• Fibers and Polymers
• /
• v.7 no.4
• /
• pp.333-338
• /
• 2006

Silk fibroin (SF) fiber from the Antheraea pernyi silkworm was treated with a 1.23 N iodine-potassium iodide ($I_2-KI$) aqueous solution, and the structure and physical properties were investigated to clarify the effects of the iodine treatment. The noticeably high weight gain value of SF fiber, about 25 wt% was attributed to the absorption of polyiodide ions in the form of $I_3{^-}\;and\;I_5{^-}$. Fourier transform infrared spectroscopy and X-ray diffraction measurements suggested that polyiodide ions mainly entered the amorphous region. In addition, a new sharp reflection on the meridional direction, corresponding to a period of $7.0{\AA}$, was observed and indicated the possibility of the formation of mesophase structure of ${\beta}$-conformation chains. Dynamic viscoelastic measurements showed that the damping tan ${\delta}$ peak at $270^{\circ}C$ gradually shifted to lower temperature in the iodinated SF fibers, suggesting an enhancement of the molecular motion of the fibroin chains induced by the presence of polyiodide ions. With heating above $254^{\circ}C$, the iodine component introduced intermolecular cross-linking of SF, and the melt flow of the sample was inhibited. The thermal decomposition stability of fibroin molecules was greatly enhanced by iodine treatment.

• The Bulletin of The Korean Astronomical Society
• /
• v.46 no.2
• /
• pp.36.1-37
• /
• 2021

Six images of IRC+10216 taken by the Hubble Space Telescope at three epochs in 2001, 2011, and 2016 are compared in the rest frame of the central carbon star. An accurate astrometry has been achieved with the help of Gaia Data Release 2. The positions of the carbon star in the individual epochs are determined using its known proper motion, defining the rest frame of the star. In 2016, a local brightness peak with compact and red nature is detected at the stellar position. A comparison of the color maps between 2016 and 2011 epochs reveals that the reddest spot moved along with the star, suggesting a possibility of its being the dusty material surrounding the carbon star. Relatively red, ambient region is distributed in an Ω shape and well corresponds to the dusty disk previously suggested based on near-infrared polarization observations. In a larger scale, differential proper motion of multiple ring-like pattern in the rest frame of the star is used to derive the average expansion velocity of transverse wind components, resulting in ~12.5 km s-1 (d/123 pc), where d is the distance to IRC+10216. Three dimensional geometry is implied from its comparison with the line-of-sight wind velocity determined from half-widths of submillimeter emission line profiles of abundant molecules. Uneven temporal variations in brightness for different searchlight beams and anisotropic distribution of extended halo are revisited in the context of the stellar light illumination through a porous envelope with postulated longer-term variations for a period of 10 years.

• Journal of The Korean Association For Science Education
• /
• v.23 no.6
• /
• pp.609-616
• /
• 2003

This study investigated the effects of 3-level systematic drawing upon students' achievement, conceptions, learning motivation, perceptions of involvement and attitudes toward science instruction. Two classes of 7th grade at a coed middle school were assigned to the control and the treatment groups. They were taught about change of states and motion of molecules for 8 class periods. Two-way ANCOVA results revealed that the scores of achievement test, a conceptions test, motivation and attitudes toward science instruction tests for the treatment group were significantly higher than those for the control group. But there was no difference in the scores of the perceptions of involvement test.

• Journal of The Korean Astronomical Society
• /
• v.27 no.1
• /
• pp.31-44
• /
• 1994

The 4.8GHz formaldehyde absorption line in the dark clouds in M17 and NGC 2024 regions has been mapped. In both nebulae, we detected two $H_2CO$ line components. In M17, the 24km $S^{-1}$ cloud is closely associated with the HII region located in front of the radio continuum source, and the 19km $S^{-1}$ cloud is associated with the visual dark clouds with a larger extent which are closer to us. The 19km $S^{-1}$ cloud has a mass motion approaching to the HII region. In both clouds, a velocity gradient from the north-east to the south-west directions is observed. The linewidth has no variation indicating no collapsing motion. In NGC 2024, the 9km $S^{-1}$ feature is extended along the dark bar in front of the bright nebula and a weak second component at 13km $S^{-1}$ is confined to the immediate vicinity of the radio source. Indications are that the 9km $S^{-1}$ cloud is physically associated with the dark bar and the 13km $S^{-1}$ cloud is located behind the radio source. The angular extent, the column density, and the total mass of the clouds are derived. The radial velocities of other molecular lines observed in these clouds are compared.

