• Title/Summary/Keyword: n-doped

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A Study on Characteristics of ZnO/n-Si Low Cost Solar Cells (ZnO/n-Si 저가 박막태양전지의 특성연구)

  • Baik, D.G.;Cho, S.M.
    • Solar Energy
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    • v.19 no.1
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    • pp.29-36
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    • 1999
  • ZnO/n-Si junctions were fabricated by spin coating with ZnO precursor produced by the sol-gel process. In order to increase the electrical conductivity of ZnO films, the films were n-doped with Al impurity and subsequently annealed at about $450^{\circ}C$ under reducing environments. The ohmic contacts between n-Si and AI for a bottom electrode were successfully fabricated by doping the rear surface of Si substrate with phosphorous atoms. The front surface of the substrate was also doped with phosphorous atoms for improving the efficiency of the solar cells. Consequently, conversion efficiencies ranging up to about 5.3% were obtained. These efficiencies were found to decrease slowly with time because of the oxide films formed at the ZnO/Si interface upon oxygen penetration through the porous ZnO. Oxygen barrier layers could be necessary in order to prevent the reduction of conversion efficiencies.

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Nitrogen Doping Characterization of ZnO Prepared by Atomic Layer Deposition (원자층 증착법으로 성장된 ZnO 박막의 질소 도핑에 대한 연구)

  • Kim, Doyoung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.10
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    • pp.642-647
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    • 2014
  • For feasible study of opto-electrical application regarding to oxide semiconductor, we implemented the N doped ZnO growth using a atomic layer deposition technique. The p-type ZnO deposition, necessary for ZnO-based optoelectronics, has considered to be very difficulty due to sufficiently deep acceptor location and self-compensating process on doping. Various sources of N such as $N_2$, $NH_3$, NO, and $NO_2$ and deposition techniques have been used to fabricate p-type ZnO. Hall measurement showed that p-type ZnO was prepared in condition with low deposition temperature and dopant concentration. From the evaluation of photoluminescence spectroscopy, we could observe defect formation formed by N dopant. In this paper, we exhibited the electrical and optical properties of N-doped ZnO thin films grown by atomic layer deposition with $NH_3OH$ doping source.

Magnetic Properties of Cu-doped AlN Semiconductor (AlN 반도체와 Cu의 도핑 농도에 대한 자성)

  • Kang, Byung-Sub;Lee, Haeng-Ki
    • Journal of the Semiconductor & Display Technology
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    • v.9 no.3
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    • pp.1-4
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    • 2010
  • First-principles calculations based on spin density functional theory are performed to study the spin-resolved electronic properties of AlN doped with a Cu concentration of 6.25%-18.75%. The ferromagnetic state is more energetically favorable state than the antiferromagnetic state or the nonmagnetic state. For $Al_{0.9375}Cu_{0.0625}N$, a global magnetic moment of 1.26 mB per supercell, with a localized magnetic moment of 0.75 $m_B$ per Cu atom is found. The magnetic moment is reduced due to an increase in the number of Cu atoms occupying adjacent cation lattice position. For $Al_{0.8125}Cu_{0.1875}N$, the magnetism of the supercell disappears by the interaction of the neighboring Cu atoms. The nonmagnetic to ferromagnetic phase transition is found to occur at this Cu concentration. The range of concentrations that are spin-polarized should be restricted within very narrow.

Influence of Nitrogen Doping and Surface Modification on Photocatalytic Activity of $TiO_2$ Under Visible Light

