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UV Enhanced NO2 Sensing Properties of Pt Functionalized Ga2O3 Nanorods

  • An, Soyeon;Park, Sunghoon;Mun, Youngho;Lee, Chongmu
    • Bulletin of the Korean Chemical Society
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    • v.34 no.6
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    • pp.1632-1636
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    • 2013
  • $Ga_2O_3$ one-dimensional (1D) nanostructures were synthesized by using a thermal evaporation technique. The morphology, crystal structure, and sensing properties of the $Ga_2O_3$ nanostructures functionalized with Pt to $NO_2$ gas at room temperature under UV irradiation were examined. The diameters of the 1D nanostructures ranged from a few tens to a few hundreds of nanometers and the lengths ranged up to a few hundreds of micrometers. Pt nanoparticles with diameters of a few tens of nanometers were distributed around a $Ga_2O_3$ nanorod. The responses of the nanorods gas sensors fabricated from multiple networked $Ga_2O_3$ nanorods were improved 3-4 fold at $NO_2$ concentrations ranging from 1 to 5 ppm by Pt functionalization. The Pt-functionalized $Ga_2O_3$ nanorod gas sensors showed a remarkably enhanced response at room temperature under ultraviolet (UV) light illumination. In addition, the mechanisms via which the gas sensing properties of $Ga_2O_3$ nanorods are enhanced by Pt functionalization and UV irradiation are discussed.

Enhanced Internal Quantum Efficiency and Light Extraction Efficiency of Light-emitting Diodes with Air-gap Photonic Crystal Structure Formed by Tungsten Nano-mask

  • Cho, Chu-Young;Hong, Sang-Hyun;Kim, Ki Seok;Jung, Gun-Young;Park, Seong-Ju
    • Bulletin of the Korean Chemical Society
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    • v.35 no.3
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    • pp.705-708
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    • 2014
  • We demonstrate the blue InGaN/GaN multiple quantum wells light-emitting diodes (LEDs) with an embedded air-gap photonic crystal (PC) which was fabricated by the lateral epitaxial overgrowth of GaN layer on the tungsten (W) nano-masks. The periodic air-gap PC was formed by the chemical reaction of hydrogen with GaN on the W nano-mask. The optical output power of LEDs with an air-gap PC was increased by 26% compared to LEDs without an air-gap PC. The enhanced optical output power was attributed to the improvement in internal quantum efficiency and light extraction efficiency by the air-gap PC embedded in GaN layer.

Basic Study on the Assembly Process Design of Curtain-wall System for Minimization of Carbon Emission

  • Yi, June-Seong
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.6
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    • pp.648-663
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    • 2012
  • With recent attempts to improve quality and productivity, the prefabrication manufacturing system has been occupying an increasing share of the construction area. To minimize site work, material is more frequently being produced and partially assembled at a plant, and then installed at a site. For this reason, the production process is being divided and the materials are being delivered to the site after passing through multiple plants. With these changes in the production process, the materials delivery plan is becoming an important management point. In particular, as road transportation using trucks has a 71 percent share of the domestic transportation market, selecting the proper transportation path is important when delivering materials and equipment to a site. But the management system at the project design phase to calculate the delivery cost by considering the production process of the pre-fab material and the $CO_2$ emission at the material delivery phase is currently lacking. This study suggests a process design model for assembly production of the pre-fab material and transportation logistics based on carbon emission. The suggested model can be helpful to optimize the location of the intermediate plant. It is expected to be utilized as a basic model at the project plan and design phase when subcontractors make decisions on items such as materials procurement, selecting the production method, and choosing the location of the assembly plant.

