• Resources Recycling
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• v.21 no.4
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• pp.53-59
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• 2012

In this study, behaviors of removing Sb and Pb by oxidation of molten Bi-Pb-Sb alloy which is a by-product of non-ferrous smelting process was investigated. The molten alloy was oxidized at 1173 K by bubbling $N_2+O_2$ gas through a submerged nozzle. The Sb was removed and recovered as mixed phase of $Sb_2O_3$ and metal Sb. In the case of bubbling $N_2+O_2$ gas into molten Bi-Pb alloy at 923 K, Pb was oxidized and removed to slag. But Bi could not be refined due to simultaneous oxidization of Bi with Pb.

• Journal of the Korean Society of Industry Convergence
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• v.25 no.5
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• pp.889-898
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• 2022

In this study, sand casting process was applied to manufacture a large aluminum turbo-type fan used for tank powerpack. To apply the sand casting method, the turbo fan was reverse engineered, and after designing three gating systems, the optimal gating system design was selected by performing casting simulation. In the case of the bottom up-gating system, there is a significant temperature loss of the molten alloy during blade filling. When the molten alloy is completely filled into the sand mold, the blade upper tip and front shroud are below the liquidus temperature. In the case of the top down-gating system, molten alloy scattering occurs, but the temperature loss while the blade is filled is smaller than that of the bottom up type. And after the inflow of molten alloy into the mold is completed, the blade upper tip and front shroud are higher than the liquidus temperature. A sand mold was manufactured with the top down-gating system and the casting process was performed. The fan was made perfectly in appearance without any unfilled parts.

• Journal of Korea Foundry Society
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• v.10 no.1
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• pp.31-42
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• 1990

The full mould casting process in one of the newly developed techniques which has many advantages. Unbonded sand mould has been prepared for the major mould and $CO^2$ gas mould has been used occasionally for comparison. Patterns were built up with expanded polystyrene and coated with three different materials. Silica, graphite and zircon were used for the coating layer. The effects on fluidity and temperature loss of molten metals were investigated. The molten metals were Al-5% Si alloy, Cu-30% Zn alloy and gray iron of approximately 4.0% of carbon equivalent. Experimental variables were runner section area, superheat, sprue height, coating materials, coating thickness and apparent density of EPS pattern. The effects of coating materials on fluidity and temperature loss of the molten metals during transient pouring are summarized as follows : As runner section area, superheat and sprue height increased, fluidity increased. Temperature loss decreased as runner section area and sprue height increased. However, reversed effects were observed in the case of superheat increment. The coating materials decreased the fluidity of each alloy in the order of silica, graphite and zircon. Zircon brought to the highest temperature loss among the coating materials used. The fluidity increased in the order gray iron, Cu-30% Zn and Al-5% Si alloy while temperature loss in the reverse order. Especially in case of reduced pressure process, the fluidity was increased apparently. Al-5% Si alloy showed the lowest temperature loss among the alloys. The increment of the apparent density of EPS pattern resulted in the fluidity decrease and temperature loss increase. The relation between fluidity and temperature loss of each alloy can be expressed by the following equation within the coating thickness limit of 0.5-1.5㎜. F^*={\frac{a}{T^*-b}}-c$ where, $F^*$ : fluidity in the Full mould, $T^*$ : temperature loss in the mould. a : parameter for full mould. b, c : constants.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.6
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• pp.459-463
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• 2017

Hot dip galvanizing in the steel plant is one of the most widely used methods for preventing the corrosion of steel materials including structures, steel sheets, and materials for industrial facilities. While hot dip galvanizing has the advantage of stability and economic feasibility, it has difficulty in repairing equipment and maintaining the facilities due to high-temperature oxidation caused by Zn Fume where molten zinc used in the open spaces. Currently, SM45C (carbon steel plate for mechanical structure, KS standard) is used for the equipment. If a part of the equipment is resistant to high temperature and Zn fume, it is expected to improve equipment life and performance. In this study, the manufactured Ni alloy was tested for its corrosion resistance against Zn fume when it was used in the hot dip galvanizing equipment in the steel plant. Two kinds of materials currently used in the equipment, new Ni alloy and Inconel(typical corrosion-resistant Ni alloy), were selected as the reference groups. Two kinds of molten metal were used to confirm the corrosion of each alloy according to the molten metal. Zn fume was generated by bubbling Ar gas from molten Zn in a furnace($500{\sim}700^{\circ}C$) and the samples were analyzed after 30 days. After 30 days, the specimens were taken out, the oxide layer on the surface was confirmed with an optical microscope and SEM, and the corrosion was confirmed using a potentiodynamic polarization test. Corrosion depends on the type of molten metal.

