• Title/Summary/Keyword: nanorod

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Internal modals interactions analysis in terms of AFG nanorods based on Rayleigh model of nonlinear nonlocal axial behaviour

  • Somaye Jamali Shakhlavi;Shahrokh Hosseini Hashemi;Reza Nazemnezhad
    • Steel and Composite Structures
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    • v.52 no.5
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    • pp.557-569
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    • 2024
  • Nonlinear internal modals interactions analysis of axially functionally graded nanorods is evaluated on the basis of nonlocal elasticity theory and Rayleigh beam model for the first time. Functionally graded materials can be determined as nonhomogeneous composites which are obtained by combining of two various materials in order to get a new ideal material. In this research, material properties of nanorods are supposed to be calmly varied along the axial direction. Hamilton's principle is used to derive the equations with consideration of Von-Kármán's geometrically nonlinearity. Harmonic Differential Quadrature (HDQ) and Multiple Scale (MS) solution techniques are used to derive an approximate-analytic solution to the linear and nonlinear free axial vibration problem of non-classical nanorods for clamped-clamped and clamped-free boundary conditions. A parametric study is carried out to indicate the effects of index of AFG, aspect ratio, mode number, internal resonances and nonlinear amplitude on nonlinear nonlocal frequencies of axially functionally graded nanorods. Also, the effects of nonlocal and nonlinear coefficients and AFG index on relationships of internal resonances have been investigated. The presented theatrical-semi analytical model has the ability to predict very suitable results for extracting the internal modal interactions in the AFG nanorod.

Effect of Support Geometry on Catalytic Activity of Pt/CeO2 Nanorods in Water Gas Shift Reaction (Water Gas Shift 반응에서 Pt/CeO2 촉매의 지지체구조에 따른 촉매활성 연구)

  • Im, Hyo Been;Kwon, Soon Jin;Byun, Chang Ki;Ahn, Hee Sung;Koo, Kee Young;Yoon, Wang Lai;Yi, Kwang Bok
    • Journal of Hydrogen and New Energy
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    • v.25 no.6
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    • pp.577-585
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    • 2014
  • Nanorod and particle shape $CeO_2$ were synthesized via hydrothermal process and precipitation method, respectively, and used as supports of Pt catalyst for water gas shift (WGS) reaction. Three different durations (12, 48, and 96h) for hydrothermal process were applied for the preparation of nanorod type $CeO_2$. 1.0 wt% of Pt was loaded on the prepared supports with incipient wetness method prior to the catalytic activity tests that were carried out at a GHSV of $95,541h^{-1}$, and a temperature range of 200 to $360^{\circ}C$. Varying duration of hydrothermal process led to the difference in physical characteristics of $CeO_2$ nanorods, such as aspect ratio, BET surface area, pore diameter, and pore volume. Consequently, the catalytic activities of Pt/$CeO_2$ nanorods were affected by the physical characteristics of the supports and appeared to be in the order of Pt/$CeO_2$(12) > Pt/$CeO_2$(48) > Pt/$CeO_2$(96). The comparison of the catalytic activities and results of the analysis (XPS, XRD, SEM, BET and TPR) for the supports revealed that the activity of the catalysts depends on chemical states of the Pt and the support materials in the temperature range that is lower than $280^{\circ}C$. However, the activity is rather dependent on the physical characteristic of the supports because the increased gas velocity limits the mass transfer of reactants in micropores of the supports.

Effects of Growth Temperature on Hydrothermally Grown ZnO Nanorod Arrays (수열합성법으로 성장된 산화 아연 나노로드의 성장 온도에 따른 구조적, 광학적 특성 연구)

  • Jeong, Yong-Il;Ryu, Hyuk-Hyun
    • Journal of the Korean Vacuum Society
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    • v.20 no.3
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    • pp.211-216
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    • 2011
  • In this study, the effects of growth temperature on structural and optical properties of hydrothermally grown ZnO nanorod arrays have been investigated. Zinc nitrate ($Zn(NO_3)_2$) and hexamethylenetetramine were used as precursors. The ZnO buffered Si(100) with a thickness of 40 nm was used as the substrates. The ZnO nanorods were grown on these substrates with the temperature ranging from 55 to $115^{\circ}C$. The results were characterized by scanning electron microscope, X-ray diffraction and room temperature photoluminescence measurements. Well-aligned ZnO nanorods arrays were obtained from all samples. The tips of nanorods were flat when the temperature was less than $95^{\circ}C$, and the sharp-tip nanoneedle-like morphologies were obtained with the temperature of $115^{\circ}C$. In addition, some bundles were on the nanorods arrays with $115^{\circ}C$ due to the non-equilibrium growth. The growth temperature could affect the crystal and optical properties of ZnO. For the effects on crystal properties, the intensity of (002) peak was increased as the temperature was increased to $75^{\circ}C$, then decreased as the temperature was further increased to $115^{\circ}C$. As for the effects on optical properties, the intensity ratio of UV peak to visible peak is increased with the temperature increasing and the strongest UV peak intensity was obtained with the growth temperature of $95^{\circ}C$.

Piezoelectric Nanogenerators: Energy Harvesting Technology (압전 나노발전기: 에너지 수확 기술)

  • Shin, Dong-Myeong;Hwang, Yoon-Hwae
    • Vacuum Magazine
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    • v.3 no.2
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    • pp.17-20
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    • 2016
  • Piezoelectric nanogenerators are energy harvesting device to convert a mechanical energy into an electric energy using nanostructured piezoelectric materials. This review summarizes works to date on piezoelectric nanogenerators, starting with a basic theory of piezoelectricity and working mechanism, and moving through the reports of numerous nanogenerators using nanorod arrays, flexible substrates and alternative materials. A sufficient power generated from nanogenerators suggests feasible applications for either power supplies or strain sensors of highly integratedl nano devices. Further development of nanogenerators holds promise for the development of self-powered implantable and wearable electronics.

Forced vibration of nanorods using nonlocal elasticity

  • Aydogdu, Metin;Arda, Mustafa
    • Advances in nano research
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    • v.4 no.4
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    • pp.265-279
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    • 2016
  • Present study interests with the longitudinal forced vibration of nanorods. The nonlocal elasticity theory of Eringen is used in modeling of nanorods. Uniform, linear and sinusoidal axial loads are considered. Dynamic displacements are obtained for nanorods with different geometrical properties, boundary conditions and nonlocal parameters. The nonlocal effect increases dynamic displacement and frequency when compared with local elasticity theory. Present results can be useful for modeling of the axial nanomotors and nanoelectromechanical systems.