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Supercritical Fluids and Preparation of Porous Materials  

Lee, Jun-Young (Nanotechnology Research Center, Yonsei University)
An, Joon-Hyun (Nanosphere Process & Technology Laboratory, Department of Chemical Engineering, Yonsei University)
Kim, Jung-Hyun (Nanosphere Process & Technology Laboratory, Department of Chemical Engineering, Yonsei University)
Publication Information
Applied Chemistry for Engineering / v.16, no.2, 2005 , pp. 169-179 More about this Journal
Abstract
Porous materials are useful in a wide range of applications including bio/electronic products. The preparation and processing of these materials are mainly progressed by using an organic solvent, which gives rise to air pollution by its emissions. Alternatively, supercritical fluids are well suited to the production of functional porous materials due to a number of specific physical, chemical, and toxicological advantages. In this review, we will introduce the preparation and processing techniques for the formation of the nano/macro pore structure and their morphology, which can be controled by using supercritical fluids.
Keywords
supercritical fluid; supercritical $CO_2$; porous materials; pore structure; porogen;
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1 P. G. Jessop and W. Leitner, Chemical Synthesis Using Supercritical Fluids, Wiley-VCH, Weinheim, Germany (1999)
2 M. J. Earle and K. R. Seddon, ACS Symposium Series, 819, 10 (2002)
3 K. N. Lee and J. H. Kim, Chemical industry and Technology, 16(4), 352 (1998)
4 C. K. Ober, A. H. Gabor, P. Gallagher-Wetmore, and R. D. Allen, Adv. Mater., 9, 1039 (1997)   DOI   ScienceOn
5 S. Yesodharan, Curr. Sci., 82, 1112 (2002)
6 B. Warwick, F. Dehghani, N. R. Foster, J. R. Biffin, and H. L. Regtop, Ind. Eng. Chem. Res., 41, 1993 (2002)   DOI   ScienceOn
7 B. Krause, M. Kloth, N. F. A. van der Vegt, and M. Wessling, Ind. Eng Chem. Res., 41, 1195 (2002)   DOI   ScienceOn
8 S. M. Howdle, M. S. Watson, M. J. Whitaker, V. K. Popov, M. C. Davies, F. S. Mandel, J. D. Wang, and K. M. Shakesheff, Chem. Commun., 109 (2001)
9 X. B. Yang, H. I. Roach, N. M. P. Clarke, S. M. Howdle, R. A. Quirk, K. M. Shakesheff, and R. O. C. Oreffo, Bone, 29, 523 (2001)   DOI   ScienceOn
10 D. D. Hile, M. L. Amirpour, A. Akgerman, and M. V. Pishko, J. Controlled Release, 66, 177 (2000)   DOI   ScienceOn
11 P. D. Whaley, S. Kulkarni, P. Ehrlich, R. S. Stein, H. H. Winter, W. C. Conner, and G. Beaucage, J. Polym. Sci. B, Polym. Phys., 36, 617 (1998)   DOI   ScienceOn
12 J. vonBehren, E. H. Chimowitz, and P. M. Fauchet, Adv. Mater., 9, 921 (1997)   DOI   ScienceOn
13 J. Y. Lee, C. H. Song, J. I. Kim, and J. H. Kim, J. Nanoparticle Research, 2, 53 (2002)
14 D. C. Sherrington, Chem. Commun., 2275 (1998)
15 C. T. Lee, P. A. Psathas, K. P. Johnston, J. deGrazia, and T. W. Randolph, Langmuir, 15, 6781 (1999)   DOI   ScienceOn
16 Y. N. Xia, B. Gates, and Z. Y. Li, Adv. Mater., 13, 409 (2001)   DOI   ScienceOn
17 H. Wakayama and Y. Fukushima, Ind. Eng. Chem. Res., 39, 4641 (2000)   DOI   ScienceOn
