• Title/Summary/Keyword: natural barrier

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Vibration-Rotation Coupling in a Quasilinear Symmetric Triatomic Molecule

  • Lee, Jae-Shin
    • Bulletin of the Korean Chemical Society
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    • v.15 no.3
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    • pp.228-236
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    • 1994
  • The effect of the vibration mode coupling induced by the vibration-rotation interaction on total energy was investigated for the states with zero total angular momentum(J=0) in a quasilinear symmetric triatomic molecule of $AB_2$ type using a model potential function with a slight potential barrier to linearity. It is found that the coupling energy becomes larger for the levels of bend and asymmetric stretch modes and smaller for symmetric stretch mode as the excitation of the vibrational modes occurs. The results for the real molecule of $CH_2^+$, which is quasilinear, generally agree with the results for the model potential function in that common mode selective dependence of coupling energy is exhibited in both cases. The differences between the results for the model and real potential function in H-C-H system are analyzed and explained in terms of heavy mixing of the symmetric stretch and bend mode in excited vibrational states of the real molecule of $CH_2^+$. It is shown that the vibrational mode coupling in the potential energy function is primarily responsible for the broken nodal structure and chaotic behavior in highly excited levels of $CH_2^+$ for J= 0.

Missing Pattern Analysis of the GOCI-I Optical Satellite Image Data

  • Jeon, Ho-Kun;Cho, Hong Yeon
    • Ocean and Polar Research
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    • v.44 no.2
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    • pp.179-190
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    • 2022
  • Data missing in optical satellite images caused by natural variations have been a crucial barrier in observing the status of marine surfaces. Although there have been many attempts to fill the gaps of non-observation, there is little research to analyze the ratio of missing grids to overall sea grids and their seasonal patterns. This report introduces the method of quantifying the distribution of missing points and then shows how the missing points have spatial correlation and seasonal trends. Both temporal and spatial integration methods are compared to assess the effectiveness of reducing missing data. The temporal integration shows more outstanding performance than the spatial integration. Moran's I and K-function with statistical hypothesis testing show that missing grids are clustered and there is a non-random distribution from daily integration. The result of the seasonality test for Moran's I through a periodogram shows dependency on full-year, half-year, and quarter-year periods respectively. These analysis results can be used to deduce appropriate integration periods with permissible estimation errors.

Design and Fabrication of High Temperature Superconducting Rapid Single Flux Quantum T Flip-Flop (고온 초전도 단자속 양자 T 플립 플롭 설계 및 제작)

  • Kim, J. H.;Kim, S. H.;Jung, K. R.;Kang, J. H.;Syng, G. Y.
    • Progress in Superconductivity
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    • v.3 no.1
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    • pp.87-90
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    • 2001
  • We designed a high temperature superconducting rapid single flux quantum(RSFQ) T flip-flop(TFF) circuit using Xic and WRspice. According to the optimized circuit parameters, we fabricated the TFF circuit with $Y_1$$Ba_2$Cu$_3$$O_{7-x}$(YBCO) interface-controlled Josephson junctions. The whole circuit was comprised of five epitaxial layers including YBCO ground plane. The interface-controlled Josephson junction was fabricated with natural junction barrier that was formed by interface-treatment process. In addition, we report second design for a new flip-flop without ground palne.e.

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Review for Mechanisms of Gas Generation and Properties of Gas Migration in SNF (Spent Nuclear Fuel) Repository Site (사용 후 핵연료 처분장 내 가스의 발생 기작 및 거동 특성 고찰)

