• Title/Summary/Keyword: n-Paraffin

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Vibrational Spectroscopic Studies of Crystallization in Mixed n-Paraffins (진동분광실험을 이용한 n-Paraffin혼합물의 결정화에 관한 연구)

  • 김도균;임현주;최선남;김성수;송기국
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.752-758
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    • 2002
  • FTIR, FT-Raman, and X-ray diffraction techniques were used to determine chain segregations and lamellar structures of the mixed binary n-paraffins with different chain lengths. The results of three different techniques, infrared spectroscopic studies of crystal field splitting, the Raman longitudinal acoustic mode, and the SAXS long period measurements were compared one another to understand the crystallization mechanism of separated or mixed n- paraffin lamellae.

Shape-Stabilized Phase Change Materials : Frozen Gels From Polypropylene and n-Paraffin for Latent Heat Storage

  • Ko, Jae-Wang;Son, Tae-Won
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2010.03a
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    • pp.80-81
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    • 2010
  • We prepared polymer-PCM gels such as prepared frozen gel from polypropylene and n-Paraffin for thermal storage and release materials, their basic properties and possible applications especially in latent heat storage. The preparation methods are used to melting method and absorption method respectively. The composition and properties of prepared frozen gels from polypropylene and n-Paraffin were observed by DSC, FT-IR spectra, ARES and Elemental analysis. We can prepare frozen gels in different temperature for latent heat storage materials as controlling composition of phase change material as well as using different incorporating phase change materials. These frozen gels can be used to latent heat storage materials for several applications.

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Production of Single-Cell Protein on Petroleum Hydrocarbon Part 6. Selection of the Strains for Mixed Cultivation and Evaluation of the Medium Composition (석유탄화수소를 이용한 단세포단백질의 생산에 관한 연구 제 6 보 혼합배양균주의 선정 및 배지조성의 검토)

  • Mheen, Tae-Ick;Pyun, Yoo-Ryang;Kwon, Tai-Wan
    • Korean Journal of Food Science and Technology
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    • v.6 no.4
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    • pp.219-230
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    • 1974
  • For the production of single cell protein from n-paraffin, yeasts utilizing n-paraffin and ethanol were isolated from oil deposit and oil field soils. The mixed cultivation between yeasts assimilating n-paraffin and ethanol was carried out to increase cell yield. Finally, selected strains were identified and suitable medium composition for mixed culture was compared with that of single cultures using flask and 5 l-jar fermentor. Yeasts grow on n-paraffin and ethanol were identified as Candida tropicalis var. KIST 76 and Trichosporon cutaneum KIST 76H respectively. By mixed cultivation under the suitable medium composition using 5 l-jar fermentor, maximum dry cell weight reached 20 g/l after 12 hrs. cultivation and it's protein content was 58%. Yield has been increased about 25% and protein content has been increased 6.7% compared to that of single culture, Candida tropicalis var. KIST 76, after 16 hrs. cultivation.

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Recovery of Paraffin Components from Pyrolysis Oil Fraction of Waste Plastic by Batch Cocurrent 4 Stages Equilibrium Extraction (회분 병류 4단 평형추출에 의한 폐플라스틱 열분해유 유분 중의 파라핀 성분의 회수)

  • Kang, Ho-Cheol;Shin, Sung Soon;Kim, Doo Han;Kim, Su Jin
    • Applied Chemistry for Engineering
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    • v.29 no.5
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    • pp.630-634
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    • 2018
  • The recovery of paraffin components contained in the fraction as a part of improving the quality for the fraction of waste plastics pyrolysis oil (WPPO) was investigated by batch cocurrent 4 stages equilibrium extraction. The fraction at a distilling temperature of $120-350^{\circ}C$ recovered from WPPO by the simple distillation and a little water-added dimethylformamide (DMF) solution were used as a raw material and solvent, respectively. As the number of equilibrium extraction (n) and the carbon number of paraffin component increased, the concentration of paraffin component contained in the raffinate increased. The concentrations of $C_{12}$, $C_{14}$, $C16$ and $C_{18}$ paraffin components present in the raffinate recovered at n = 4 were about 1.2, 1.5, 1.6 and 1.8 times higher than those of using the raw materials, respectively. Recovery rates (residue rates present in raffinate) of paraffin components rapidly decreased with increasing n, and increased sharply with increasing the carbon number. Furthermore, it was possible to predict the recovery rates at n = 1 - 4 for all paraffin components ($C_7-C_{24}$) contained in the raw material. The raffinate recovered through this study is expected to be used as a renewable energy.

The Functions of Polyoxyethylene Tocopherylethers in the Formulations of Cosmetics (화장품 제형에서 폴리옥시에틸렌 토코페릴에테르의 기능)

  • 김영대;김창규
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.19 no.1
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    • pp.108-126
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    • 1993
  • The functions of polyoxyethylene tocopheryl ethers [POE(n)TEs] in emulsion, solubilization and gel were studied. For emulsification of liquid paraffin, POE(10)TE showed better emulsifying effect in O/W emulsions than others tested. The effects of oil and polyol content on the formulation of W/O and O/W emulsions were also studied. In O/W emulsion, the viscosity was increased by increasing the liquid paraffin content, at about 70%, and slightly increased by increasing the propylene glycol content, However, in W/O emulsion, the viscosity was decreased by increasing the oil content, and also decreased by increasing the propylene glycol content, For solubilization of perfume oil, POE(18)TE showed better solubilizing effect than the others tested. The gelling effect of POE(n)TEs increased with ethylene oxide chain length up to 50 moles. The gelling property was evaluated for hardness and viscosity.

