• Title/Summary/Keyword: nano porous

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Development of Membrane Filters with Nanostructured Porous Layer by Coating of Metal Nanoparticles Sintered onto a Micro-Filter (마이크로-필터 상에 소결 처리된 금속 나노입자 코팅에 의한 나노구조 기공층 멤브레인 필터 개발)

  • Lee, Dong-Geun;Park, Seok-Joo;Park, Young-Ok;Ryu, Jeong-In
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.8
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    • pp.617-623
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    • 2008
  • The membrane filter adhered with nanostructured porous layer was made by heat treatment after deposition of nanoparticle-agglomerates sintered in aerosol phase onto a conventional micron-fibrous metal filter as a substrate filter. The Sintered-Nanoparticle-Agglomerates-coated NanoStructured porous layer Membrane Filter (SNA-NSMF), whose the filtration performance was improved compared with the conventional metal membrane filters, was developed by adhesion of nanoparticle-agglomerates of dendrite structure sintered onto the micron-fibrous metal filter. The size of nanoparticle-agglomerates of dendrite structure decreased with increasing the sintering temperature because nanoparticle-agglomerates shrank. When shrinking nanoparticle-agglomerates were deposited and treated with heat onto the conventional micron-fibrous metal filter, pore size of nanostructured porous layer decreased. Therefore, pressure drops of SNA-NSMFs increased from 0.3 to 0.516 kPa and filtration efficiencies remarkably increased from 95.612 to 99.9993%.

Synthesis of Nanoporous Carbon as a Gas Adsorbent by Reverse Replication Process of Silica Template

  • Cho, Churl-Hee;Kim, Joon-Soo;Kim, Hong-Soo;Ahn, Young-Soo;Han, Moon-Hee;Yoo, Jong-Sung
    • Journal of the Korean Ceramic Society
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    • v.40 no.6
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    • pp.519-524
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    • 2003
  • Porous carbon with high surface area and pore volume was prepared by a reverse replication process and its toluene equilibrium adsorption behavior was investigated. The preparation process of the porous carbon was composed of fellowing sub-processes in series: synthesis and template preparation of silica gel, impregnation and polymerization of DVB monomer in silica template, carbonization of DVB polymer in a silica-polymer composite, and HF-assisted selective etching of silica in carbon-silica composite. The prepared porous carbon was nano porous and had ultrahigh specific surface area (2007 ㎡/g) and large pore volume (3.07 ㎤/g). The nanoporous carbon showed rapid toluene adsorption rate and good toluene adsorption capacity, compared with a commercial Y-type zeolite. In the present study, a reverse replication process to prepare nanoporous carbons will be introduced and its application potential as a gas adsorbent will be discussed.

Multi-scale simulation of drying process fey porous materials using molecular dynamics (part 3: multi-scale simulation) (분자동역학을 이용한 다공성 물질 건조공정 멀티스케일 시뮬레이션(3부: 멀티스케일 시뮬레이션))

  • Baik S.M.;Keum Y.T.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.4
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    • pp.168-174
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    • 2005
  • In this study, the numerical simulation of drying processes for porous materials is performed by employing the hierarchical multi-scale modeling and the nano-scale material properties obtained from the molecular dynamics simulation. The multi-scale simulation system is set up using pre- and post-processors and the drying process of electric porous ceramic insulator is simulated. The temperature, moisture, residual stress, and displacement distributions are compared with those based on homogenized properties.

Effect of SiC Filler Content on Microstructure and Flexural Strength of Highly Porous SiC Ceramics Fabricated from Carbon-Filled Polysiloxane (SiC 필러 함량이 탄소 함유 Polysiloxane으로부터 제조된 고기공률 탄화규소 세라믹스의 미세조직과 꺾임강도에 미치는 영향)

