• 제목/요약/키워드: nanostructures

검색결과 727건 처리시간 0.023초

Separation of Human Breast Cancer and Epithelial Cells by Adhesion Difference in a Microfluidic Channel

  • Kwon, Keon-Woo;Choi, Sung-Sik;Kim, Byung-Kyu;Lee, Se-Na;Lee, Sang-Ho;Park, Min-Cheol;Kim, Pil-Nam;Park, Suk-Ho;Kim, Young-Ho;Park, Jun-Gyul;Suh, Kahp-Y.
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제7권3호
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    • pp.140-150
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    • 2007
  • A simple, label-free microfluidic cell purification method is presented for separation of cancer cells by exploiting difference in cell adhesion. To maximize the adhesion difference, three types of polymeric nanostructures (50nm pillars, 50nm perpendicular and 50nm parallel lines with respect to the direction of flow) were fabricated using UV-assisted capillary moulding and included inside a polydimethylsiloxane (PDMS) microfluidic channel bonded onto glass substrate. The adhesion force of human breast epithelial cells (MCF10A) and human breast carcinoma (MCF7) was measured independently by injecting each cell line into the microfluidic device followed by culture for a period of time (e.g., one, two, and three hours). Then, the cells bound to the floor of a microfluidic channel were detached by increasing the flow rate of medium in a stepwise fashion. It was found that the adhesion force of MCF10A was always higher than that of MCF cells regardless of culture time and surface nanotopography at all flow rates, resulting in a label-free detection and separation of cancer cells. For the cell types used in our study, the optimum separation was found for 2 hours culture on 50nm parallel line pattern followed by flow-induced detachment at a flow rate of $300{\mu}l/min$.

금속 나노 구조체의 형상에 따른 국소 표면 플라즈몬 특성 (Dependence of Localized Surface Plasmon Properties on the Shape of Metallic Nanostructures)

  • 김주영;조규만;이택성;김원목;이경석
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.77-77
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    • 2008
  • 금(Au)이나 은(Ag)과 같은 귀금속 물질로 형성된 금속 나노 구조체는 표면 플라즈몬 공진(Surface Plasmon Resonance, SPR) 현상과 이의 국부 환경(local environment) 변화에 대해 민감한 의존성으로 인하여 생화학적 센서로의 응용이 주목 받고 있다. 표면 플라즈몬 공진은 광 흡수와 광 산란을 수반하는데, 두 가지 특성 모두 분광학적 신호검출방식으로 센서에 응용가능하다. 이 중 광 산란을 이용하는 방식은 광원의 배경잡음 효과가 배제되기 때문에 단일 입자 검출에 유리하다. 광 흡수와 광 산란 특성은 금속 나노 구조체는 크기, 형상, 주변 매질, 물질의 선택에 따라서 영향을 받는다. 본 연구에서는 금 나노 디스크(nanodisc)의 형상에 따라서 여기 되는 표면 플라즈몬이 광 흡수와 광 산란 특성에 미치는 영향을 가시광과 근적외선 영역에 대해서 불연속 쌍극자 근사법(Discrete Dipole Approximation, DDA)을 이용하여 전사모사(simulation) 하였다. 금 나노 디스크의 형상과 플라즈몬 특성 간의 관계는 공명 파장과 산란 양자 거둠율(scattering quantum yield, $\eta$)을 이용하여 분석하였고, 센서로서의 응용을 가늠하기 위해 주변 매질의 굴절률을 조절하여 그에 따른 민감도(sensitivity )를 비교하였다. 나노 디스크의 모양이 판상에 가까워질수록 공명 파장은 적색 편이하였고 광 산란 효율과 민감도는 증가하는 현상이 나타났다. 또한, 산란 양자 거둠율은 증가하다가 완만하게 감소하는 경향이 나타났다.

