• 제목/요약/키워드: nParticle

검색결과 1,373건 처리시간 0.031초

Metal Nano Particle modified Nitrogen Doped Amorphous Hydrogenated Diamond-Like Carbon Film for Glucose Sensing

  • Zeng, Aiping;Jin, Chunyan;Cho, Sang-Jin;Seo, Hyun-Ook;Lim, Dong-Chan;Kim, Doo-Hwan;Hong, Byung-You;Boo, Jin-Hyo
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.434-434
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    • 2011
  • Electrochemical method have been employed in this work to modify the chemical vapour deposited nitrogen doped hydrogen amorphous diamond-like carbon (N-DLC) film to fabricate nickel and copper nano particle modified N-DLC electrodes. The electrochemical behaviour of the metal nano particle modified N-DLC electrodes have been characterized at the presence of glucose in electrolyte. Meanwhile, the N-DLC film structure and the morphology of metal nano particles on the N-DLC surface have been investigated using micro-Raman spectroscopy, X-ray photoelectron spectroscopy and atomic force microscopy. The nickel nano particle modified N-DLC electrode exhibits a high catalytic activity and low background current, while the advantage of copper modified N-DLC electrode is drawn back by copper oxidizations at anodic potentials. The results show that metal nano particle modification of N-DLC surface could be a promising method for controlling the electrochemical properties of N-DLC electrodes.

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The Effects of TiN Particles on the HAZ Microstructure and Toughness in High Nitrogen TiN Steel

  • Jeong, H.C.;An, Y.H.;Choo, W.Y.
    • International Journal of Korean Welding Society
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    • 제2권1호
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    • pp.25-28
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    • 2002
  • In the coarse grain HAZ adjacent to the fusion line, most of the TiN particles in conventional Ti added steel are dissolved and austenite grain growth is easily occurred during welding process. To avoid this difficulty, thermal stability of TiN particle is improved by increasing the nitrogen content in steel. In this study, the effect of hlgh nitrogen TiN particle on preventing austenite grain growth in HAZ was investigated. Increased thermal stability of TiN particle is helpful for preventing the austenite grain growth by pinning effect. High nitrogen TiN particle in simulated HAZ were not dissolved even at high temperature such as 1400'E and prevented the austenite grain growth in simulated HAZ. Owing to small austenite grain size in HAZ the width of coarse grain HAZ in high nitrogen TiN steel was decreased to 1/10 of conventional TiN steel. Even high heat input welding, the microstructure of coarse grain HAZ consisted of fine polygonal ferrite and pearlite and toughness of coarse grain HAZ was significantly improved.

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서스펜션 중에서 입자의 형태와 크기가 침강특성에 미치는 영향 (The Effect of Particle Shape and Size on the Settling Characteristics in Suspension)

  • 이기종
    • 한국재료학회지
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    • 제4권8호
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    • pp.927-933
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    • 1994
  • 비구형 입자들의 크기와 형태에 따른 침강 특성의 영향을 검토하였다. 비구형입자를 포함하는 서스펜션의 침강에서 $log \mu_{c}$$log \varepsilon$로부터 얻은 기울기 지표n값은 형태와 크기가 다른 입자는 같은 부피 농도에서 흡착되는유체량이 달라져 입자크기가 감소하거나 불균일한 경우 증가하는 경향을 나타내었다. 실험결고 비구형입자를 포함하는 서스펜션의 침강에서 기울기 지표 $n_{i}$값에 대하여 $n_{i}=n(a+b/d_{v})$와 같은 식을 얻었으며 이때 a, b는 입자형태에 따른 상수이다.

