• Advances in materials Research
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• v.7 no.3
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• pp.185-194
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• 2018

The mechanism of biological materials structure is very complex and has optimal properties compared to engineering materials. Top Neck mollusks shells, as an example of biological materials, have hierarchical structure, which 95 percent of its structure is Aragonite and 5 percent organic materials. This article detected mechanical properties of the Top Neck mollusks shell as a Nano composite using Nano-indentation method in different situations. Research findings indicate that mechanical properties of the Top Neck mollusks shell including elastic modulus and hardness are higher than a fresh one preserved in -50 centigrade and also a Top Neck mollusks shell preserved in environmental conditions. Nano-indentation test results are so close in range, overall, that hardness degree is 3900 to 5200 MPa and elastic modulus is 70 to 85 GPa.

• Bulletin of the Korean Chemical Society
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• v.33 no.12
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• pp.4251-4254
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• 2012

• Bulletin of the Korean Chemical Society
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• v.33 no.4
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• pp.1349-1352
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• 2012

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.17 no.11
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• pp.1149-1155
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• 2004

In this paper, novel methods for improvement of thermal stability of Ni-germano Silicide were proposed for nano CMOS applications. It was shown that there happened agglomeration and abnormal oxidation in case of Ni-germano Silicide using Ni only structure. Therefore, 4 kinds of tri-layer structure, such as, Ti/Ni/TiN, Ni/Ti/TiN, Co/Ni/TiN and Ni/Co/TiN were proposed utilizing Co and Ti interlayer to improve thermal stability of Ni-germano Silicide. Ti/Ni/TiN structure showed the best improvement of thermal stability and suppression of abnormal oxidation although all kinds of structures showed improvement of sheet resistance. That is, Ti/Ni/TiN structure showed only 11 ohm/sq. in spite of 600 $^{\circ}C$, 30 min post silicidation annealing while Ni-only structure show 42 ohm/sq. Therefore, Ti/Ni/TiN structure is highly promising for nano-scale CMOS technology.

• Journal of the Semiconductor & Display Technology
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• v.18 no.3
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• pp.19-24
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• 2019

In this study, the Ag nano-dots structure was applied to the textured wafer surface to improve the light trapping effect of crystalline silicon solar cell. The Ag nano-dots structure was formed by the annealing of Ag thin film. Ag thin film deposition was performed using a thermal evaporator. The effect of light trapping was compared and analyzed through light reflectance measurements. The optimization process of the Ag nano-dots structure was made by varying the thickness of Ag thin film, the annealing temperature and time. The thickness of Ag thin films was in the range of 5 ~ 20 nm. The annealing temperature was in the range of 450~650℃ and the annealing time was in the range of 30 ~ 60 minutes. As a result, the light reflectance of 10 nm Ag thin film annealed at 650℃ for 30 minutes showed the lowest value of about 9.67%. This is a value that is about 3.37% lower than the light reflectance of the sample that has undergone only the texturing process. Finally, the change of the light reflectance by the HF treatment of the sample on which the Ag nano-dots structure was formed was investigated. The HF treatment time was in the range of 0 ~ 120 seconds. As a result, the light reflectance decreased by about 0.41% due to the HF treatment for 75 seconds.

• Bulletin of the Korean Chemical Society
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• v.29 no.4
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• pp.817-821
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• 2008

We have investigated the influence of the crystal structure on the chemical bonding nature and photocatalytic activity of cubic and hexagonal perovskite A[$Cr_{1/2}Ta_{1/2}$]O3 (A = Sr, Ba) compounds. According to neutron diffraction and field emission-scanning electron microscopy, the crystal structure and particle size of these compounds are strongly dependent on the nature of A-site cations. Also, it was found that the face-shared octahedra in the hexagonal phase are exclusively occupied by chromium ions, suggesting the presence of metallic (Cr-Cr) bonds. X-ray absorption and diffuse UV-vis spectroscopic analyses clearly demonstrated that, in comparison with cubic Sr[$Cr_{1/2}Ta_{1/2}$]$O_3$ phase, hexagonal Ba[$Cr_{1/2}Ta_{1/2}$]$O_3$ phase shows a decrease of Cr oxidation state as well as remarkable changes in interband Cr d-d transitions, which can be interpreted as a result of metallic (Cr-Cr) interactions. According to the test of photocatalytic activity, the present semiconducting materials have a distinct activity against the photodegradation of 4-chlorophenol. Also the Srbased compound was found to show a higher photocatalytic activity than the Ba-based one, which is attributable to its smaller particle size and its stronger absorption in visible light region.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.385-385
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• 2011