  • Danu Kim;Soyoung Jeon;Seon-ok Kim;Sookyun Wang;Minhee Lee
    • Economic and Environmental Geology
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    • v.56 no.2
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    • pp.167-183
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    • 2023
  • Gases originated from the final SNF (spent nuclear fuel) disposal site are very mobile in the barrier and they may also affect the migration of radioactive nuclides generated from the SNF. Mechanisms of gas-nuclide migration in the multi-barrier and their influences on the safety of the disposal site should be understood before the construction of the final SNF disposal site. However, researches related to gas-nuclide coupled movement in the multi-barrier medium have been very little both at home and abroad. In this study, properties of gas generation and migration in the SNF disposal environment were reviewed through previous researches and their main mechanisms were summarized on the hydrogeological evolution stage of the SNF disposal site. Gas generation in the SNF disposal site was categorized into five origins such as the continuous nuclear fission of the SNS, the Cu-canister corrosion, the oxidation-reduction reaction, the microbial activity, and the inflow from the natural barriers. Migration scenarios of gas in porous medium of the multi-barrier in the SNF repository site were investigated through reviews for previous studies and several gas migration types including ① the free gas phase flow including visco-capillary two-phase flow, ② the advection and diffusion of dissolved gas in pore water, ③ dilatant two-phase flow, and ④ tensile fracture flow, were presented. Reviewed results in this study can support information to design the further research for the gas-nuclide migration in the repository site and to evaluate the safety of the Korean SNF disposal site in view points of gas migration in the multi-barrier.

Assessment of Physicochemical Properties of Domestic Bentonite and Zeolite as Candidate Materials for a Engineered Barrier in a Radwaste Repository (방사성폐기물 처분장 공학방벽 재료로서의 국산 벤토나이트 및 제올라이트에 대한 물리화학적 특성 평가)

  • 정찬호
    • The Journal of Engineering Geology
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    • v.9 no.2
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    • pp.89-100
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    • 1999
  • This study was carried out to assess the physicochemical properties of domestic bentonites and zeolites from Tertiary Formation as the candidate material for a engineered barrier of a radioactive waste repository. Natural bentonite and zeolite samples were collected from nine bentonite mines and six zeolite mines in Yeonil-Gampo area. The commercial products of bentonite and zeolite were obtained from local companies. The collected samples were investigated to study the following physicochemical properties: X-ray diffraction patterns, swelling, cation exchange capacity(CEC), specific surface area, montmorillonite content, pH, organic carbon content, thermal property, microstruciure and chemical composition. Based on the physicochemical properties of bentonite and zeolite, the bentonites from U-41 and G-46 mines and the zeolites from Daedo and Y-1 mines are regarded as the most desirable candidate materials.

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Human Exposure and Health Effects of Inorganic and Elemental Mercury

  • Park, Jung-Duck;Zheng, Wei
    • Journal of Preventive Medicine and Public Health
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    • v.45 no.6
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    • pp.344-352
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    • 2012
  • Mercury is a toxic and non-essential metal in the human body. Mercury is ubiquitously distributed in the environment, present in natural products, and exists extensively in items encountered in daily life. There are three forms of mercury, i.e., elemental (or metallic) mercury, inorganic mercury compounds, and organic mercury compounds. This review examines the toxicity of elemental mercury and inorganic mercury compounds. Inorganic mercury compounds are water soluble with a bioavailability of 7% to 15% after ingestion; they are also irritants and cause gastrointestinal symptoms. Upon entering the body, inorganic mercury compounds are accumulated mainly in the kidneys and produce kidney damage. In contrast, human exposure to elemental mercury is mainly by inhalation, followed by rapid absorption and distribution in all major organs. Elemental mercury from ingestion is poorly absorbed with a bioavailability of less than 0.01%. The primary target organs of elemental mercury are the brain and kidney. Elemental mercury is lipid soluble and can cross the blood-brain barrier, while inorganic mercury compounds are not lipid soluble, rendering them unable to cross the blood-brain barrier. Elemental mercury may also enter the brain from the nasal cavity through the olfactory pathway. The blood mercury is a useful biomarker after short-term and high-level exposure, whereas the urine mercury is the ideal biomarker for long-term exposure to both elemental and inorganic mercury, and also as a good indicator of body burden. This review discusses the common sources of mercury exposure, skin lightening products containing mercury and mercury release from dental amalgam filling, two issues that happen in daily life, bear significant public health importance, and yet undergo extensive debate on their safety.