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In-line (α,n) source sampling methodology for monte carlo radiation transport simulations

  • Griesheimer, David P.;Pavlou, Andrew T.;Thompson, Jason T.;Holmes, Jesse C.;Zerkle, Michael L.;Caro, Edmund;Joo, Hansem
    • Nuclear Engineering and Technology
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    • 제49권6호
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    • pp.1199-1210
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    • 2017
  • A new in-line method for sampling neutrons emitted in (${\alpha}$,n) reactions based on alpha particle source information has been developed for continuous-energy Monte Carlo simulations. The new method uses a continuous-slowing-down model coupled with (${\alpha}$,n) cross section data to precompute the expected neutron yield over the alpha particle lifetime. This eliminates the complexity and computational cost associated with explicit charged particle transport. When combined with an integrated alpha particle decay source sampling capability, the proposed method provides an efficient and accurate method for sampling (${\alpha}$,n) neutrons based solely on nuclide inventories in the problem, with no additional user input required. Results from several example calculations show that the proposed method reproduces the (${\alpha}$,n) neutron yields and energy spectra from reference experiments and calculations.

입방체 TiN 석출물에 의한 오스테나이트 결정립 성장 억제 효과 (Pinning efficiency of austenite grain boundary by Cubic shaped TiN particle : Modification of Zener coefficient for Cubic shaped particle)

  • 문준오;유종근;이창희;안영호;이종봉
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2005년도 춘계학술발표대회 개요집
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    • pp.158-160
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    • 2005
  • Zener coefficient on cubic shaped particle was proposed. Most previous researches about Zener coefficient were developed on the assumption that the shape of particle is spherical. But, some particle has other shape, and modification of Zener coefficient needs with shape of particle. In this research, TiN particle that has a cubic shape was considered. A Zener coefficient of a cubic shape TiN was theoretically calculated with appropriate assumptions. And, using a semi-empirical method, Zener coefficient was also measured. Finally, the proposed Zener coefficient was proved by comparing with experimentally measured data.

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AIP-TiN/WC-Co계에서 WC입자크기와 Co함량이 밀착력에 미치는 영향 (Effect of the WC particle size and Co content on the adhesion property between AIP-TiN coating and WC-Co substrate)

  • 한대석;류정민;권식철;김광호
    • 한국표면공학회지
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    • 제35권3호
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    • pp.165-171
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    • 2002
  • TiN coating were deposited onto different WC-Co substrates using arc ion plating (AIP) technique. The structure and morphology for the deposited coating were characterized by x-ray diffraction (XRD) and scanning electron microscopy (SEM). The adhesion behavior of the deposited TiN coating was investigated with a conventional scratch test. Effects of WC particle size and Co content on the adhesion strength between the deposited TiN coating and substrate were studied. During the scratch test, the value of critical load was dependent of WC particle size and Co content on substrate. As the WC particle size and Co content on substrate decreased, the critical load increased. The highest critical load, approximately 110N, was obtained at WC particle size of 1$\mu\textrm{m}$ and Co content of 10wt.%.

GIS내 파티클의 상태에 따른 부분방전 신호의 분석 (The analysis of partial discharge signals according to particle states in GIS)

  • 김경화;이동준;곽희로
    • 조명전기설비학회논문지
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    • 제14권1호
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    • pp.67-74
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    • 2000
  • 본 논문에서는 GIS내 파티클에 의해 발생할 수 있는 절연사고를 미연에 방지하고 또한 파티클의 상태를 파 악하기 위하여 GIS 41 파티클 상태에 따른 부분방전 신호를 측정하고 분석하였다. 본 논문에서는 GIS내 파티콜 의 상태를 4가지(전극부착시, 외함부착시, 스페이서 부착시, 자유운동시)로 모의하였으며, 이때 발생하는 부분방전 신호의 $\Phi$-Q-N 분포를 형태적으로 분석하였다 또한, $\Phi$-Q 분포에 대하여 통계적 연산자를 도입하여 파티 클 상태에 따른 부분방전 신호를 정량적으로 분석하였다. 그 결과 파티클 상태에 따른 $\Phi$-Q-N 분포의 형태적인 분석과 $\Phi$-Q 분포의 정량적인 분석으로 파티콜의 상태 구별이 가능하였다.

