• Title/Summary/Keyword: nanocomposite coating

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The Fabrication and Characteristics of 0-3 PbTiO$_3$/P(VDF/TrFE) Nanocomposite Thin Films for Passive Pyroelectric Infrared Sensors

  • Kwon, Sung-Yeol
    • KIEE International Transactions on Electrophysics and Applications
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    • v.4C no.2
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    • pp.73-76
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    • 2004
  • 0-3 PbTiO$_3$/P(VDF/TrFE) nanocomposite thin films for passive pyroelectric infrared sensors were fabricated by a two-step spin coating technique. 65wt% VDF and 35 wt% TrFE was formed into a P(VDF/TrFE) powder. Nano size PbTiO$_3$ powder was used. 0-3 connectivity of PbTiO$_3$/P(VDF/TrFE) composite film was successfully achieved and observed using SEM photography. The dielectric constant and pyroelectric coefficient were measured and compared with P(VDF/TrFE). A very low dielectric constant (13.48 at 1KHz and sufficiently high pyroelectric coefficient (3.101 nC/$\textrm{cm}^2$ㆍk at 5$0^{\circ}C$) were measured. This nanocomposite can be used for a new pyroelectric infrared sensor to achieve better performance.

Airtightness performance evaluation of ultra-high performance concrete using polymer coating materials (그래핀을 활용한 폴리머 도막재료의 물리적 특성 평가)

  • Lee, Hyun Seung;Kim, Kang Min;Yoon, Seob;Seo, Tae Suk
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.257-258
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    • 2023
  • In this study, it was conducted to improve the physical properties of VAE polymer matrix used as a coating material. A nanocomposite was manufactured using graphene as a reinforcing agent based on a VAE matrix. As a result, improvements in tensile strength, adhesion strength, and porosity were confirmed.

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Characteristics of diamond-like nanocomposite films grown by plasma enhanced chemical vapor deposition (플라즈마 화학기상증착에 의해 성장된 유사 다이아몬드 나노복합체 박막의 특성 평가)

  • 양원재;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.1
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    • pp.36-40
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    • 2003
  • The diamond-like nanocomposite (DLN) thin films were deposited on Si substrates using $CH_4/(C_2H_5O)_4Si/H_2$/Ar gas mixtures as source gases by the plasma enhanced chemical vapor deposition (PECVD). The chemical structure and microstructure of grown films were investigated and their tribological properties were evaluated by a ball-on-plate type tribometer. The deposited DLN films mainly consisted of diamond-like a-C:H and quartz-like a-Si:O networks. The DLN films had a good agreement with tribological coating applications due to their extremely low friction coefficients and low wear rates.

Property and formation behavior of TiAlSiWN nanocomposite coating layer by the AIP process (AIP 공정 적용 TiAlSiWN 나노 복합체 코팅층의 형성 거동 및 특성 평가)

  • Lee, Jeong-Han;Park, Hyeon-Guk;Jang, Jun-Ho;Hong, Seong-Gil;O, Ik-Hyeon
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.97.2-97.2
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    • 2018
  • This study formed a hard TiAlSiWN coating layer using Ti, Al, Si and W raw powders that were mechanically alloyed and refined. The TiAlSi and TiAlSiW coating targets were fabricated using a single PCAS process in a short time with the optimal sintering conditions. The coating targets were deposited on the WC substrate by forming coating layers using TiAlSiN and TiAlSiWN nitride nano-composite structures with an AIP process. The properties of the nitride nano-composite coating layers were compared according to the addition of W. The microstructure of the nitride nano-composite coating layer was analyzed, focusing on the distribution of the crystalline phases, amorphous phases ($Si_3N_4$), and growth orientation of the columnar crystal depending on the addition of W. The mechanical properties of the coating layers were exhibited a hardness of approximately $3,000kg/mm^2$ and adhesion of about 117.77N in the TiAlSiN. In particular, the TiAlSiWN showed excellent properties with a hardness of more than $4,300kg/mm^2$ and an adhesion of about 181.47N.

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Incorporation of Montmorillonite/Silica Composite for the Corrosion Protection of an Epoxy Coating on a 2024 Aluminum Alloy Substrate

  • Thai Thu Thuy;Trinh Anh Truc;Pham Gia Vu
    • Corrosion Science and Technology
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    • v.22 no.2
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    • pp.99-107
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    • 2023
  • Layered silicate clay montmorillonite (MMT) has been used in nanocomposite coating to improve corrosion protection by reinforcing the barrier property. The better dispersion of MMT in the coating produces a higher barrier effect. Pretreatment with MMT could favor the delamination of clay platelets, facilitating MMT dispersion in the coating. In the present work, a montmorillonite/silica (MMT/Si) composite was prepared by the in situ sol-gel method. x-ray diffraction measurements and field-emission scanning electron microscopy observations showed silica crystal formation and increased basal spacing between the MMT platelets. Composite MMT/Si particles were introduced in an epoxy resin to reinforce the corrosion protection of the coating applied on the AA2024 surface. Electrochemical impedance spectroscopy (EIS) was performed to characterize the protective property of the coating. The results demonstrated the high barrier effect of the coating containing 5 wt% of MMT/Si. Adhesion evaluation after a salt spray test exhibited a high adherence to the epoxy coating containing MMT/Si.