Classification of Parents' Materialism Inclination Recognized by the Adolescents and Analysis of Their Financial Characteristics (청소년이 지각한 부모의 물질주의 성향과 그에 따른 유형 분류 및 재정적 특성 분석)

  • Hong, Eun-Sil
    • Journal of Families and Better Life
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    • v.26 no.5
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    • pp.377-390
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    • 2008
  • This paper investigated materialism inclination of the parents recognized by the adolescents and analysed the relationships between 5 categorized types about parents' materialism inclination and financial characteristics of the adolescents. Statistical analysis was achieved by using Cronbach'$\alpha$, paired t-test, one-way ANOVA, two-way ANOVA, Duncan's multiple range test, chi-square analysis, and Ward' hierarchical cluster analysis with a total of 801 questionnaires. The results are summarized as follows: First, the adolescents felt that calculated points of father and mother's materialism inclination were lower than median points and mother's inclination for materialism was higher than that of father. Second, five categories were classified according to materialism inclination of parents. First classified category was the type which showed both parents had little interest in materials and the second category was the type which father had strong interest in materials. The third one was the type which mother had strong interest in materials. The last two categories were the ones which both parents had much interest in materials. Final result of this study revealed that attitudes of the adolescents for materialism and money were higher for those whose parents had strong interest in materialism than those whose parents had little materialism interest. They showed not only the behaviors of impulsive and overspending consumption but also low financial satisfaction and high financial stress.

Study of Turbine Module Design for Die Casting Mold Release Injection Robot System (다이케스팅 이형재 분사 로봇시스템의 터빈 모듈 설계에 관한 연구)

  • Choi, Hyun-Jin;Son, Young-Bum;Park, Chul-Woo;Lee, Seung-Yong;Choi, Seong-Dae
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.14 no.5
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    • pp.1-7
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    • 2015
  • Cleaning by injecting dry ice and water is a generally adopted trend these days to clean molds (injection, diecasting foundry, press, rubber mold, etc). This cleaning method is performed manually, or by installing multiple high pressure spray nozzles. We have manufactured a turbine cleaning module device that is able to clean diecasting modules at any position and angle in the space by mounting an articulated robot instead of the existing pipe type injection nozzle, to minimize lead time and enhance working yield of the cleaning process. In this paper, we analyzed process factors that are required to design the turbine module by reviewing number of revolution, and results according to different blade angles and thicknesses of the mold release injection turbine module, using computational fiuid dynamics (CFD).

The Color Painting on Yellow Poplar (Liriodendron tulipifera L.) Board for Using Furniture Materials (가구재 이용을 위한 백합나무 판재의 도장방법)

  • Park, Sang Bum;Lee, Min
    • Journal of the Korea Furniture Society
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    • v.24 no.4
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    • pp.345-349
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    • 2013
  • Yellow poplar is well known commercial hardwood species in the world because of its availability, rapid growth, large size, excellent form, early natural pruning, and the good working quality of the wood. Therefore, yellow poplar (Liriodendron tulipifera L.) has been adopted in South Korea for decades ago, and its cultivating the saplings and silvicultural system have been studied. However, yellow poplar is still embroiled in controversy for utilization of use and worth. This species has not only advantages such as lower weight, light color, and higher machinability and bending processing, but also has disadvantages which are bad smell and different colors on heartwood and sapwood. In this study, the objective was that use of yellow poplar board as furniture materials by drying and painting process. Thirty years old yellow poplar was cut and dried for 7 days by high-frequency dryness. Adjustment of color tone to walnut color was conducted with multiple colorants and various number of spread times. Uniform color of yellow poplar on heartwood and sapwood was accomplished by applying 1 time stain (green), 2 times transparent primer, 1 time middle-painting (walnut), and 2 times top-painting (walnut) in sequentially. The painted yellow poplar board was used to manufacture table and dressing table. During the furniture manufacture process, no critical issues were occurred on part of jointing and painting. This painting method may be useful data for future use of yellow poplar as furniture materials.

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Fabrication, Structure and Gas Sensing Properties of Pt-functionalized ZnS Nanowires

  • Kim, Soohyun;Park, Sunghoon;Jung, Jihwan;Lee, Chongmu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.315.2-315.2
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    • 2014
  • Pt-functionalized ZnS nanowires were synthesized on Au-deposited c-plane sapphire substrates by thermal evaporation of ZnS powders followed by wet Pt coating and annealing. The $NO_2$ gas sensing properties of multiple-networked Pt-functionalized ZnS nanowire sensors were examined. Scanning electron microscopy showed the nanowires with diameters of 20-80 nm. Transmission electron microscopy and X-ray diffraction showed that the nanowires were wurtzite-structured ZnS single crystals. The Pt-functionalized ZnS nanowire sensors showed enhanced sensing performance to $NO_2$ gas at $150^{\circ}C$ compared to pristine ZnS nanowire sensors. Pristine and Pt-functionalized ZnS nanowire sensors showed responses of 140-211% and 207-488%, respectively, to 1-5 ppm $NO_2$, which are better than or comparable to those of many oxide semiconductor sensors. In addition, the underlying mechanism of the enhancement of the sensing properties of ZnS nanowires by Pt functionalization is discussed.