  • Eom, Jung-Hye;Kim, Young-Wook;Song, In-Hyuck
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.625-630
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    • 2012
  • Highly porous silicon carbide (SiC) ceramics were fabricated from polysiloxane, SiC and carbon black fillers, AlN-$Y_2O_3$ additives, and poly (ether-co-octene) (PEOc) and expandable microsphere templates. Powder mixtures with a fixed PEOc content (30 wt%) and varying SiC filler contents from 0-21 wt% were compression-molded. During the pyrolysis process, the polysiloxane was converted to SiOC, the PEOc generated a considerable degree of interconnected porosity, and the expandable microspheres generated fine cells. The polysiloxane-derived SiOC and carbon black reacted and synthesized nano-sized SiC with a carbothermal reduction during a heat-treatment. Subsequent sintering of the compacts in a nitrogen atmosphere produced highly porous SiC ceramics with porosities ranging from 78 % to 82 % and a flexura lstrength of up to ~7 MPa.

Supercritical Fluids and Preparation of Porous Materials (초임계 유체 및 다공성 소재 제조 기술)

  • Lee, Jun-Young;An, Joon-Hyun;Kim, Jung-Hyun
    • Applied Chemistry for Engineering
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    • v.16 no.2
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    • pp.169-179
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    • 2005
  • Porous materials are useful in a wide range of applications including bio/electronic products. The preparation and processing of these materials are mainly progressed by using an organic solvent, which gives rise to air pollution by its emissions. Alternatively, supercritical fluids are well suited to the production of functional porous materials due to a number of specific physical, chemical, and toxicological advantages. In this review, we will introduce the preparation and processing techniques for the formation of the nano/macro pore structure and their morphology, which can be controled by using supercritical fluids.

Buckling and vibration of porous sandwich microactuator-microsensor with three-phase carbon nanotubes/fiber/polymer piezoelectric polymeric nanocomposite face sheets

  • Arani, Ali Ghorbanpour;Navi, Borhan Rousta;Mohammadimehr, Mehdi
    • Steel and Composite Structures
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    • v.41 no.6
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    • pp.805-820
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    • 2021
  • In this research, the buckling and free vibration of three-phase carbon nanotubes/ fiber/ polymer piezoelectric nanocomposite face sheet sandwich microbeam with microsensor and micro-actuator surrounded in elastic foundation based on modified couple stress theory (MCST) is investigated. Three types of porous materials are considered for sandwich core. Higher order (Reddy) and sinusoidal shear deformation beam theories are employed for the displacement fields. Sinusoidal surface stress effects are extracted for sinusoidal shear deformation beam theory. The equations of motion are derived by Hamilton's principle and then the natural frequency and critical buckling load are obtained by Navier's type solution. The determined results are in good agreement with other literatures. The detailed numerical investigation for various parameters is performed for this microsensor-microactuator. The results reveal that the microsensor-microactuator enhanced by increasing of Skempton coefficient, carbon nanotubes diameter length to thickness ratio, small scale factor, elastic foundation, surface stress constants and reduction in porous coefficient, micro-actuator voltage and CNT weight fraction. The valuable results can be expedient for micro-electro-mechanical (MEMS) and nano-electro-mechanical (NEMS) systems.

Guided waves of porous FG nanoplates with four edges clamped

  • Zhao, Jing-Lei;She, Gui-Lin;Wu, Fei;Yuan, Shu-Jin;Bai, Ru-Qing;Pu, Hua-Yan;Wang, Shilong;Luo, Jun
    • Advances in nano research
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    • v.13 no.5
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    • pp.465-474
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    • 2022
  • Based on the nonlocal strain gradient (NSG) theory and considering the influence of moment of inertia, the governing equations of motion of porous functionally graded (FG) nanoplates with four edges clamped are established; The Galerkin method is applied to eliminate the spatial variables of the partial differential equation, and the partial differential governing equation is transformed into an ordinary differential equation with time variables. By satisfying the boundary conditions and solving the characteristic equation, the dispersion relations of the porous FG strain gradient nanoplates with four edges fixed are obtained. It is found that when the wave number is very small, the influences of nonlocal parameters and strain gradient parameters on the dispersion relation is very small. However, when the wave number is large, it has a great influence on the group velocity and phase velocity. The nonlocal parameter represents the effect of stiffness softening, and the strain gradient parameter represents the effect of stiffness strengthening. In addition, we also study the influence of power law index parameter and porosity on guided wave propagation.