Ion beam Sputtering (IBS)를 이용한 물질 표면의 pattern 형성은 물리적 변수 조절로 손쉽게 nano structure의 크기와 형태를 조절할 수 있어 관심을 받고 있다. 본 연구발표에서는 massless Dirac Fermion behavior로 인한 highly carrier mobility와 같은 특성으로 인해 차세대 device material로 각광받고 있는 Graphene의 layered compound (층상구조) 형태인 HOPG (Highly Ordered Pyrolysis Graphite)에 IBS (Ion beam Sputtering)를 이용해 nano structure가 형성 가능함을 보이고 그 특징에 대해 소개하려 한다. HOPG(0001)를 Sputter 했을 때, 표면에 잘 정렬된 nano ripple pattern이 형성 가능함을 확인하였으며 sputter하는 시간을 변화하면 약 10 nm에서 80 nm까지 wavelength를 조절할 수 있다. 또한 이전의 IBS를 이용한 연구들에서 확인할 수 있는 다른 물질의 곧게 뻗은 nano ripple과는 다르게 ripple의 끝에 nano swab이 생기는 것을 AFM (Atomic Force Microscope)으로 확인할 수 있었다. 이러한 Graphite에서만 나타나는 Sputter에 의한 표면의 변화의 원인을 규명하고자 Sputter가 지속됨에 따라 나타나는 mopology의 roughness와 wavelength의 시간에 따른 dynamic scaling behavior를 확인하였고 그 얼개를 알기 위해 simulation을 수행 하였다.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.126-127
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• 2006

In this study, nano grain W is fabricated by Severe Plastic Deformation-Powder Metallurgy (SPD-PM) process. W powder and W-Re powder mixtures are processed by SPD-PM process, a Mechanical Milling (MM) process. As results, a nano grain structure, whose grain size is approximately 20nm, is obtained in W powder after MM for 360ks. A nano grain W compact, whose grain size 630nm, has excellent deformability above 1273K. A nano grain W-10Re compact is composed of equiaxed grain, a grain growth is restrained and has low dislocation density after the large deformation; therefore it is considered that W-Re compact shows superplasticity.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.171-171
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• 2011

Co and Fe doped multi-wall carbon nano-tubes (MWCNTs) synthesized by microwave plasma enhanced chemical vapor deposition (PECVD) technique are investigated with synchrotron radiations at Pohang Light Source (PAL) and European Synchrotron Radiation Facility (ESRF). Near edge x-ray absorption spectroscopy (NEXAFS) measurement at C K, Co $L_{3,2}$ and Fe $L_{3,2}$-edges, and x-ray magnetic circular dichroism (XMCD) at Co and Fe $L_{3,2}$-edges have been carried at 7B1 XAS KIST and 2A MS beamline, respectively, to understand the electronic structure and responsible magnetic interactions at room temperature. X-ray absorption spectroscopy (XAS) at C K-edge shows significant p-bonding and Co and Fe L-edges proves the presence of $Co^{2+}$ and $Fe^{2+}$ in octahedral symmetry. Co and Fe doped MWCNTs show good XMCD spectra at 300K. The effect on the magnetism is also studied through swift heavy ion (SHI) radiations and magnetism is found enhanced and change in the electronic structure in Co-CNTs is investigated.

• Bulletin of the Korean Chemical Society
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• v.30 no.2
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• pp.449-453
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• 2009

A mesoporous assembly of layered titanate with well-dispersed Pt cocatalysts has been synthesized via a restacking of exfoliated titanate nanosheets and a simultaneous adsorption of Pt nanoparticles. According to powder X-ray diffraction analysis, the obtained mesoporous assembly shows amorphous structure corresponding to the disordered stacking of layered titanate crystallites. Field emission-scanning electron microscopy and $N_2$ adsorption-desorption isotherm measurement clearly demonstrate the formation of mesoporous structure with expanded surface area due to the house-of-cards type stacking of the titanate crystallites. From high resolution-transmission electron microscopy and elemental mapping analyses, it is found that Pt nanoparticles with the size of ~2.5 nm are homogeneously dispersed in the mesoporous assembly of layered titanate. In comparison with the protonated titanate, the present mesoporous assembly of layered titanate exhibits better photocatalytic activity for the photodegradation of organic molecules. This finding underscores that the restacking of exfoliated nanosheets is quite useful not only in creating mesoporous structure but also in improving the photocatalytic activity of titanium oxide.