• 제목/요약/키워드: natural cellulose

검색결과 266건 처리시간 0.034초

섬유종류와 염색조건에 따른 쪽 염색직물의 색채감성과 색채선호도 (Color Sensibility and Preferences for Cellulose Fabrics Dyed with Natural Indigo According to Fiber Type and Dyeing Condition)

  • 신주동;최종명
    • 감성과학
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    • 제20권3호
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    • pp.3-12
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    • 2017
  • 본 연구에서는 인체 친화적이고 환경 친화적인 패션제품 소재기획을 위한 기초 자료를 제시하고자 수행되었다. 이를 위해서 4종의 섬유소 소재를 대상으로 염색조건을 달리하여 천연 쪽 염색을 실시하여 색채특성과 색채감성을 평가하였으며, 이러한 특성이 선호도에 미치는 영향을 분석하였다. 쪽 염색된 직물은 모두 중, 저명도와 저채도의 남색(PB)을 구현하였다. 이들 직물의 색채특성은 섬유종류와 염색조건에 따라 유의한 차이를 보였다. 쪽 염색된 직물에 대한 색채감성은 스포티 감성, 클래식 감성, 내추럴 감성 등 3가지 요인으로 분류되었다. 이러한 색채감성은 섬유종류와 염색조건에 따라 부분적으로 유의한 차이를 나타내었다. 또한 쪽 염색 직물의 색채특성과 색채감성 요인 간에는 부분적으로 유의한 상관관계를 보였다. 쪽 염색 직물의 색채 선호도에 영향을 주는 요인으로는 색채감성 요인 중에서 클래식 감성과 스포티 감성, 색채특성에서는 $L^*$값인 것으로 나타났다.

African marigold(Tagetes erecta L.) 생화(生花) 추출물(抽出物) 염색(染色)에서 염욕(染浴)의 pH, 매염제(媒染劑,), Chitosan 처리(處理)가 섬유소섬유(纖維素纖維)의 염색성(染色性)에 미치는 영향(影響) (Effect of Dyeing Bath, Mordant and Chitosan Treatment on the Dyeing of Natural Cellulose Fiber Using African Marigold(Tagetes erecta L.) Petals Extract)

  • 김경선;전동원;김종준
    • 패션비즈니스
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    • 제11권1호
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    • pp.136-148
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    • 2007
  • African marigold is a common plant easily available in many flower beds. It has been reported as a practical and prospective resource of dyes since the dyes can be extracted from their bodies as well as petals. In this research, cotton and ramie fabrics which are made from natural cellulose were dyed using the extract of the African Marigold which is a variety of marigold. Dyeing tests were carried out under different pH of the dye solution and mordants. Dyeability was evaluated by examining and measuring surface color, K/S value, and the changes in the maximum absorption wavelength. The probability of improving dyeability was investigated by pre-mordanting with pre-treated chitosan. For the dyeing with marigold extract, the color tone did not differ by pre-mordanting and non-mordanting. Reaction with post-mordanting was excellent, which was colored in various yellow series. The best dyeability was achieved in dye solution of pH 6.5-7.0 which is not conditioned. The largest K/S value and color difference were obtained in tin mordanting. The dye uptake was greatly increased in chitosan pre-treated mordanting compared with the post-mordanting without chitosan pre-treatment. Due to its high heat resistance, African Marigold extract is easy for dye extraction and dyeing, and its dyeability is excellent for natural cellulose fibers. Also, colorfastness was proved to be practically usable.

Cellulose-based Nanocrystals: Sources and Applications via Agricultural Byproducts

  • Seo, Yu-Ri;Kim, Jin-Woo;Hoon, Seonwoo;Kim, Jangho;Chung, Jong Hoon;Lim, Ki-Taek
    • Journal of Biosystems Engineering
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    • 제43권1호
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    • pp.59-71
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    • 2018
  • Purpose: Cellulose nanocrystals (CNCs) are natural polymers that have been promoted as a next generation of new, sustainable materials. CNCs are invaluable as reinforcing materials for composites because they can impart improved mechanical, chemical, and thermal properties and they are biodegradable. The purpose of this review is to provide researchers with information that can assist in the application of CNCs extracted from waste agricultural byproducts (e.g. rice husks, corncobs, pineapple leaves). Methods & Results: This paper presents the unique characteristics of CNCs based on agricultural byproducts, and lists processing methods for manufacturing CNCs from agricultural byproducts. Various mechanical treatments (microfluidization and homogenization) and chemical treatments (alkali treatment, bleaching and hydrolysis) can be performed in order to generate nanocellulose. CNC-based composite properties and various applications are also discussed. Conclusions: CNC-based composites from agricultural byproducts can be combined to meet end-use applications such as sensors, batteries, films, food packaging, and 3D printing by utilizing their properties. The review discusses applications in food engineering, biological engineering, and cellulose-based hydrogels.