  • Jeong, Bora;Park, Eun Ji;Jeong, Myung-Geun;Yoon, Hye Soo;Kim, Young Dok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.130.1-130.1
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    • 2013
  • We made attempts to improve photocatalytic activity of $TiO_2$ nanoparticles under visible light exposure by combining two additional treatments. N-doping of $TiO_2$ by ammonia gas treatment at $600^{\circ}C$ increased absorbance of visible light. By coating thin film of polydimethylsiloxane (PDMS), and subsequent vacuum-annealing at $800^{\circ}C$, $TiO_2$, became more hydrophilic, thereby enhancing photocatalytic activity of $TiO_2$. Four types of $TiO_2$ samples were prepared, bare-$TiO_2$, hydrophilic-modified $TiO_2$ ($h-PDMS/TiO_2$), N-doped $TiO_2$ ($N/TiO_2$) and hydrophilic-modified and N-doped $TiO_2$ ($h-PDMS/N/TiO_2$). Adsorption capability was evaluated under dark condition and photocatalytic activity of $TiO_2$ was evaluated by photodegradation of MB under blue LED (400 nm< ${\lambda}$) irradiation. N-doping on $TiO_2$ was characterized using XPS and hydrophilic modification of $TiO_2$ surface was analyzed by FT-IR spectrometer. It was found that N-doping and hydrophilic modification both had positive effect on enhancing adsorption capability and photocatalytic activity of $TiO_2$ at the same time. Particularly, N-doping enhanced visible light absorption of $TiO_2$, whereas hydrophilic surface modification increased MB adsorption capacity. By combining these two strategies, photocatalytic acitivity under visible light irradiation became the sum of individual effects of N-doping and hydrophilic modification.

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A study on GaN thin film and GaN nanowire doped with neutron-transmuted isotopes (중성자를 이용한 GaN박막과 GaN 나노와이어의 핵전환 도핑)

  • Kang, Myung-Il;Kim, Hyun-Suk;Lee, Jong-Soo;Kim, Sang-Sig;Han, Hyon-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.41-45
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    • 2003
  • Impurities transmuted in GaN thin film and GaN nanowires after neutron irradiation are studied in this work. The structural properties of GaN nanowires were shown using by Transmission Electron Microscope(TEM). Transmuted impurities that are expected to be doped into GaN thin film and GaN nanowires are then confirmed by photoluminescence(PL). Transmuted atom in GaN materials is Ge atom, Ge-related peaks in GaN thin film lead to emit at 2.9eV, 2.25eV. But emission bands at 2.9eV, 2.25eV are not shown in PL spectra of GaN nanowires. Our experimental results are expected to give deep impact on nano-material doping technology for the achievement of the fabrication of nano-devices.

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Effect of Targets on Synthesis of Aluminum Nitride Thin Films Deposited by Pulsed Laser Deposition (펄스레이저법으로 증착 제조된 AlN박막의 타겟 효과)

  • Chung, J.K.;Ha, T.K.
    • Transactions of Materials Processing
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    • v.29 no.1
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    • pp.44-48
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    • 2020
  • Aluminum nitride (AlN), as a substrate material in electronic packaging, has attracted considerable attention over the last few decades because of its excellent properties, which include high thermal conductivity, a coefficient of thermal expansion that matches well with that of silicon, and a moderately low dielectric constant. AlN films with c-axis orientation and thermal conductivity characteristics were deposited by using Pulsed Laser Deposition (PLD). The epitaxial AlN films were grown on sapphire (c-Al2O3) single crystals by PLD with AlN target and Y2O3 doped AlN target. A comparison of different targets associated with AlN films deposited by PLD was presented with particular emphasis on thermal conductivity properties. The quality of AlN films was found to strongly depend on the growth temperature that was exerted during deposition. AlN thin films deposited using Y2O3-AlN targets doped with sintering additives showed relatively higher thermal conductivity than while using pure AlN targets. AlN thin films deposited at 600℃ were confirmed to have highly c-axis orientation and thermal conductivity of 39.413 W/mK.

The Effect of N2 Gas Doping on Sb2Te3Thin Film for PRAM Recording Layer (PRAM 기록막용 Sb2Te3 박막의 질소 첨가에 대한 영향)

  • Bae, Jun-Hyun;Cha, Jun-Ho;Kim, Kyoung-Ho;Kim, Byung-Geun;Lee, Hong-Lim;Byeon, Dae-Seop
    • Journal of the Korean Ceramic Society
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    • v.45 no.5
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    • pp.276-279
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    • 2008
  • In this research, properties of $N_2$-doped $Sb_2Te_3$ thin film were evaluated using 4-point probe, XRD and AFM. $Sb_2Te_3$ material has faster crystallization rate than $Ge_2Sb_2Te_5$, but sheet resistance difference between amorphous and crystallization state is very low. This low sheet resistance difference decreases sensing margin in reading operation at PRAM device operation. Therefore, in order to overcome this weak point, $N_2$ gas was doped on $Sb_2Te_3$ thin film. Sheet resistance difference between amorphous and crystallized state of $N_2$-doped $Sb_2Te_3$ thin film showed about $10^4$ times higher than Un-doped $Sb_2Te_3$ thin film because of the grain boundary scattering.