Analysis of Thermomechanical Properties Considering the Thermal Expansion Anisotropy of Membrane-Type Fiber-Reinforced Composite Material (멤브레인 형 섬유강화 복합재료의 열팽창 이방성을 고려한 열 기계적 특성 분석)

  • Jeong, Yeon-Jae;Kim, Hee-Tae;Kim, Jeong-Dae;Oh, Hoon-Gyu;Kim, Yong-Tai;Park, Seong-Bo;Lee, Jae-Myung
    • Journal of the Society of Naval Architects of Korea
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    • v.58 no.1
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    • pp.17-23
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    • 2021
  • The membrane-type Liquefied Natural Gas (LNG) cargo tank is equipped with a double barrier to seal the LNG, of which the secondary barrier serves to prevent LNG leakage and mainly uses fiber-reinforced composite materials. However, the composite materials have thermal expansion anisotropy, which deteriorates shape distortion and mechanical performance due to repeated thermal loads caused by temperature changes between cryogenic and ambient during the unloading of LNG. Therefore, in this study, the longitudinal thermal expansion characteristics of the composite materials were obtained using a vertical thermo-mechanical analyzer, and the elastic modulus was obtained through the tensile test for each temperature to perform thermal load analysis for each direction. This is considered that it is useful to secure reliability from the viewpoint of the design of materials for a LNG cargo hold.

Josephson effect of the superconducting van der Waals junction

  • Park, Sungyu;Kwon, Chang Il;Kim, Jun Sung
    • Progress in Superconductivity and Cryogenics
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    • v.23 no.2
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    • pp.6-9
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    • 2021
  • Heterostructures fabricated by various combinations of van der Waals (vdW) materials enable us to investigate disorder-free physical properties and realize novel functional devices. Superconducting vdW junctions have attracted a lot of attention because of its simple structure without a barrier layer. In superconducting vdW junction, without extra fabrication effort, a natural barrier can be formed, whose character is sensitive to distance and angle of lattice between two superconducting vdW materials. Using high-quality single crystals and the dry transfer technique, we fabricated the vertically stacked NbSe2/NbSe2 and FeSe/FeSe vdW junctions and investigated their Josephson junction properties. We found that in the FeSe junctions, Josephson coupling is extremely sensitive to the fabrication conditions, in contrast to the NbSe2 junctions. We attributed this distinct character of the FeSe junctions to surface instability and small Fermi surface of FeSe.

Degradation Properties of a Bi-layered Cross-linked Collagen Membrane for Localized Bone Regeneration: In Vitro and In Vivo Study

  • Park, Jin-Young;Lee, Jae-Hong;Cha, Jae-Kook;Lee, Jung-Seok;Jung, Ui-Won;Choi, Seong-Ho
    • Journal of Korean Dental Science
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    • v.14 no.1
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    • pp.12-25
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    • 2021
  • Purpose: (i) To evaluate the biologic properties of a bi-layered 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloride-cross-linked collagen membrane (CCM) in vitro. (ii) To assess the efficacy of CCM for localized bone regeneration in vivo. Materials and Methods: Biodegradation of CCM compared to a native collagen membrane (NCM) was assessed in vitro. In vivo, twelve male New Zealand White rabbits were used. Four calvarial, circular defects (diameter 8 mm) were created in each animal. The sites were randomly allocated to i) CCM+biphasic calcium phosphate (BCP) (CCM-BCP group), ii) CCM alone (CCM), iii) BCP alone (BCP) and, iv) negative control (control). Animals were sacrificed at 2 (n=6) and 8 weeks (n=6). Outcome measures included: micro-computed tomography (μCT) analysis (total augmented volume [TAV], new bone volume) and histomorphometry (total augmented area [TAA], newly formed bone, remaining membrane thickness [RMT]). Result: CCM was more resistant to degradation than NCM. μCT analysis showed CCM-BCP (196.43±25.30 mm3) and BCP (206.23±39.13 mm3) groups had significantly (P<0.01) larger TAV than the control (149.72±12.28 mm3) after 8 weeks. Histomorphometrically, CCM-BCP group (17.75±5.97 mm2) had significantly (P<0.01) greater TAA compared to the CCM group (7.74±2.25 mm2) and the control (8.13±1.81 mm2) after 8 weeks. After 8 weeks, RMT was reduced by 67%. Conclusion: CCM can be a favorable choice of barrier membrane when performing guided bone regeneration (GBR) in localized bone defects. CCM has better resistance to degradation than the natural collagen membrane, in vitro. In vivo, CCM provides an advantageous integration of prolonged barrier function and biocompatibility for GBR.