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전기방사법으로 제작한 In2O3 나노섬유 기반 고감도 실내독성 CO 및 HCHO 가스센서 (Highly Sensitive Gas Sensors Based on Electrospun Indium Oxide Nanofibers for Indoor Toxic CO and HCHO Gases)

  • 임동하;황성환;권세훈;정현성
    • 한국전기전자재료학회논문지
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    • 제29권12호
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    • pp.803-808
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    • 2016
  • In this work, one dimension $In_2O_3$ nanostructures as detecting materials for indoor toxic gases were synthesized by an electrospinning process. The morphology of electrospun $In_2O_3$ nanofibers was controlled by electrolyte composition, applied voltage and working distance between a nozzle and a substrate. The synthesized $In_2O_3$ nanofibers-based paste with/without carbon black additives was prepared for the integration on a sensor device. The integration of $In_2O_3$ sensing materials was conducted by a hand-printing of the paste into the interdigit Au electrodes patterned on Si wafer. Gas sensing properties on CO and HCHO gases were characterized at $300^{\circ}C$. The evaluated sensing properties such as sensitivity, response time and recovery time were improved in $In_2O_3$ nanofiber pastes with carbon black, compared to the paste without carbon black.

Type-II ZnO/ZnSe 코어/쉘 이종 구조 합성 및 광촉매활성 평가 (Synthesis and Characteristics of Type-II ZnO/ZnSe Core/Shell Heterostructures for High Efficient Photocatalytic Activity)

  • 이우형;최광일;강동천;백수웅;이석호;임철현
    • 한국전기전자재료학회논문지
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    • 제27권3호
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    • pp.178-183
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    • 2014
  • Recently, various type of nanomaterials such as nanorod, nanowire, nanotube and their core/shell nanostructures have attracted much attention in photocatalyst due to their unique properties. Among them, Type-II core/shell heterostructures have extensively studied because it has exhibited improved electrical and optical properties against their single-component nanostructure. Such structures are expected to offer high absorption efficiency and fast charge transport due to their stepwised energetic combination and large internal surface area. Thus, it has been considered as potential candidates for high efficient photocatalytic activity. In this work, we introduce a novel chemical conversion process to synthesize Type-II ZnO/ZnSe core/shell heterostructures. A plausible conversion mechanism to ZnO/ZnSe core/shell heterostructres was proposed based on SEM, XRD, TEM and XPS analysis. The ZnO/ZnSe heterostructures exhibited excellent photocatalytic activity toward the decomposition of RhB dye compared to the ZnO nanorod arrays due to enhanced light absorption and the type-II cascade band structure.

Nonlocal strain gradient 3D elasticity theory for anisotropic spherical nanoparticles

  • Karami, Behrouz;Janghorban, Maziar;Tounsi, Abdelouahed
    • Steel and Composite Structures
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    • 제27권2호
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    • pp.201-216
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    • 2018
  • In this paper, three-dimensional (3D) elasticity theory in conjunction with nonlocal strain gradient theory (NSGT) is developed for mechanical analysis of anisotropic nanoparticles. The present model incorporates two scale coefficients to examine the mechanical characteristics much accurately. All the elastic constants are considered and assumed to be the functions of (r, ${\theta}$, ${\varphi}$), so all kind of anisotropic structures can be modeled. Moreover, all types of functionally graded spherical structures can be investigated. To justify our model, our results for the radial vibration of spherical nanoparticles are compared with experimental results available in the literature and great agreement is achieved. Next, several examples of the radial vibration and wave propagation in spherical nanoparticles including nonlocal strain gradient parameters are presented for more than 10 different anisotropic nanoparticles. From the best knowledge of authors, it is the first time that 3D elasticity theory and NSGT are used together with no approximation to derive the governing equations in the spherical coordinate. Moreover, up to now, the NSGT has not been used for spherical anisotropic nanoparticles. It is also the first time that all the 36 elastic constants as functions of (r, ${\theta}$, ${\varphi}$) are considered for anisotropic and functionally graded nanostructures including size effects. According to the lack of any common approximations in the displacement field or in elastic constant, present theory can be assumed as a benchmark for future works.