18 H. Wakayama, H. Itahara, N. Tatsuda, S. Inagaki, and Y. Fukushima, Chem. Mater., 13, 2392 (2001)   DOI   ScienceOn
19 N. Z. Clarke, C. Waters, K. A. Johnson, J. Satherley, and D. J. Schiffrin, Langmuir, 17, 6048 (2001)   DOI   ScienceOn
20 C. Y. Yeh, S. B. Zhang, and A. Zunger, Phys. Rev. B, 50(14), 405 (1994)
21 L. Brus, J. Phys. Chem., 98, 3575 (1994)   DOI   ScienceOn
22 J. D. Holmes, K. P. Johnston, R. C. Doty, and B. A. Korgel, Science, 287, 1471 (2000)   DOI   ScienceOn
23 F. M. Kerton, G. A. Lawless, and S. P. Armes, J. Mater. Chem., 7, 1965 (1997)   DOI   ScienceOn
24 K. N. Lee, Y. J. Suh, H. J. Lee, and J. H. Kim, Polymer(Korea), 23(2), 181 (1999)
25 A. K. Hebb, and A. I. Cooper, Comp. Sci. Technol., 63, 2379 (2003)   DOI   ScienceOn
26 N. R. B. Coleman, M. A. Morris, T. R. Spalding, and J. D. Holmes, J. Am. Chem. Soc., 123, 187 (2001)   DOI   ScienceOn
27 O. D. Velev and E. W. Kaler, Adv. Mater., 12, 531 (2000)   DOI   ScienceOn
28 K. N. Lee, H. J. Lee, J. Y. Lee, Y. J. Suh, and J. H. Kim, ACS Symposium Series, 801(12), 152 (2002)
29 P. G. Debenedetti, J. W. Tom, X. Kwauk, and S. D. Yeo, Fluid Phase Equilib., 82, 311 (1993)   DOI   ScienceOn
30 J. Y. Lee and J. H. Kim, Chemistry Letters, 33, 5, 526 (2004)   DOI   ScienceOn
31 K. I. Kim, J. H. An, J. Y. Lee, and J. H. Kim, Applied Chemistry, 7, 69 (2003)
32 J. M. DeSimone, Z. Guan, and C. S. Elsbernd, Science, 257, 945 (1992)   DOI   ScienceOn
33 J. L. Kendall, D. A. Canelas, J. L. Young, and J. M. DeSimone, Chem. Rev., 99, 543 (1999)   DOI   ScienceOn
34 C. F. Kirby, and M. A. Mcllugh, Chem. Rev., 99, 565 (1999)   DOI   ScienceOn
35 M. A. McHugh and V. J. Krukonis, Supercritical Fluid Extraction, 2nd ed., Butterworth-Heinemann, Stoneham, MA (1994)
36 H. H. Winter, G. Gappert, and H. Ito, Macromolecules, 35, 3325 (2002)   DOI   ScienceOn
37 E. Dujardin and S. Mann, Adv. Mater., 14, 775 (2002)   DOI   ScienceOn
38 N. Husing and U. Schubert, Angew. Chem. Int. Ed., 37, 23 (1998)
39 R. Langer and J. P. Vacanti, Science, 260, 920 (1993)   DOI
40 D. J. Abdallah and R. G. Weiss, Adv. Mater., 12, 1237 (2000)   DOI   ScienceOn
41 H. Ohde, M. Ohde, F. Bailey, H. Kim, and C. M. Wai, Nano Lett., 2, 721 (2002)   DOI   ScienceOn
42 R. Y. Hsu, C. S. Tan, and J. M. Chen, J. Appl. Polym. Sci., 84, 1657 (2002)   DOI   ScienceOn
43 J. M. Desimone, Science, 297, 799 (2002)   DOI   ScienceOn
44 K. N. Lee, H. J. Lee, and J. H. Kim, Polymer International, 49(7), 712 (2000)   DOI   ScienceOn
45 M. J. Whitaker, R. A. Quirk, S. M. Howdle, and K. M. Shakesheff, J. Pharm. Pharmacol., 53, 1427 (2001)   DOI   ScienceOn
46 E. Reverchon, J. Supercrit. Fluids, 15, 1 (1999)   DOI   ScienceOn
47 W. S. Koegler, C. Patrick, M. J. Cima, and L. G. Griffith, J. Biomed. Mater. Res., 63, 567 (2002)   DOI   ScienceOn
48 B. J. Zhang, S. A. Davis, and S. Mann, Chem. Mater., 14, 1369 (2002)   DOI   ScienceOn
49 N. R. Cameron, and D. C. Sherrington, Adv. Polym. Sic., 126, 163 (1996)
50 E. J. Beckman, Environ. Sci. Tech., 36, 347A (2002)   DOI   ScienceOn
51 D. J. Dixon, G. Luna-Burcenas, and K. P. Johnston, Polymer, 35, 3998 (1994)   DOI   ScienceOn
