important roles in atmospheric chemistry and make significant impacts on air pollution and climate change, especially due to their contribution to secondary organic aerosol production and photochemical ozone formation. It is essential to measure monoterpene concentrations accurately for understanding their oxidation processes, emission processes and estimation, and interactions between biosphere and atmosphere. Thus, traceable calibration standards are crucial for the accurate measurement of monoterpenes at ambient levels. However, there are limited information about developing calibrations standards for monoterpenes in pressured cylinders. This study describes about developing primary standard gas mixtures (PSMs) for monoterpenes at about 2 nmol/mol, near ambient levels. The micro-gravimetric method was applied to prepare monoterpene (${\alpha}$-pinene, 3-carene, R-(+)-limonene, 1,8-cineole) PSMs at $10{\mu}mol/mol$ and then the PSMs were further diluted to 2 nmol/mol level. To select an optimal cylinder for the development of monoterpene PSMs, three different kinds of cylinders were used for the preparation and were evaluated for uncertainty sources including long-term stability. Results showed that aluminum cylinders with a special internal surface treatment (Experis) had little adsorption loss on the cylinder internal surface and good long-term stability compared to two other cylinder types with no treatment and a special treatment (Aculife). Results from uncertainty estimation suggested that monoterpene PSMs can be prepared in pressured cylinders with a special treatment (Experis) at 2 nmol/mol level with an uncertainty of less than 4%.

Development of the Catalytic Combustion Condensing Boiler of Lower Emission Type for Domestic Use (저공해형 촉매연소식 소형 콘덴싱보일러 개발)

  • Kim Hoyeon;Lee Seungho;Cho Wonihl;Baek Youngsoon
    • Journal of the Korean Institute of Gas
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    • v.5 no.1
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    • pp.45-51
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    • 2001
  • Catalytic combustion is the environmental-friendly technology, which has been applied to a variety of areas for industrial and domestic use in recent years. Accordingly, this study performed the development of the catalytic manufacturing technology for the high temperature and of the catalytic combustor in priority, which were aimed to be aimed to a commercialized condensing boiler. Palladium(Pd) of a noble meta] was used as a catalyst for the high temperature and supported on $alumina(Al_{2}O_{3})\;and\;zirconia(ZrO_2)$ in constant weight ratio. Activity of Pd catalysts is compared and analysed in the catalytic combustion of natural gas. The ratio of $Pd/Al_{2}O_{3}\;=\;4$ was found to be better than any other weight ratios in activity and durability. The performance examination of catalysts and of combustion through the plate-type combustor made it possible to be developed the cylindrical-type combustor which has increased combustion area. Catalytic combustion condensing boiler of 25,000 kcal/hr class was also developed, which had the optimum combustion condition at the no221e of 5.95mm and the orifice of 21mm. This condition was determined through the performance experiments of catalytic combustion condensing boiler to which the cylindrical-type catalytic combustor was applied.

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Parameter Optimization and Automation of the FLEXPART Lagrangian Particle Dispersion Model for Atmospheric Back-trajectory Analysis (공기괴 역궤적 분석을 위한 FLEXPART Lagrangian Particle Dispersion 모델의 최적화 및 자동화)

  • Kim, Jooil;Park, Sunyoung;Park, Mi-Kyung;Li, Shanlan;Kim, Jae-Yeon;Jo, Chun Ok;Kim, Ji-Yoon;Kim, Kyung-Ryul
    • Atmosphere
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    • v.23 no.1
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    • pp.93-102
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    • 2013
  • Atmospheric transport pathway of an air mass is an important constraint controlling the chemical properties of the air mass observed at a designated location. Such information could be utilized for understanding observed temporal variabilities in atmospheric concentrations of long-lived chemical compounds, of which sinks and/or sources are related particularly with natural and/or anthropogenic processes in the surface, and as well as for performing inversions to constrain the fluxes of such compounds. The Lagrangian particle dispersion model FLEXPART provides a useful tool for estimating detailed particle dispersion during atmospheric transport, a significant improvement over traditional "single-line" trajectory models that have been widely used. However, those without a modeling background seeking to create simple back-trajectory maps may find it challenging to optimize FLEXPART for their needs. In this study, we explain how to set up, operate, and optimize FLEXPART for back-trajectory analysis, and also provide automatization programs based on the open-source R language. Discussions include setting up an "AVAILABLE" file (directory of input meteorological fields stored on the computer), creating C-shell scripts for initiating FLEXPART runs and storing the output in directories designated by date, as wells as processing the FLEXPART output to create figures for a back-trajectory "footprint" (potential emission sensitivity within the boundary layer). Step by step instructions are explained for an example case of calculating back trajectories derived for Anmyeon-do, Korea for January 2011. One application is also demonstrated in interpreting observed variabilities in atmospheric $CO_2$ concentration at Anmyeon-do during this period. Back-trajectory modeling information introduced in this study should facilitate the creation and automation of most common back-trajectory calculation needs in atmospheric research.