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Establishment of diagnositc method for bovine neosporosis by PCR using paraffin block (파라핀 블록 PCR을 이용한 소 네오스포라 감염증의 진단법 확립)

  • Lee, Jung-keun;Kim, Jae-Hoon;Kim, Jin-Hyun;Lee, Byung-chun;Hwang, Woo-suk;Youn, Hee-jeong;Nam, Hoo-woo;Jean, Young-wha;Kim, Dae-Yong
    • Korean Journal of Veterinary Research
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    • v.41 no.3
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    • pp.381-385
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    • 2001
  • Neospora caninum infections have been associated with neonatal paresis as well as abortion around the world. Bovine abortion induced by N caninum was first reported in 1997 in Korea. Diagnosis of N caninum infection is usually based on histopathology and immunohistochemical detection of organism. However, often the tissues having lesion suggestive of N caninum infection were negative on immunohistochemistry. Here, we describe establishment of PCR-based diagnostic strategy for N caninum infection using DNA extracted from paraffin blocks containing the lesion. PCR was able to amplify N caninum-specific bands from the paraffin blocks containing at least moderate degree of inflammation. Compared to paraffin-blocks, DNA extracted from fresh tissues were less sensitive than that of paraffin blocks. This PCR-based method can be practically applicable for rapid diagnosis of bovine N caninum infection with high specificity and sensitivity. Based on this method, 17% of bovine abortion surveyed during a designated period was associated with N caninum infection.

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Studies on a Mixed Yeast Culture -Part 1. Interactions in a Mixed Yeast Culture- (효모의 혼합 배양에 관한 연구 -제1보 혼합배양의 상호작용-)

  • Pyun, Yu-Ryang;Kwon, Tai-Wan;Yu, Ju-Hyun
    • Korean Journal of Food Science and Technology
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    • v.9 no.4
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    • pp.306-312
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    • 1977
  • A mixed culture of Candida tropicalis and Trichosporon cutaneum was carried out using a n-paraffin medium. The growth of C. tropicalis was markedly enhanced by the mixed culture with T. cutaneum which did not grow on n-paraffin. C. tropicalis extracellularly excreted free fatty acids as metabolic products of n-paraffin in the culture medium. T. cutaneum appeared to assimilate these free fatty acids which were growth inhibitors for C. tropicalis, threreby enhancing the growth of C. tropicalis.

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Development of Reduced Normal Dodecane Chemical Kinetics (축소 노멀 도데케인 화학반응 메커니즘 개발)

  • Lee, Sangyul;Kim, Gyujin;Min, Kyoungdoug
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.2
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    • pp.37-44
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    • 2013
  • Generally, a reduced chemical mechanism of n-heptane is used as chemical fuel of a 3-D diesel engine simulation because diesel fuel consists of hundreds of chemical components and various chemical classes so that it is very complex and large to use for the calculation. However, the importance of fuel in a 3-D simulation increases because detailed fuel characteristics are the key factor in the recent engine research such as homogeneous charged compression ignition engine. In this study, normal paraffin, iso paraffin and aromatics were selected to represent diesel characteristics and n-dodecane was used as a representative normal paraffin to describe the heavy molecular weight of diesel oil (C10~C20). Reduced kinetics of iso-octane and toluene which are representative species of iso paraffin and aromatics respectively were developed in the previous study. Some species were selected based on the sensitivity analysis and a mechanism was developed based on the general oxidation scheme. The ignition delay times, maximum pressure and temperature of the new reduced n-dodecane chemical mechanisms were well matched to the detailed mechanism data.

The Expression of nNOS in Hirschsprung's Disease (히르쉬스프룽병의 병변부위에서 nNOS 발현)

  • Kim, Ki-Hong;Kim, Han-Seung;Lee, Seong-Cheol
    • Advances in pediatric surgery
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    • v.11 no.1
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    • pp.9-18
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    • 2005
  • Abnormal distribution of enteric nerves such as adrenergic, cholinergic and non-adrenergic non-cholinergic nerves (NANC) may cause the failure of relaxation at the involved bowel segment in Hirschsprung's disease (HD). Nitric oxide (NO) is a major inhibitory NANC neurotransmitter in the gastrointestinal tract. NO is synthesized by activation of nNOS (neuronal nitric oxide synthase) in the intramural ganglion cells and regulates bowel movement. To assess the distribution of nNOS in HD, immunohistochemical staining to nNOS was utilized on paraffin embedded specimens. Ten control colon specimens were tested for feasibility of staining. Immunohistochemisrty was done on ganglionic colon as well as aganglionic segment of 15 patients with HD. nNOS immunoreactivity was observed in the neuronal cells, small cells and nerve fibers in the muscle layer and submucosal neuronal cells of control specimens. This finding was also observed in the ganglionic segments of HD. But, there was no nNOS immunoreactivity in aganglionic segments of HD. In conclusion nNOS immunohistochemical staining of paraffin embedded specimen is feasible and reliable. And the results suggest that the relaxation failure of the aganglionic bowel in HD is related to the absence of nNOS containing cells and nerve fibers.

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Shape-Stabilized Phase Change Materials : Frozen Gels From Polypropylene and n-Paraffin for Latent Heat Storage

  • Kim, Jong-Hwan;Ko, Jae-Wang;Son, Tae-Won
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2009.03a
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    • pp.120-121
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    • 2009
  • We prepared polymer-PCM gels such as prepared frozen gel from polypropylene and n-Paraffin for thermal storage and release materials, their basic properties and possible applications especially in latent heat storage. The preparation methods are used to melting method and absorption method respectively. The composition and properties of prepared frozen gels from polypropylene and n-Paraffin were observed by DSC, FT-IR spectra, ARES and Elemental analysis. We can prepare frozen gels in different temperature for latent heat storage materials as controlling composition of phase change material as well as using different incorporating phase change materials. These frozen gels can be used to latent heat storage materials for several applications.

  • PDF