52 F. Svec and J. M. J. Frechet, Science, 273, 205 (1996)   DOI   ScienceOn
53 E. de Wolf, G. van Koten, and B. J. Deelman, Chem. Soc. Rev., 28, 37 (1999)   DOI   ScienceOn
54 K. M. K. Yu, A. M. Steele, J. Zhu, Q. J. Fu, and S. C. Tsang, J. Mater. Chem., 13, 130 (2003)   DOI   ScienceOn
55 H. Matsuyama, H. Yano, T. Maid, M. Teramoto, K. Mishima, and K. Matsuya, J. Membrane Sci., 194, 157 (2001)   DOI   ScienceOn
56 W. Busby, N. R. Cameron, and C. A. B. Jahoda, Biomacromolecules, 2, 154 (2001)   DOI   ScienceOn
57 L. P. Barthel-Rosa and J. A. Gladysz, Coord. Chem. Rev., 192, 587 (1999)   DOI   ScienceOn
58 H. Wakayama, S. Inagaki, and Y. Fukushima, J. Am. Ceram. Soc., 85, 161 (2002)   DOI   ScienceOn
59 F. E. Henon, M. Camaiti, A. L. C. Burke, R. G. Carbonell, J. M. DeSimone, and F. Piacenti, J. Supercrit. Fluids, 15, 173 (1999)   DOI   ScienceOn
60 K. A. Arora, A. J. Lesser, and T. J. McCarthy, Macromolecules, 32, 2562 (1999)   DOI   ScienceOn
61 C. Shi, Z. Huang, S. Kilic, J. Xu, R. M. Enick, E. J. Beckman, A. J. Carr, and R. E. Melendez, A. D. Hamilton, Science, 286, 1540 (1999)   DOI   ScienceOn
62 R. Butler, C. M. Davies, and A. I. Cooper, Adv. Mater., 13, 1459 (2001)   DOI   ScienceOn
63 J. J. Watkins and T. J. McCarthy, Chem. Mater., 7, 1991 (1995)   DOI   ScienceOn
64 P. B. Webb, P. C. Marr, A. J. Parsons, H. S. Gidda, and S. M. Howdle, Pure Appl. Chem., 72, 1347 (2000)   DOI   ScienceOn
65 J. Y. Lee, K. N. Lee, H. J. Lee, and J. H. Kim, J. Industry Engineering Chemistry, 8, 546 (2002)
66 J. J. Watkins and T. J. McCarthy, Macromolecules, 27, 4845 (1994)   DOI   ScienceOn
67 P. G. Shah, J. D. Holmes, R. C. Doty, K. P. Johnston, and B. A. Korgel, J. Am. Chem. Soc., 122, 4245 (2000)   DOI   ScienceOn
68 F. Svec and J. M. J. Frechet, Ind. Eng. Chem. Res., 38, 34 (1998)   DOI   ScienceOn
69 M. J. Whitcombe and E. N. Vulfson, Adv. Mater., 13, 467 (2001)   DOI   ScienceOn
70 E. Kung, A. J. Lesser, and T. J. McCarthy, Macromolecules, 31, 4160 (1997)   DOI   ScienceOn
71 P. Rajagopalan and T. J. McCarthy, Macromolecules, 31, 4791 (1998)   DOI   ScienceOn
72 F. Placin, J. P. Desvergne, and F. Cansell, J. Mater. Chem., 10, 2147 (2000)   DOI   ScienceOn
73 M. Poliakoff, J. M. Fitzpatrick, T. R. Farren, and P. T. Anastas, Science, 297, 807 (2002)   DOI   ScienceOn
74 K. I. Kim, J. H. An, J. Y. Lee, and J. H. Kim, Polymeric Materials: Science & Engineering, 89, 320 (2003)
75 N. R. B. Coleman, N. O'Sullivan, K. M. Ryan, T. A. Crowley, M. A. Morris, T. R. Spalding, D. C. Steytler, and J. D. Holmes, J. Am. Chem. Soc., 123, 7010 (2001)   DOI   ScienceOn
76 A. I. Cooper, J. Mater. Chem., 10, 207 (2000)   DOI   ScienceOn
77 J. Abeln, M. Kluth, G. Petrich, and H. Schmieder, High Press. Res., 20, 537 (2001)   DOI   ScienceOn
78 C. D. Wood and A. I. Cooper, Macromolecules, 34, 5 (2001)   DOI   ScienceOn
79 M. Ji, X. Y. Chen, C. M. Wai, and J. L. Fulton, J. Am. Chem. Soc., 121, 2631 (1999)   DOI   ScienceOn
80 J. J. Watkins and T. J. McCarthy, Macromolecules, 28, 4067 (1995)   DOI   ScienceOn
81 F. Rindfleisch, T. P. DiNoia, and M. A. McHugh, J. Phys. Chem., 100, 15581 (1996)   DOI   ScienceOn