Wideband Gain Flattened Hybrid Erbium-doped Fiber Amplifier/Fiber Raman Amplifier

  • Afkhami, Hossein;Mowla, Alireza;Granpayeh, Nosrat;Hormozi, Azadeh Rastegari
    • Journal of the Optical Society of Korea
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    • v.14 no.4
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    • pp.342-350
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    • 2010
  • An optimal wideband gain flattened hybrid erbium-doped fiber amplifier/fiber Raman amplifier (EDFA/FRA) has been introduced. A new and effective optimization method called particle swarm optimization (PSO) is employed to find the optimized parameters of the EDFA/FRA. Numerous parameters which are the parameters of the erbium-doped fiber amplifier (EDFA) and the fiber Raman amplifier (FRA) define the gain spectrum of a hybrid EDFA/FRA. Here, we optimize the length, $Er^{3+}$ concentration, and pump power and wavelength of the EDFA and also pump powers and wavelengths of the FRA to obtain the flattest operating gain spectrum. Hybrid EDFA/FRA with 6-pumped- and 10-pumped-FRAs have been studied. Gain spectrum variations are 1.392 and 1.043 dB for the 6-pumped- and 10-pumped-FRAs, respectively, in the 108.5 km hybrid EDFA/FRAs, with 1 mW of input signal powers. Dense wavelength division multiplexing (DWDM) system with 60 signal channels in the wavelength range of 1529.2-1627.1 nm, i.e. the wide bandwidth of 98 nm, is studied. In this work, we have added FRA's pump wavelengths to the optimization parameters to obtain better results in comparison with the results presented in our previous works.

Theoretical Analysis of a $1.48{\mu}m$ Diode Laser Pumped $Er^{3+}$ Doped Fiber Amplifier ($1.48{\mu}m$ 레이저 다이오드로 여기된 $Er^{3+}$ 첨가 광섬유 광증폭기에 대한 이론적 분석)

  • 김회종
    • Korean Journal of Optics and Photonics
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    • v.4 no.1
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    • pp.101-107
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    • 1993
  • We carried out the useful theoretical calculation for the optimum design of a 1.48 ${\mu}m$ diode laser pumped E$r^{3+}$ doped fiber amplifier. The model we established is based on the rate equations of three level laser system and the overlap integral between fundamental mode L$P_{01}$ and E$r^{3+}$ doped area. We determined several fiber parameters (N.A., V value, fiber length, E$r^{3+}$ concentration, cutoff wavelength etc.) for the optimum design of a high optical gain. We found that our theoretical results are very useful to the design of E$r^{3+}$ doped fiber used in EDFA.

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Continuous and Pulsed Laser Induced Copper Deposition on Silicon(Si) from Liquid Electrolyte (전해질 용액내의 실리콘 단결정 표면에서 레이저로 유기되는 구리 침착)

  • 유지영;안창남;이상수
    • Korean Journal of Optics and Photonics
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    • v.3 no.1
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    • pp.50-54
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    • 1992
  • Maskless depositon of copper onto n-doped and p-doped Si in an aqueous copper sulfate solution is investigated. On p-doped Si substrates, microscopic $(~10\mu\textrm{m}$) copper spots are deposited by illuminating continuous wave $Ar^+$ laser beam of wavelength 514.5 nm. Copper deposition on n-doped Si substrates is also achieved by shinning second harmonic pulses $(pulse width~25 nsec, \lambda=530 nm)$ of a passively Q-switched Nd:YAG laser. The observed deposition is attributed to the electric field resulting from the Galvanic potential of a semiconductor-electrolyte junction.

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