Fabrication of nickel nanoparticles-embedded carbon particles by solution plasma in waste vegetable oil

  • Pansuwan, Gun;Phuksawattanachai, Surayouth;Kerdthip, Kraiphum;Sungworawongpana, Nathas;Nounjeen, Sarun;Anantachaisilp, Suranan;Kang, Jun;Panomsuwan, Gasidit;Ueno, Tomonaga;Saito, Nagahiro;Pootawang, Panuphong
    • Journal of Advanced Marine Engineering and Technology
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    • 제40권10호
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    • pp.894-898
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    • 2016
  • Solution plasma is a unique method which provides a direct discharge in solutions. It is one of the promising techniques for various applications including the synthesis of metallic/non-metallic nanomaterials, decomposition of organic compounds, and the removal of microorganism. In the context of nanomaterial syntheses, solution plasma has been utilized to produce carbon nanoparticles and metallic-carbon nanoparticle systems. The main purpose of this study was to synthesize nickel nanoparticles embedded in a matrix of carbon particles by solution plasma in one-step using waste vegetable oil as the carbon source. The experimental setup was done by simply connecting a bipolar pulsed power generator to nickel electrodes, which were submerged in the waste vegetable oil. Black powders of the nickel nanoparticles-embedded carbon (NiNPs/Carbon) particles were successfully obtained after discharging for 90 min. The morphology of the synthesized NiNPs/Carbon was investigated by a scanning electron microscope, which revealed a good dispersion of NiNPs in the carbon-particle matrix. The X-ray diffraction of NiNPs/Carbon clearly showed the co-existence of crystalline Ni nanostructures and amorphous carbon. The crystallite size of NiNPs (through the Ni (111) diffraction plane), as calculated by the Scherrer equation was found to be 64 nm. In addition, the catalytic activity of NiNPs/Carbon was evaluated by cyclic voltammetry in an acid solution. It was found that NiNPs/Carbon did not show a significant catalytic activity in the acid solution. Although this work might not be helpful in enhancing the activity of the fuel cell catalysts, it is expected to find application in other processes such as the CO conversion (by oxidation) and cyclization of organic compounds.

개별 수직성장된 나노튜브와 금속의 복합 구조체 제작 및 분석 (Fabrication and Analysis of a Free-Standing Carbon Nanotube-Metal Hybrid Nanostructure)

  • 장원석;황준연;한창수
    • 대한기계학회논문집B
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    • 제36권1호
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    • pp.25-29
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    • 2012
  • 탄소나노튜브의 기계적 특성과 금속의 전기적 특성을 이용할 수 있는 나노 복합구조체의 특성은 두 재료 사이의 계면이 중용한 역할을 한다. 본 연구에서는 나노임프린트 패터닝을 이용하여 촉매금속을 패턴하고 이를 이용한 개별 성장된 탄소나노튜브 위에 증기증착법을 이용하여 니켈을 증착한 나노구 조체의 계면을 조사하였다. 이를 위하여 고해상의 투사전자현미경과 3 차원 원자 프로브 분석기를 이용하였다. 탄소나노튜브 위에서 성장된 나노결정의 경우 준 안정 상태인 조밀입방구조의 $Ni_3C$ 를 형성하는 것으로 나타났다. 이러한 특성을 이용한 나노복합체의 응용가능성을 살펴보았다.

열화학 기상 증착법에 의한 비정질 SiOx 나노와이어의 성장 (Growth of Amorphous SiOx Nanowires by Thermal Chemical Vapor Deposition Method)

