• Journal of ILASS-Korea
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• v.19 no.4
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• pp.188-196
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• 2014

The spray and combustion characteristics of n-dodecane fuel were investigated in a CVCC (constant volume combustion chamber). The selection of ambient conditions for the spray followed ECN (engine combustion network) guidelines, which simulates the ambient condition of diesel engines at start of fuel injection. ECN is a collaboration network whose main objective is to establish an internet library of well-documented experiments that are appropriate for model validation and the advancement of scientific understanding of combustion at conditions specific to engines. Therefore repeatability of the experiments with high accuracy was important. The ambient temperature was varied from 750 to 930 K while the density was fixed at around $23kg/m^3$. The injection pressure of the fuel was varied from 500 to 1500 bar. The spray was injected in both non-reacting ($O_2$ concentration of 0%) and reacting conditions ($O_2$ concentration of 15%) to examine the spray and the combustion characteristics. Direct imaging with Mie Scattering was used to obtain the liquid penetration length. Shadowgraph was implemented to observe vapor length and lift-off length at non-reacting and reacting conditions, respectively. Pressure data was analyzed to determine the ignition delay with respect to the spray and ambient conditions.

• Transactions of the Korean Society of Automotive Engineers
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• v.21 no.2
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• pp.37-44
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• 2013

Generally, a reduced chemical mechanism of n-heptane is used as chemical fuel of a 3-D diesel engine simulation because diesel fuel consists of hundreds of chemical components and various chemical classes so that it is very complex and large to use for the calculation. However, the importance of fuel in a 3-D simulation increases because detailed fuel characteristics are the key factor in the recent engine research such as homogeneous charged compression ignition engine. In this study, normal paraffin, iso paraffin and aromatics were selected to represent diesel characteristics and n-dodecane was used as a representative normal paraffin to describe the heavy molecular weight of diesel oil (C10~C20). Reduced kinetics of iso-octane and toluene which are representative species of iso paraffin and aromatics respectively were developed in the previous study. Some species were selected based on the sensitivity analysis and a mechanism was developed based on the general oxidation scheme. The ignition delay times, maximum pressure and temperature of the new reduced n-dodecane chemical mechanisms were well matched to the detailed mechanism data.

• Analytical Science and Technology
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• v.21 no.5
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• pp.403-411
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• 2008

Dimethyldibutyltetradecylmalonamide (DMDBTDMA) extractant was used in a solvent extraction process for a radioactive liquid waste treatment. For the study of radiolysis phenomena, DMDBTDMA was synthesized and the degradation compounds (n-methylbutylamine, tetradecane, 1-tetradecanol) in the DMDBTDMA extractant, irradiated with $^{60}Co$ gamma ray, were identified and determined as radiolysis products by a Fourier transform infrared (FT-IR), gas chromatograph/mass spectrometer (GC/MS) analysis and GC/MS with selected ion monitoring (SIM) mode. Retention behavior of n-methylbutylamine, n-dodecane, tetradecane and 1-tetradecanol in the total ion chromatogram with the standard materials and n-dodecane as the internal standard (ISTD) were 2.35 min., 8.83 min., 10.68 min. and 12.75 min., respectively. In the case of tetradecane, there was a linear relationship between the concentration of the tetradecane and the absorbed dose of the ${\gamma}$-ray irradiated DMDBTDMA.

• Biotechnology and Bioprocess Engineering:BBE
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• v.11 no.3
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• pp.245-250
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• 2006

The effects of aliphatic hydrocarbons (n-hexadecane and n-dodecane) on the volumetric oxygen mass transfer coefficient $(k_L\;a)$ were studied in flat alveolar airlift reactor and continuous stirred tank reactors (CSTRs). In the flat alveolar airlift reactor, high aeration rates (>2vvm) were required in order to obtain efficient organic-aqueous phase dispersion and reliable $k_La$ measurements. Addition of 1% (v/v) n-hexadecane or n-dodecane increased the $k_La$ 1.55- and 1.33-fold, respectively, compared to the control (superficial velocity: $25.8{\times}10^{-3}m/s$, sparger orifice diameter: 0.5 mm). Analysis of the gas-liquid interfacial area a and the liquid film mass transfer coefficient $k_L$ suggests that the observed $k_La$ increase was a function of the media's liquid film mass transfer. Addition of 1% (v/v) n-hexadecane or n-dodecane to analogous setups using CSTRs led to a $k_La$ increase by a factor of 1.68 and 1.36, respectively (superficial velocity: $2.1{\times}10^{-3}m/s$, stirring rate: 250 rpm). These results propose that low-concentration addition of oxygen-vectors to aerobic microbial cultures has additional benefit relative to incubation in purely aqueous media.