• Elastomers and Composites
• /
• v.52 no.1
• /
• pp.17-21
• /
• 2017

The optimum mixing conditions of silica and silane containing rubber composites were evaluated by investigating the properties of rubber composites prepared with a silica composition of 10, 20, 40, 60, and 80 g, respectively. The crosslinking rate decreased with increasing silica content, with he promoters being adsorbed on the silica surface with in the rubber composite. As a result, the increase in crosslinking time resulted in the destruction of the silica structure. The increase of the bound rubber content due to the destruction of the silica structure inhibited the chain motion of the polymer molecules and reduced the cohesion of the silica itself. Finally, the increase of silica content showed the increase of hardness, tensile strength, and storage modulus of rubber composites.

• Korean Journal of Radiology
• /
• v.22 no.1
• /
• pp.9-22
• /
• 2021

Diffusion-weighted (DW) magnetic resonance imaging (MRI) is a rapid, unenhanced imaging technique that measures the motion of water molecules within tissues and provides information regarding the cell density and tissue microstructure. DW MRI has demonstrated the potential to improve the specificity of breast MRI, facilitate the evaluation of tumor response to neoadjuvant chemotherapy and can be employed in unenhanced MRI screening. However, standardization of the acquisition and interpretation of DW MRI is challenging. Recently, the European Society of Breast Radiology issued a consensus statement, which described the acquisition parameters and interpretation of DW MRI. The current article describes the basic principles, standardized acquisition protocols and interpretation guidelines, and the clinical applications of DW MRI in breast imaging.

• Macromolecular Research
• /
• v.8 no.6
• /
• pp.292-297
• /
• 2000

The theoretical synthesis of the isotactic and syndiotactic poly(methyl methacrylate) were carried out as a model for real polymerization reactions following the normal chain reaction processes by repeating the uniform localization of wave functions with inclusion of the interaction between the end group of the cluster and an attaching molecule by the elongation method, and then, the calculated value was compared with the usual PM$_3$ calculation. The results revealed that a reaction of cluster with monomer molecules has made it possible to calculate the electronic structure and total energy of polymer with nearly infinite length and a matrix of constant dimension. The isotactic poly(methyl methacrylate) is more stable than syndiotactic one. The same tendency have been found between the experimentally measured properties and a calculated total energy to explain the chain motion in isotatic and syndiotactic poly(methyl methacrylate).

• Journal of the Korean Chemical Society
• /
• v.64 no.3
• /
• pp.145-152
• /
• 2020

Flip-flop rate constants were measured by dithionite assay of NBD-PE fluorescence in DMPC/POPC vesicles made of various DMPC/POPC ratios. The activation energy, enthalpy, entropy, and free energy were determined based on the transition state theory. We found that the activation energy, enthalpy, and entropy increased as the amount of POPC increased, but the activation free energy was almost constant. These experimental results and other similar studies allow us to propose that the POPC molecules included in DMPC vesicles affect the flip-flop motion of NBD-PE in DMPC/POPC vesicles via increasing the packing order of the ground state of the bilayer of the vesicles. The increase in the packing order in the ground state seems to be a result of the effect of the overall molecular shape of POPC with a monounsaturated tail group, rather than the effect of the longer tail group.

• Rapid Communication in Photoscience
• /
• v.3 no.4
• /
• pp.64-66
• /
• 2014

Synthesis of a deuterium-labeled derivative of nitrospirobenzopyran (NSP), one of representative photochromic compounds, has been described. Four deuteriums were successfully introduced on 1-methyl and ${\alpha}$-methyne relative to spiro-carbon in the title compound with more than 95atom%D purity. Main photodegraded products of NSP were two oxindoles in acetonitrile, and additional products were formed in poly(isobutyl-methacrylate) films possibly due to restricted molecular motion in polymer matrix. Quantitative HPLC analysis revealed that partial introduction of deuterium to NSP brought a noticeable isotope effect, recognizable enhancement in photo-resistivity of NSP, i.e.,8.3% in solutions and 29% in polymeric films.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.2
• /
• pp.574-578
• /
• 2013

In this work, the friction and diffusion coefficients of a tracer in a mesoscopic solvent are evaluated as a function of the tracer size by a hybrid molecular dynamics simulation where solute molecules evolve by Newton's equations of motion but the solvent evolves through the multi-particle collision dynamics. The friction coefficient is shown to scale linearly with the tracer size for larger tracers in accord with predictions of hydrodynamic theories. The diffusion coefficient of tracer is found to be inversely proportional to tracer size. The behavior of Stokes-Einstein formula is validated as a function of tracer size.