  • 김기출
    • 융합정보논문지
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    • 제7권5호
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    • pp.123-128
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    • 2017
  • 나노구조를 갖는 물질들은 나노구조물이 갖는 고유의 체적 대비 높은 표면적 비와 양자 갇힘 효과에 기인하는 독특한 전기적, 광학적, 광전기적, 자기적 특성으로 인하여 많은 주목을 받아왔다. 열화학 기상 증착 공정은 나노 구조물의 성장과정에서 다양한 구조를 갖는 나노소재의 합성 능력 때문에 더욱 주목을 받아왔다. 본 연구에서는 두 영역 열화학 기상 증착법과 소스 물질 $TiO_2$ 파우더를 이용하여 VLS 공정으로 Si\$SiO_2$(300 nm)\Pt(5~40 nm) 기판 위에 실리콘 옥사이드 나노와이어를 성장시켰다. 성장된 실리콘 옥사이드 나노와이어의 형상과 결정학적 특성을 전계방출 주사전자현미경과 투과전자현미경으로 분석하였다. 분석결과, 성장된 실리콘 옥사이드 나노와이어의 형상인 지름과 길이는 촉매 박막의 두께에 의존하여 다른 모양을 나타내었다. 또한 성장된 실리콘 옥사이드 나노와이어는 비정질 상을 갖는 것으로 분석되었다.

비대칭 자기터널접합에서의 수직 스핀 전달 토크: 물질 변수에 대한 의존성 (Perpendicular Spin-transfer Torque in Asymmetric Magnetic Tunnel Junctions: Material Parameter Dependence)

  • 한재호;이현우
    • 한국자기학회지
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    • 제21권2호
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    • pp.52-55
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    • 2011
  • 스핀전달토크는 나노구조에서 자성상태를 제어하는데 유용한 수단이다. 자기터널접합에서 스핀전달토크는 자성물질층의 자화가 이루는 평면에 평행한 성분과 수직인 성분으로 나눌 수 있다. 이중 평행한 성분의 스핀전달토크의 성질은 상당히 잘 알려져 있으나, 수직인 성분의 스핀전달토크의 성질에 대해서는 여전히 이견이 많다. 비대칭 자기터널접합에서의 최근 실험에서, 수직전달토크의 전압 의존성이 전압의 이차항 성분뿐만 아니라 일차항 성분도 가짐을 보고하였다. 하지만 물질 변수에 대한 의존성은 여전히 잘 알려지지 않았다. 이 논문에서는 비대칭 자기터널접합에서의 스핀전달토크의 전압의존성을, 강자성층의 스핀 갈라짐 에너지와 일함수의 차이, 그리고 페르미 에너지를 변화시켜 가면서 체계적인 조사를 하였다.

Spin Wave Interference in Magnetic Nanostructures

  • Yang, Hyun-Soo;Kwon, Jae-Hyun;Mukherjee, Sankha Subhra;Jamali, Mahdi;Hayashi, Masamitsu
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2011년도 자성 및 자성재료 국제학술대회
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    • pp.7-8
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    • 2011
  • Although yttrium iron garnet (YIG) has provided a great vehicle for the study of spin waves in the past, associated difficulties in film deposition and device fabrication using YIG had limited the applicability of spin waves to practical devices. However, microfabrication techniques have made it possible to characterize both the resonant as well as the travelling characteristics of spin waves in permalloy (Py). A variety of methods have been used for measuring spin waves, including Brillouin light scattering (BLS), magneto-optic Kerr effect (MOKE), vector network analyzer ferromagnetic resonance (VNA-FMR), and pulse inductive microwave magnetometry (PIMM). PIMM is one of the most preferred methodologies of measuring travelling spin waves. In this method, an electrical impulse is applied at one of two coplanar waveguides patterned on top of oxide-insulated Py, producing a local disturbance in the magnetization of the Py. The resulting disturbance travels down the Py in the form of waves, and is inductively picked up by the other coplanar waveguide. We investigate the effect of the pulse width of excitation pulses on the generated spin wave packets using both experimental results and micromagnetic simulations. We show that spin wave packets generated from electrical pulses are a superposition of two separate spin wave packets, one generated from the rising edge and the other from the falling edge, which interfere either constructively or destructively with one another, depending upon the magnitude and direction of the field bias conditions. A method of spin wave amplitude modulation is also presented by the linear superposition of spin waves. We use interfering spin waves resulting from two closely spaced voltage impulses for the modulation of the magnitude of the resultant spin wave packets.

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