투과증발법에 의한 방사성폐액의 감용 (Volume Reduction of Radioactive Liquid Waste by Pervaporation Method)

  • 강영호;권선길;양영석;황성태;장인순
    • 공업화학
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    • 제3권2호
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    • pp.327-334
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    • 1992
  • 저준위 방사성 액체폐기물의 새로운 감용방법으로써 cellulose acetate막을 사용한 투과증발법의 연구가 수행되었다. 실험결과에 의하면 일반적으로 유기물의 분리에 사용되는 투과증발법은 액체폐기물의 감용을 위한 제염효과가 우수하였고, 수분의 증발속도도 저준위 방사성 액체폐기물의 감용을 위해 널리 사용되는 자연증발에 비해 현저히 빨랐다. 또한 주입용액의 조건에 따른 실험결과를 토대로 투과증발특성을 평가하였으며, 투과증발량을 증가시키기 위해 cellulose acetate막의 최적제막조건을 설정하였다.

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Cellulose Diacetate/Starch 복합체의 제조 및 물성 (Preparation and Properties of Celluose Diacetate/Starch Composite)

  • 이상율;이승경;임환규;계형산;이영관
    • 폴리머
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    • 제30권6호
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    • pp.532-537
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    • 2006
  • 최근 환경문제가 대두되면서 기존의 석유계 플라스틱을 대체할 생분해성 플라스틱에 관심이 고조되고 잇다. 이에 본 실험에서는 토양에서 생분해가 가능한 셀룰로오스 디아세테이트/전분 혼합체를 제조하여 그 특성을 연구하였다. 이 혼합체에 가소제로 트리아세틴을 첨가하여 용융가공한 복합체의 물성을 조사하였다. 전분의 함량이 증가할수록 이 복합체의 가공성이 향상되며 인장강도와 탄성률은 감소하고 신율은 증가하였다. 전분의 함량이 증가하면 복합체의 $T_g$는 감소하였다. SEM을 이용하여 전분의 복합체내에서의 분산성을 관찰하였다.

면직물의 쪽 천연염색에서 염색조건의 변화가 염색성에 미치는 영향 (A Study on the Effect of the Changes of Dyeing Conditions on the Dyeability of Cotton Fabrics dyed with Natural Polygoum tinctoria)

  • 김미경;전동원
    • 패션비즈니스
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    • 제15권4호
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    • pp.144-154
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    • 2011
  • Polygoum tinctoria dye is the one using the method of reducing dyeing, and so is made by the mechanism different from natural dye in general, and the reproductive dye is more difficult because it varies in accordance with manufacturing method and days being manufactured in case of natural indigo dye that has been used traditionally. In addition, overall analysis is short of color changes in accordance with natural dyeing condition and barely none of the research for cellulose system such as cotton in particular. Accordingly, this study tries to research on the natural dyeing method optimal for color development that is desirable in designing and development of natural dyeing as comparing and contemplating the change of dyeing quality and color in accordance with reduction temperature and time, reductant quantity, dyeing temperature and time, NaOH quantity, and dyeing repetition times in order to expand dyeing methods and use variously polygoum tinctoria by improving traditional dyeing methods as well as to establish exact dyeing method of cotton which is a fabric of cellulose system in order to make such polygoum tinctoria quantificated and reproductive. The optimum conditions in the dyeing procedure are as follows: Reducing temperature is $50^{\circ}C$. Added concentration of the reducing agent is $3g/{\ell}$. Reducing time is 30minutes. Dyeing temperature is $30^{\circ}C$. Added concentration of NaOH is $1g/{\ell}$. Dyeing time is 30minutes.

Dimethyl oxalate에 의한 barium titanyl oxalate의 균일 침전에 미치는 화학적 인자와 이들이 티탄산 바륨의 특성에 미치는 영향 (Chemical Factors on the Homogeneous Precipitation of Barium Titanyl Oxalate by Dimethyl Oxalate and Their Effects on the Charateristics of Barium Titanate)

  • 류경열;허우영;이철
    • 분석과학
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    • 제12권3호
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    • pp.230-234
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    • 1999
  • $Ba^{2+}$$Ti^{4+}$이 함유된 염산용액에서 dimethyl oxalate(DMO)가 열분해되면 barium titanyl oxalate(BTO)가 균일 생성되었다. 일정량의 hydroxy propyl cellulose(HPC)를 분산제로 사용하였고 120min의 숙성시간에서 생성된 BTO의 전 침전물을 회수하였다. 반응온도, 염화이온의 농도, $[DMO]_0/([Ba^{2+}]_0+[Ti^{4+}]_0)$의 초기 농도비, 그리고 가한 HPC가 BTO입자의 형태, 화학적 회수율, 그리고 그들의 선구물질로부터 형성된 티탄산 바륨의 특성에 영향을 미침을 알았다.