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THE EFFECTS OF TiN PARTICLES ON THE HAZ MICROSTRUCTURE AND TOUGHNESS IN HIGH NITROGEN TiN STEEL

  • Jeong, Hong-Chul;An, Young-Ho;Choo, Wung-Yong
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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    • pp.217-221
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    • 2002
  • In the coarse grain HAZ adjacent to the fusion line, most of the TiN particles in conventional Ti added steel are dissolved and austenite grain growth is easily occupied during welding process. To avoid this difficulty, thermal stability of TiN particle is improved by increasing the nitrogen content in steel. In this study, the effect of high nitrogen TiN particle on preventing austenite grain growth in HAZ was investigated. Increased thermal stability of TiN particle is helpful for preventing the austenite grain growth by pinning effect. High nitrogen TiN particle in simulated HAZ were not dissolved even at high temperature such as 1400 C and prevented the austenite grain growth in simulated HAZ. Owing to small austenite grain size in HAZ the width of coarse grain HAZ in high nitrogen TiN steel was decreased to 1/10 of conventional TiN steel. Even high heat input welding, the microstructure of coarse grain HAZ consisted of fine polygonal ferrite and pearlite and toughness of coarse grain HAZ was significantly improved.

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스티렌/노말 부틸 메타크릴레이트와 알루미나의 분산 공중합에 관한 연구 (A Study on Dispersion Copolymerization of Styrene/n-Butylmethacrylate and Alumina)

  • 방현수;조을룡
    • 폴리머
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    • 제32권6호
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    • pp.549-554
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    • 2008
  • 분산중합법에 의해 고분자 미립자를 합성하기 위해 스티렌과 n-butylmethacrylate가 알루미나와 함께 중합되었다. 스티렌과 n-butylmethacrylate의 비는 3 : 1이었고, 입자안정제는 poly (N-vinyl pyrrolidon), 중합 개시제로는 2,2'-azobis(isobutyronitrile)를 커플링제는 3-methacryloxypropyl trimethoxysilane을, 분산매로 이소프로판올과 이온교환수를 70 : 30의 비로 사용하였다. TEM 사진을 통해 알루미나가 고분자 미립자에 분산되어 있음을 확인하였고 알루미나의 농도가 증가함에 따라 평균 입자경이 증가하였으며 입자경 분포는 감소되는 경향을 보였다. XRD 측정에 의해 알루미나의 농도 증가는 피크 강도와 2$\theta$값의 증가를 보였으며 TGA 측정으로 알루미나의 농도의 증가는 고분자 미립자의 내열성을 증가시킴을 알 수 있었다. 사용한 개시제의 반감기가 길수록 입자경은 감소하였고 입자인정제의 농도가 증가할수록 반응초기의 핵생성이 증가하여 입자경이 또한 감소함을 알 수 있었다.

제주 고산에서 2009년 가을에 관측된 입자 생성 및 성장 현상의 특성 (Characteristics of New Particle Formation and Growth Events Observed at Gosan Climate Observatory in Fall 2009)

  • 김유미;김상우;윤순창;장임석;이석조;이미혜;김지형
    • 대기
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    • 제21권1호
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    • pp.35-44
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    • 2011
  • We investigated characteristics of new particle formation and growth events observed at Gosan climate observatory using Scanning Mobility Particle Sizer (SMPS) measurements of particle number size distribution with 54 size ranges from 10 to 487 nm in October 2009. Four days (17~20 October) and five days (22~26 October) were classified into strong new particle formation and growth event ($N_S$) and weak particle formation and growth event ($N_W$), respectively. $N_S$ and $N_W$ divided by increase of aerosol number concentration in nucleation mode and continuity of growth from nucleation to Aitken mode. Particle growth rates of $N_S$ (5.34~$9.19nm\;h^{-1}$) were greater than that of $N_W$ (2.15~$3.53nm\;h^{-1}$). $N_S$ and $N_W$ were analyzed with synoptic pattern over East Asia, meteorological elements, and sulfur dioxide ($SO_2$) measured at Gosan. We found that $N_S$ was characterized by a fast and northwesterly wind accompanied cold and dry airmass, but $N_W$ was affected airmass originated from South China and come through the Korea Peninsula. The events ($N_S$ and $N_W$) occurred at conditions of high solar flux ($&gt;700W\;m^{-2}$) and low relative humidity (< 60%). The $SO_2$ concentration on $N_S$ and $N_W$ was higher than that on case of non observed new particle formation.