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Synchronization Error-based Control Approach for an Industrial High-speed Parallel Robot (다축 동기 제어 방법 기반의 산업용 고속 병렬로봇 제어)

  • Do, Hyun Min;Kim, Byung In;Park, Chanhun;Kyung, Jin Ho
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.25 no.5
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    • pp.354-361
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    • 2016
  • Parallel robots are usually used for performing pick-and-place motion to increase productivity in high-speed environments. The present study proposes a high-speed parallel robot and a control approach to improve the tracking performance for the purpose of handling a solar cell. However, the target processes are not limited to the solar cell-handling field. Therefore, a delta-type parallel manipulator is designed, and a ball joint structure is specifically proposed to increase the allowed angle that would meet the required workspace. A control algorithm considering the synchronization between multiple joints in a closed-chain mechanism is also suggested to improve the tracking performance, where the tracking and synchronization errors are simultaneously considered. In addition, a prototype machine with the proposed ball joint is implemented. A satisfactory tracking performance is achieved by applying the proposed control algorithm, with a cycle time of 0.3 s for a 0.1 kg payload.

Failure Mechanism of Cu/PET Flexible Composite Film with Anisotropic Interface Nanostructure

  • Park, Sang Jin;Han, Jun Hyun
    • Korean Journal of Materials Research
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    • v.30 no.3
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    • pp.105-110
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    • 2020
  • Cu/PET composite films are widely used in a variety of wearable electronics. Lifetime of the electronics is determined by adhesion between the Cu film and the PET substrate. The formation of an anisotropic nanostructure on the PET surface by surface modification can enhance Cu/PET interfacial adhesion. The shape and size of the anisotropic nanostructures of the PET surface can be controlled by varying the surface modification conditions. In this work, the effect of Cu/PET interface nanostructures on the failure mechanism of a Cu/PET flexible composite film is studied. From observation of the morphologies of the anisotropic nanostructures on plasma-treated PET surfaces, and cross-sections and surfaces of the fractured specimens, the Cu/PET interface area and nanostructure width are analyzed and the failure mechanism of the Cu/PET film is investigated. It is found that the failure mechanism of the Cu/PET flexible composite film depends on the shape and size of the plasmatreated PET surface nanostructures. Cu/PET interface nanostructures with maximal peel strength exhibit multiple craze-crack propagation behavior, while smaller or larger interface nanostructures exhibit single-path craze-crack propagation behavior.

Cohesive Interface Model on Concrete Materials

  • Rhee In-Kyu;Roh Young-Sook
    • Journal of the Korea Concrete Institute
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    • v.17 no.6 s.90
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    • pp.1053-1064
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    • 2005
  • The mechanical damage of concrete is normally attributed to the formation of microcracks and their propagation and coalescence into macroscopic cracks. This physical degradation is caused from progressive and hierarchical damage of the microstructure due to debonding and slip along bimaterial interfaces at the mesoscale. Their growth and coalescence leads to initiation of hairline discrete cracks at the mesoscale. Eventually, single or multiple major discrete cracks develop at the macroscale. In this paper, from this conceptual model of mechanical damage in concrete, the computational efforts were made in order to characterize physical cracks and how to quantify the damage of concrete materials within the laws of thermodynamics with the aid of interface element in traditional finite element methodology. One dimensional effective traction/jump constitutive interface law is introduced in order to accommodate the normal opening and tangential slips on the interfaces between different materials(adhesion) or similar materials(cohesion) in two and three dimensional problems. Mode I failure and mixed mode failure of various geometries and boundary conditions are discussed in the sense of crack propagation and their spent of fracture energy under monotonic displacement control.