82 S. G. Kazarian, Macromol. Symp., 184, 215 (2002)
83 J. W. Tom and P. G. Debenedetti, J. Aerosol Sci., 22, 555 (1991)   DOI   ScienceOn
84 A. Blasig, C. M. Shi, R. M. Enick, and M. C. Thies, Ind. Eng. Chem. Res., 41, 4976 (2002)   DOI   ScienceOn
85 C. F. Kirby and M. A. McHugh, Chem. Rev., 99, 565 (1999)   DOI   ScienceOn
86 A. I. Cooper, C. D. Wood, and A. B. Holmes, Ind. Eng. Chem. Res., 39, 4741 (2000)   DOI   ScienceOn
87 H. Ohde, J. M. Rodriguez, Y. Xiang-Rong, and C. M. Wai, Chem. Commun., 2353 (2000)
88 K. S. Morley, P. C. Marr, P. B. Webb, A. R. Berry, F. J. Allison, G. MoldoP. D. Brown, and S. M. Howdle, J. Mater. Chem., 12, 1898 (2002)   DOI   ScienceOn
89 A. K. Hebb, K. Senoo, R. Bhat, and A. I. Cooper, Chem. Mater., 15, 2061 (2003)   DOI   ScienceOn
90 S. Siripurapu, Y. J. Gay, J. R. Royer, J. M. DeSimone, R. J. Spontak, and S. A. Khan, Polymer, 43, 5511 (2002)   DOI   ScienceOn
91 Y. Fukushima and H. Wakayama, J. Phys. Chem. B, 103, 3062 (1999)   DOI   ScienceOn
92 H. Wakayama and Y. Fukushima, Chem. Mater., 12, 756 (2000)   DOI   ScienceOn
93 B. Krause, G. H. Koops, N. F. A. van der Vegt, M. Wessling, M. Wubbenhorst, and J. van Turnhout, Adv. Mater., 14, 1041 (2002)   DOI   ScienceOn
94 H. Wakayama and Y. Fukushima, Chem. Commun., 391 (1999)
95 R. A. Caruso, M. Giersig, F. Willig, and M. Antonietti, Langmuir, 14, 6333 (1998)   DOI   ScienceOn
96 A. S. O'Neil, R. Mokaya, and M. Poliakoff, J. Am. Chem. Soc., 124, 10636 (2002)   DOI   ScienceOn
97 Y. Chemyak, F. Henon, R. B. Harris, R. D. Gould, R. K. Franklin, J. R. Edwards, J. M. DeSimone, and R. G. Carbonell, Ind. Eng. Chem. Res., 40, 6118 (2001)   DOI   ScienceOn
98 Z. H. Huang, C. M. Shi, R. Enick, and E. Beckman, Chem. Mater., 14, 4273 (2002)   DOI   ScienceOn
99 C. Yu, M. C. Xu, F. Svec, and J. M. J. Frechet, J. Polym. Sci. A, Polym. Chem., 40, 755 (2002)   DOI   ScienceOn
100 J. Y. Ying, C. P. Mehnert, and M. S. Wong, Angew. Chem. Int. Ed., 38, 56 (1999)   DOI   ScienceOn
101 A. I. Cooper and A. B. Holmes, Adv. Mater., 11, 1270 (1999)   DOI   ScienceOn
102 H. Matsuyama, A. Yamamoto, H. Yano, T. Maki, M. Teramoto, K. Mishima, and K. Matsuyama, J. Membrane Sci., 204, 81 (2002)   DOI   ScienceOn
103 J. L. Owens, K. S. Anseth, and J. W. Randolph, Macromolecules, 35, 4289 (2002)   DOI   ScienceOn
104 D. A. Loy, E. M. Russick, S. A. Yamanaka, B. M. Baugher, and K. J. Shea, Chem. Mater., 9, 2264 (1997)   DOI   ScienceOn
105 H. Zhang and A. I. Cooper, Chem. Mater., 14, 4017 (2002)   DOI   ScienceOn
106 P. S. Shah, J. D. Holmes, K. P. Johnston, and B. A. Korgel, J. Phys. Chem. B, 106, 2545 (2002)   DOI   ScienceOn
107 J. Y. Lee, K. I. Kim, and J. H. Kim, J. of Korean Ind. Eng. Chem., 13, 623 (2002)
108 X. Yang, R. S. Tare, K. A. Partridge, H. I. Roach, N. M. P. Clarke, S. M. Howdle, K. M. Shakesheff, and R. O. C. Oreffo, J. Bone Miner. Res., 18, 47 (2003)   DOI   ScienceOn
109 D. D. Hile and M. V. Pishko, Macromol. Rapid Commun., 20, 511 (1999)   DOI
110 J. Zhang, A. J. Busby, C. J. Roberts, X. Chen, M. C. Davies, S. J. B. Tendler, and S. M. Howdle, Macromolecules, 35, 8869 (2002)   DOI   ScienceOn