• Journal of Korea Soil Environment Society
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• v.1 no.2
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• pp.61-72
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• 1996

A series of batch and lab-scale continuous tests were conducted to optimize the design parameters for the full-scale in-situ soil flushing experiments. The cleaning abilities of the surfactant solutions of Tween 80, Triton X-100 and SDS were compared for the soil artificially contaminated by hydrophobic organic contaminants: n-dodecane, naphthalene and anthracene. Tween 80 and Triton X-100 were shown to be efficient for n-dodecane. SDS and Tween 80 were shown to be efficient for naphthalene and anthracene. At the end of each column test, the sorbed amount of surfactant to soil was also measured. Tween 80 was found to be the least adsorbed surfactant to soil. The flushing ability at flowrate of 7 ml/min, was hampered comparing to flowrate of 3 and 5 ml/min. Initial pH of the soil did not significantly affect the flushing efficiencies. Tween 80 was determined as the most harmless surfactant for the Gram(+) and Gram(-) bacteria.

• Journal of the Korean Magnetic Resonance Society
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• v.2 no.1
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• pp.1-23
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• 1998

The motions of carbon-chain backbone in n-undecance and n-dodecane dissolved in CDCl3 are investigated by 13C NMR relaxation study. For this purpose a model of C - C backbone motions for these molecules is introduced that takes into account the cooperativities between rotations about two $\beta$-coupled C - C bonds. In this model it is assumed that the major conformational interconversions occurring in the inner part of the chain involve the type II jumps only, although at terminal part of the chain both type II and type III motions are assumed to take place. Information of the rate constants of these conformational transitions could be extracted by comparing the T1's calculated on the basis of the assumed model with those observed over the temperature range of 248 - 308 K. The calculations were performed according to the method proposed by Wittebort and Szabo. The activation energies, ranging from ca 12 to 20 kJ/mol, could be obtained from the Arrhenius plots of these calculated rate constants.

• Journal of the Korean Society of Propulsion Engineers
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• v.15 no.5
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• pp.1-9
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• 2011

Researches on hypersonic aircraft technologies have been carried out to increase flight speeds. However, increase in flight speeds causes heat loads that could lead structural change of aircraft's component. Researches on cooling technologies using endothermic fuels are progressing in the USA, France and Russia to treat the heat loads. Endothermic fuels are liquid hydrocarbon aircraft fuels which are able to absorb the heat loads by undergoing endothermic reactions, such as thermal and catalytic cracking. In this study, methylcyclohexane, n-octane, and n-dodecane were selected as model endothermic fuels and experiments in endothermic properties were implemented. Experimental conditions were supercritical condition of each model fuels in which actual endothermic fuels were exposed. The object of this study is to identify endothermic properties of the model endothermic fuels and to predict endothermic properties of actual fuels such as kerosene fuels.

• Korean Chemical Engineering Research
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• v.47 no.1
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• pp.24-30
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• 2009

In this study, solubilization experiments of n-decane, n-undecane and n-dodecane oil were performed by micellar solutions of polymeric nonionic surfactant Pluronic L64($EO_{13}PO_{30}EO_{13}$) at room temperature. A single spherical drop of hydrocarbon oil was injected into aqueous surfactant solution using an oil drop contacting technique and solubilization rate of hydrocarbon oil was measured by observing the size of oil drop with time. It was shown that solubilization rate decreased with the alkane carbon number(ACN) of the hydrocarbon oil. The solubilization rate was also found to be independent of initial oil dorp size and almost linearly proportional to the initial surfactant concentration. These results revealed that solubilization of n-decane, n-undecane and n-dodecane oils by L64 micellar solution is controlled by interface-controlled mechanism but not by diffusion-controlled mechanism. The equilibrium solubilization capacity(ESC) was measured by a turbidimeter and the result showed that EAC decreased with an increase in ACN but increased with both increases in surfactant concentration and solubilization rate. Dynamic interfacial tension measurements showed that interfacial tension and equilibrium time increased with an increase in ACN of hydrocarbon oil but decreased with an increase in surfactant concentration.

• Journal of the Korean Chemical Society
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• v.24 no.3
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• pp.245-249
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• 1980

Uranium (Ⅵ) was extracted from dilute aqueous solutions of uranyl nitrate with acetylacetone and tri-n-butyl phosphate in n-dodecane. Synergistic effect was observed with the mixed reagents above pH 1. The species extracted are the 1:2:1 and the 1:2:2 uranyl-AA-TBP complexes. The extraction constants for these reactions have been determined.

• Proceedings of the KAIS Fall Conference
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• 2002.05a
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• pp.260-263
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• 2002

이 연구는 과량의 유분(dodecane)으로 오염된 토양을 효율적으로 정화시키기 위한 화학적 토양세정(soil flushing)에서 알코올 성분에 의한 유동성을 고찰한 것이다. 탄소수가 다른 알코올 (methanol, ethanol, butanol)과 Tween-80 계면활성제를 세정용액으로 사용하여 혼합비, 조용매 종류 및 체류시간에 따른 세정결과를 도시하였다. 조용매 사용시 세척효율은 최대 94%(Butanol/Tween-80(w/w)=0.1) 이었다. 체류시간의 연장은 재흡착되는 admicelle의 증가로 말미암아 세정효율을 감소시키는 것으로 나타났다.