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beta-Galaetosidase의 고정화 및 응용에 관한 연구 제2보: Aspergillus niger CAD 1의 효소 교정화 조건 및 고정화 효소의 성질 (Studies on immobilization and application of beta-galactosidase II. Preparation and properties of the immobilized enzyme from Aspergillus niger CAD 1)

  • 이용규;전순배;최원기;정기철;배석;김관천
    • 한국식품영양과학회지
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    • 제15권4호
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    • pp.40-46
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    • 1986
  • 제1보에서 보고한 Aspergillus niger CAD 1의 beta-galactosidase를 cellulose triacetate를 담체로 하여 고정화조건을 검토하였던바, 13%(v/v)의 정제된 효소와 10%(w/v)의 cellulose triacetate를 30분간, 150stroke/min으로 진탕하면서 포괄시킨 고정화 효소의 활성이 가장 좋았다. 고정화 효소의 최적온도는 $45^{\circ}C$, 최적 pH는 4.5로서수용성 효소의 것과 같았다. 기질로서 ONPG와 유당에 대한 Km값은 각각 $8.3{\timess}10^{-3}$$117.0{\times}10^3M$, Vmax값은 각각 $30.3{\times}10^3M$$5.0{\times}10^3M$이였다. 본 고정화 효소는 $4^{\circ}C$에서 90일간 저장시에 90%, $45^{\circ}C$에서 5회 사용후에 70%의 잔존활성을 나타냈으며 유당분해율도 좋았다.

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천연염료의 복합염색에 관한 연구 - 셀룰로오즈계 섬유를 중심으로 - (A study of complex dyeing using natural dyestuffs - Focus on cellulose fiber -)

  • 김미경;김태미
    • 복식문화연구
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    • 제24권4호
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    • pp.431-440
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    • 2016
  • The purpose of this research is to revive the colors of combination dyeing and mixed dyeing with natural dyestuffs. The fabrics used were cotton and rayon. The natural dyestuffs used in this research were indigo, Phellodendron amurense, and Caesalpinia sappan. The effects of combination dyeing were as follows. First, all samples showed deeper colors. Second, according to the results of the surface K/S measurement, while the surface K/S of cotton was over 15, that of rayon was over 17. Third, the results of the light fastness measurement showed the superiority (by over grade 4) of all the samples, except in the case of rayon fiber sample no. 6 (which had been pre-dyed with indigo five times before being dyed with P. amurense once and then being dyed with C. sappan once). In the color fastness to washing measurement, all fibers showed superiority (by over grade 3~4). In addition, the color fastness to dry cleaning of all fibers was satisfactory or excellent (by over grade 3). Fourth, according to the results of the tensile strength measurement, it tended to decrease in the case of cotton and increase in the case of rayon. Fifth, the results of the density measurement showed that the density of cotton decreased by about 15~20% in the case of warp and 10% in the case of weft for all samples. The density of rayon decreased 20% in the case of warp for all samples and increased 30% in the case of weft for all samples.

Bioconversion of Sugarcane Bagasse with Japanese Koji by Solid-state Fermentation and Its Effects on Nutritive Value and Preference in Goats

  • Ramli, M.N.;Imura, Y.;Takayama, K.;Nakanishi, Y.
    • Asian-Australasian Journal of Animal Sciences
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    • 제18권9호
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    • pp.1279-1284
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    • 2005
  • The effects of 3 different strains of Japanese koji (Aspergillus oryzae, A. sojae and A. awamori) in the solid-state fermentation (SSF) of sugarcane bagasse mixed with wheat bran on chemical composition, energy, in vivo digestibility and preference of the fermented bagasse feeds (FBF) in goats were investigated. Diets consisted of lucerne hay cube (basal diet) and unfermented bagasse feed (control), FBF with A. oryzae (O), FBF with A. sojae (S) or FBF with A. awamori (A), which were mixed in a total ration of 7:3 (w/w DM). Three Nubian does were fed each of the diets, i.e. control, O, S and A in the 4 consecutive periods for digestion trials (21-day each). The goats were also used for preference trials (30-min each) of O, S and A. The O was significantly higher in CP content than others (p<0.05). The crude fiber (CF), ADF and cellulose contents of control were significantly lower than those of other diets (p<0.05). The S had significantly higher CF digestibility than control (p<0.05), and it revealed the largest value of all. Digestibilities of NDF, ADF and cellulose in S were significantly higher than those of control (about 10, 18 and 18%, respectively, p<0.05). The DE of S was significantly higher than that of others (p<0.05), though there were no significant differences in DCP and TDN between control and S. The results of preference trials demonstrated that the average intake rate was not significantly different among diets, but O and S are likely to be preferable to A (p<0.1). It was concluded that the SSF of bagasse feeds by Japanese koji can improve the fiber digestion, especially NDF, ADF or cellulose in goats, and there is a marked effect in the feed containing A. sojae, which may lead to the improvement of DE.