Situation and Composting Probability of Livestock Manure Generated from Kangwon-do (강원도내 가축분뇨의 오염현황 및 퇴비화 가능성 검토)

  • Kim, Joung-Dae;Park, Joon-Seok
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.1
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    • pp.75-86
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    • 2002
  • This study was performed to investigate situation of livestock manure generated from Kangwon-do and to evaluate its composting probability. The scale of livesrock-farming is bigger and bigger in Korea. Regulation based on the heads of livestock is slightly different from that based on livestock-farming household. So it is needed ro evaluate regulations for livestock head and livestock-farming household. Composting and liquid fertilization were thought to be appropriate technologies to the trearment of Korean cattle and pig manures, respectively. Generation quantity of pig manure was the greatest among pig, Korean cattle, cow and chicken manures. Pig manure generated the greatest amounts of BOD in Kangwon-do. Pig manure contained nitrogen, Korean cattle manure contained $K_2O$, and chicken and pig manures contained $P_2O_5$ in great amount. Alternative ratio of livestock manure to crops-fertilizer was 51% for nitrogen, 38% for $K_2O$, and 34% for $P_2O_5$.

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Sustainable Design Method of Reinforced Concrete Beam Using Embodied Energy Optimization Technique (내재에너지 최적화를 통한 철근 콘크리트 보의 지속가능 설계법)

  • Yoon, Young-Cheol;Kim, Kyeong-Hwan;Yeo, DongHun;Lee, Sang-Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.4
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    • pp.1053-1063
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    • 2014
  • This study presents a sustainable design method that optimizes the embodied energy of concrete beam based on the concept of sustainable development that effectively utilizes natural resource and energy within the range that our succeeding generation can afford to utilize. In order to get the flexural strength carrying the ultimate load, concrete beam sections are designed by optimization that consists of the embodied energy as a objective function and the requirements of design code as constrained conditions. The sustainable design can be used to minimize the embodied energy consumed in material production, construction, operation, demolition of the infrastructure. As a result of comparison of the cost and the embodied energy optimizations based on practical beam sections, it is shown that 20% embodied energy saving and 35% $CO_2$ emission saving are achieved by sacrificing 10% cost increase. The sustainable design method provides a new effective methodology that manages the strength design concept based on cost minimization together with economic feasibility and sustainability. In addition, the method is expected to be applied to more various structural design practices.

Improvement of Calcium Phosphate Forming Ability of Titanium Implant by Thermal Oxidation Method (열산화법에 의한 티타늄 임플란트의 인산칼슘 결정의 형성 능력 증진)

  • Hwang, Kyu-Seog;An, Jun-Hyung;Lee, Seon-Ok;Yun, Yeon-Hum;Kang, Bo-An;Oh, Jeong-Sun;Kim, Sang-Bok
    • Journal of the Korean Ceramic Society
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    • v.39 no.5
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    • pp.460-466
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    • 2002
  • Titanium oxide film was deposited on the commercially pure titanium (cp-Ti) by thermal oxidation method for its medical application. The cp-Ti disks were cleaned and then heat-treated at the temperatures of 500, 550, 600, 650, and 700${\circ}C$, respectively, for 10 min in air or Ar. To test the ability of calcium phosphate formation, the specimens were immersed in the Eagle's minimum essential medium solution at 36.5${\circ}C$ for 15 days. The morphology and chemical composition of the surfaces before and after soaking were analyzed by using FE-SEM and EDS. The in-vitro formation of carbonated calcium phosphate on the thin films containing nano-sized $TiO_2$ crystals was identified.

Reliability Analysis Method for Concrete Containment Structures (콘크리트 차폐(遮蔽) 구조물(構造物)의 신뢰성(信賴性) 해석방법(解析方法))

  • Han, Bong Koo;Chang, Sung Pil
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.10 no.1
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    • pp.9-16
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    • 1990
  • The safety of concrete nuclear containment structures should be secured against all kinds of loading due to various natural disasters or extraordinary accidental loads. The current design criteria of concrete containment structures are not based on the reliabillty-based design concept but rely on the conventional design concept. In this paper, a probabillty-based reliability analysis were proposed based on a FEM-based random vibration analysis and serviceability limit state of structures. The limit state model defined for the study is a serviceability limit state in terms of the more realistic crack failure that might cause the emission of radioactive materials, and the results are compared with those of the strength limit state. More accurate reliability analyses under various dynamic loads such as earthquake loads were made possible by incorporation the FEM and random vibration theory, which is different from the conventional reliability analysis method. The uncertainties in loads and resistance available in Korea and the refernces were adapted to the situation of Korea, and especially in the case of earthquake, the design earthquake was assessed based on the available re ports on probabilistic description of earthquake ground acceleration in the Korea peninsula.