An efficient numerical model for free vibration of temperature-dependent porous FG nano-scale beams using a nonlocal strain gradient theory

  • Tarek Merzouki;Mohammed SidAhmed Houari
    • Structural Engineering and Mechanics
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    • v.90 no.1
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    • pp.1-18
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    • 2024
  • The present study conducts a thorough analysis of thermal vibrations in functionally graded porous nanocomposite beams within a thermal setting. Investigating the temperature-dependent material properties of these beams, which continuously vary across their thickness in accordance with a power-law function, a finite element approach is developed. This approach utilizes a nonlocal strain gradient theory and accounts for a linear temperature rise. The analysis employs four different patterns of porosity distribution to characterize the functionally graded porous materials. A novel two-variable shear deformation beam nonlocal strain gradient theory, based on trigonometric functions, is introduced to examine the combined effects of nonlocal stress and strain gradient on these beams. The derived governing equations are solved through a 3-nodes beam element. A comprehensive parametric study delves into the influence of structural parameters, such as thicknessratio, beam length, nonlocal scale parameter, and strain gradient parameter. Furthermore, the study explores the impact of thermal effects, porosity distribution forms, and material distribution profiles on the free vibration of temperature-dependent FG nanobeams. The results reveal the substantial influence of these effects on the vibration behavior of functionally graded nanobeams under thermal conditions. This research presents a finite element approach to examine the thermo-mechanical behavior of nonlocal temperature-dependent FG nanobeams, filling the gap where analytical results are unavailable.

Nonlinear vibration analysis of FG porous shear deformable cylindrical shells covered by CNTs-reinforced nanocomposite layers considering neutral surface exact position

  • Zhihui Liu;Kejun Zhu;Xue Wen;Abhinav Kumar
    • Advances in nano research
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    • v.17 no.1
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    • pp.61-73
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    • 2024
  • This paper presents nonlinear vibration analysis of a composite cylindrical shell. The core of the shell is made of functionally graded (FG) porous materials and layers is fabricated of carbon nanotubes (CNTs) reinforced nanocomposites. To increase the accuracy of results, neutral surface position is considered. First-order shear deformation theory is used as displacement field to derive the basic relations of equation motions. In addition, von-Karman nonlinear strains are employed to account geometric nonlinearity and to enhance the results' precision, the exact position of the neutral surface is considered. To governing the partial equations of motion, the Hamilton's principle is used. To reduce the equation motions into a nonlinear motion equation, the Galerkin's approach is employed. After that the nonlinear motion equation is solved by multiple scales method. Effect of various parameters such as volume fraction and distribution of CNTs along the thickness directions, different patterns and efficiency coefficients of porous materials, geometric characteristics and initial conditions on nonlinear to linear ratio of frequency is investigated.

KOH-activated graphite nanofibers as CO2 adsorbents

  • Yuan, Hui;Meng, Long-Yue;Park, Soo-Jin
    • Carbon letters
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    • v.19
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    • pp.99-103
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    • 2016
  • Porous carbons have attracted much attention for their novel application in gas storage. In this study, porous graphite nano-fiber (PGNFs)-based graphite nano fibers (GNFs) were prepared by KOH activation to act as adsorbents. The GNFs were activated with KOH by changing the GNF/KOH weight ratio from 0 through 5 at 900℃. The effects of the GNF/KOH weight ratios on the pore structures were also addressed with scanning electron microscope and N2 adsorption/desorption measurements. We found that the activated GNFs exhibited a gradual increase of CO2 adsorption capacity at CK-3 and then decreased to CK-5, as determined by CO2 adsorption isotherms. CK-3 had the narrowest micropore size distribution (0.6–0.78 nm) among the treated GNFs. Therefore, KOH activation was not only a significant method for developing a suitable pore-size distribution for gas adsorption, but also increased CO2 adsorption capacity as well. The study indicated that the sample prepared with a weight ratio of ‘3’ showed the best CO2 adsorption capacity (70.8 mg/g) as determined by CO2 adsorption isotherms at 298 K and 1 bar.