Mechanical Properties of MoN-Cu Coatings according to Pre-treatment of AISI H13 Tool Steel (H13 공구강의 전처리에 따른 Mo-Cu-N 코팅의 기계적 특성)

  • Park, Hyun-Jun;Moon, Kyoung-Il;Kim, Sang-Sub
    • Journal of Surface Science and Engineering
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    • v.53 no.6
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    • pp.343-350
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    • 2020
  • The degradation of mechanical properties of nitride coatings to steel substrates is one of the main challenges for industrial applications. In this study, plasma nitriding treatment was used in order to increase the mechanical properties of Mo-Cu-N coating to the H13 tool steel. The nanostructured Mo-Cu-N coating was deposited using pulsed DC magnetron sputtering method with a single alloy Mo-Cu target. Mechanical properties of MoN-Cu coated samples after nitriding were found to be relatively better than non-nitrided MoN-Cu coating.

Synthesis and Characterization of SiO2/Fe2O3 Nanocomposite Particles for Hyperthermia (온열치료용 SiO2/Fe2O3 나노복합입자의 제조와 특성)

  • Yu, Ji-Hun;Lee, Chang-Woo;Lee, Jai-Sung;Choa, Yong-Ho;Hofmann, Heinrich
    • Korean Journal of Materials Research
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    • v.13 no.9
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    • pp.613-618
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    • 2003
  • The magnetic heating effect of $SiO_2$coated $ \Upsilon-Fe_2$$O_3$nanocomposite particle due to magnetic relaxational loss of superparamagnetic regime was investigated by measuring the generated heat from nanocomposite particles in alternative applied magnetic fields. The commercial $ \Upsilon-Fe_2$$O_3$nanoparticles were coated by SiO$_2$in water solution with TEOS and the synthesized nanocomposite powders and its magnetic properties were characterized and compared with the raw$ \Upsilon-Fe_2$$O_3$nanoparticles. The 10∼30 nm sized $ \Upsilon-Fe_2$$O_3$. nanoparticles were coated by 5 nm thickness of amorphous $SiO_2$film. The nanocomposite particle has very low Mr and Hc value showing superparamagnetic behavior The magnetic heating effect of nanocomposite particle on surface coating phase of $SiO_2$was discussed in terms of superparamagnetic behaviors of each particles, and their potential for hyperthermia application was evaluated.

Interfacial Durability and Acoustic Properties of Transparent xGnP/PVDF/xGnP Graphite Composites Film for Acoustic Actuator (음향 작동기를 위한 투명한 xGnP/PVDF/xGnP 그래핀 복합재료 필름의 계면 내구성 및 음향 특성)

  • Gu, Ga-Young;Wang, Zuo-Jia;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.25 no.3
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    • pp.70-75
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    • 2012
  • Interfacial durability and electrical properties of CNT, ITO or xGnP coated PVDF nanocomposites were investigated for acoustic actuator applications. The xGnP coated PVDF nanocomposite exhibited better electrical conductivity than CNT and ITO case due to the unique electrical property of xGnP, and this nanocomposite also showed good sound characteristics. Interfacial adhesion durability between either neat CNT or plasma treated CNT and plasma treated PVDF were measured by static contact angle, surface energy, work of adhesion, and spreading coefficient tests. The optimum acoustic actuation performance of xGnP coated PVDF nanocomposite was measured using sound level meter with changing radius of curvature and coating conditions. As compared to CNT and ITO, the xGnP was known as more appropriate acoustic actuator due to the characteristic electrical property. It is the most appropriate condition when the radius of curvature is 15 degree. Although sound characteristics were different with various coating thicknesses, it is possible to manufacture transparent actuator with good sound quality.

A Study on the Polymer Nanocomposite for Corrosion Protection (내식 방지용 고분자 나노복합재료에 관한 연구)

  • Lyu, Sung Gyu;Park, Se Hyeong;Park, Chan Sup;Cha, Jong Hyun;Sur, Gil Soo
    • Applied Chemistry for Engineering
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    • v.16 no.2
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    • pp.212-216
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    • 2005
  • Benzotriazole which is used as a corrosion inhibitor for the zinc coated steel was intercalated into Na-MMT. X-ray diffraction experiments on intercalant/silicate composite samples demonstrated that the intercalation of intercalant leads to an increase in the spacing between silicate layers. Water soluble poly(ethylene-co-acrylic acid) (PEA) nanocomposites, to use as a coating agent, were prepared with these modified MMT. We found that mono-layered silicates were dispersed in PEA matrix and those resultants were exfoliated nanocomposites. From the result of salt spray test, we found that this coating agent prepared with water soluble poly(ethylene-co-acrylic acid) (PEA) nanocomposite provided good corrosion protection. These results were caused by decreasing the rate of oxygen permeation from silicate layers dispersed homogeneously in PEA matrix and the effect of corrosion inhibitor from benzotriazole.