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Intensive Monitoring Survey of Nearby Galaxies: Current Status

  • Im, Myungshin;Choi, Changsu;Lim, Gu;Kim, Sophia;Paek, Seunghak Gregory;Kim, Joonho;Hwang, Sungyong;Shin, Suhyung;Baek, Insu;Lee, Sangyun;O, Sung A;Yoon, Sung Chul;Sung, Hyun-Il;Jeon, Yeong-Beaom;Lee, Sang Gak;Kang, Wonseok;Kim, Tae-Woo;Kwon, Sun-gil;Pak, Soojong;Eghamberdiev, Shuhrat
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.1
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    • pp.64.1-64.1
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    • 2018
  • SNe light curves have been used to understand the expansion history of the universe, and a lot of efforts have gone into understanding the overall shape of the radioactively powered light curve. However, we still have little direct observational evidence for the theorized SN progenitor systems. Recent studies suggest that the light curve of a supernova shortly after its explosion (< 1 day) contains valuable information about its progenitor system and can be used to set a limit on the progenitor size, R*. In order to catch the early light curve of SNe explosion and understand SNe progenitors, we are performing a ~8hr interval monitoring survey of nearby galaxies (d < 50 Mpc) with 1-m class telescopes around the world. Through this survey, we expect to catch the very early precursor emission as faint as R=21 mag (~0.1 Rsun for the progenitor). In this poster, we outline this project, and present a few scientific highlights, such as the early light curve of SN 2015F in NGC 2442.

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Some Prophylactic Options to Mitigate Methane Emi ssion from Animal Agriculture in Japan

  • Takahashi, Junichi
    • Asian-Australasian Journal of Animal Sciences
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    • v.24 no.2
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    • pp.285-294
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    • 2011
  • The abatement of methane emission from ruminants is an important global issue due to its contribution to greenhouse gas with carbon dioxide. Methane is generated in the rumen by methanogens (archaea) that utilize metabolic hydrogen ($H_2$) to reduce carbon dioxide, and is a significant electron sink in the rumen ecosystem. Therefore, the competition for hydrogen used for methanogenesis with alternative reductions of rumen microbes should be an effective option to reduce rumen methanogenesis. Some methanogens parasitically survive on the surface of ciliate protozoa, so that defaunation or decrease in protozoa number might contribute to abate methanogenesis. The most important issue for mitigation of rumen methanogenesis with manipulators is to secure safety for animals and their products and the environment. In this respect, prophylactic effects of probiotics, prebiotics and miscellaneous compounds to mitigate rumen methanogenesis have been developed instead of antibiotics, ionophores such as monensin, and lasalocid in Japan. Nitrate suppresses rumen methanogenesis by its reducing reaction in the rumen. However, excess intake of nitrate causes intoxication due to nitrite accumulation, which induces methemoglobinemia. The nitrite accumulation is attributed to a relatively higher rate of nitrate reduction to nitrite than nitrite to ammonia via nitroxyl and hydroxylamine. The in vitro and in vivo trials have been conducted to clarify the prophylactic effects of L-cysteine, some strains of lactic acid bacteria and yeast and/or ${\beta}$1-4 galactooligosaccharide on nitrate-nitrite intoxication and methanogenesis. The administration of nitrate with ${\beta}$1-4 galacto-oligosaccharide, Candida kefyr, and Lactococcus lactis subsp. lactis were suggested to possibly control rumen methanogenesis and prevent nitrite formation in the rumen. For prebiotics, nisin which is a bacteriocin produced by Lactococcus lactis subsp. lactis has been demonstrated to abate rumen methanogenesis in the same manner as monensin. A protein resistant anti-microbe (PRA) has been isolated from Lactobacillus plantarum as a manipulator to mitigate rumen methanogenesis. Recently, hydrogen peroxide was identified as a part of the manipulating effect of PRA on rumen methanogenesis. The suppressing effects of secondary metabolites from plants such as saponin and tannin on rumen methanogenesis have been examined. Especially, yucca schidigera extract, sarsaponin (steroidal glycosides), can suppress rumen methanogenesis thereby improving protein utilization efficiency. The cashew nutshell liquid (CNSL), or cashew shell oil, which is a natural resin found in the honeycomb structure of the cashew nutshell has been found to mitigate rumen methanogenesis. In an attempt to seek manipulators in the section on methane belching from ruminants, the arrangement of an inventory of mitigation technologies available for the Clean Development Mechanism (CDM) and Joint Implementation (JI) in the Kyoto mechanism has been advancing to target ruminant livestock in Asian and Pacific regions.