• Korean Journal of Materials Research
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• v.8 no.8
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• pp.685-692
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• 1998

Since a wet-seal area of Molten Carbonate Fuel Cell (MCFC) operated at $650^{\circ}C$ is exposed to severe environment, a life-time of MCFC is influenced by the corrosion resistance of separator. In order to improve corrosion resistance of 316L stainless steel used as separator material, AI- base alloy such as NiAI has been widely used as coat¬ing material on the wet-seal area. The purpose of this work is to develope a more protective coating material by adding yttrium on NiAI alloy. An immersion test and a polarization test were performed in molten carbonate salt at $650^{\circ}C$ to estimate corrosion resistance of the NiAI alloy and the NiAl/Y alloys with up to L5at% yttrium. NiAl/Y alloys showed better corrosion resistance than NiAI alloy. We found that more than 0.7 at% yttrium was required to improve the corrosion resistance of NiAI alloy in molten carbonate salt at $650^{\circ}C$.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.20 no.1
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• pp.43-63
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• 2022

The aim of this review is to communicate some essential knowledge of the underlying mechanism of the corrosion of structural containment alloys during molten salt reactor operation in the context of prospective online monitoring in future MSR installations. The formation of metal halide species and the progression of their concentration in the molten salt do reflect containment corrosion, tracing the depletion of alloying metals at the alloy salt interface will assure safe conditions during reactor operation. Even though the progress of alloying metal halides concentrations in the molten salt do strongly understate actual corrosion rates, their prospective 1^st order kinetics followed by near-linearly increase is attributed to homogeneous matrix corrosion. The service life of the structural containment alloy is derived from homogeneous matrix corrosion and near-surface void formation but less so from intergranular cracking (IGC) and pitting corrosion. Online monitoring of corrosion species is of particular interest for molten chloride systems since besides the expected formation of chromium chloride species CrCl₂ and CrCl₃, other metal chloride species such as FeCl₂, FeCl₃, MoCl₂, MnCl₂ and NiCl₂ will form, depending on the selected structural alloy. The metal chloride concentrations should follow, after an incubation period of about 10,000 hours, a linear projection with a positive slope and a steady increase of < 1 ppm per day. During the incubation period, metal concentration show 1^st order kinetics and increasing linearly with time^1/2. Ideally, a linear increase reflects homogeneous matrix corrosion, while a sharp increase in the metal chloride concentration could set a warning flag for potential material failure within the projected service life, e.g. as result of intergranular cracking or pitting corrosion. Continuous monitoring of metal chloride concentrations can therefore provide direct information about the mechanism of the ongoing corrosion scenario and offer valuable information for a timely warning of prospective material failure.

• Korean Journal of Materials Research
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• v.22 no.6
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• pp.309-315
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• 2012

Metal foam has many excellent properties, such as light weight, incombustibility, good thermal insulation, sound absorption, energy absorption, and environmental friendliness. It has two types of macrostructure, a closed-cell foam with sealed pores and an open-cell foam with open pores. The open-cell foam has a complex macrostructure consisting of an interconnected network. It can be exploited as a degradable biomaterial and a heat exchanger material. In this paper, open cell Mg alloy foams have been produced by infiltrating molten Mg alloy into porous pre-forms, where granules facilitate porous material. The granules have suitable strength and excellent thermal stability. They are also inexpensive and easily move out from open-cell foamed Mg-Al alloy materials. When the melt casting process used an inert gas, the molten magnesium igniting is resolved easily. The effects of the preheating temperature of the filler particle mould, negative pressure, and granule size on the fluidity of the open cell Mg alloy foam were investigated. With the increased infiltration pressure, preheat temperature and granule sizes during casting process, the molten AZ31 alloy was high fluidity. The optimum casting temperature, preheating temperature of the filler particle mould, and negative pressure were $750^{\circ}C$, $400-500^{\circ}C$, and 5000-6000 Pa, respectively, At these conditions the AZ31 alloy had good fluidity and castability with the longest infiltration length, fewer defects, and a uniform pore structure.

• Journal of Korea Foundry Society
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• v.35 no.1
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• pp.8-14
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• 2015

Variations of nickel contents and microstructures in molten magnesium alloys on the addition of aluminum, zirconium, and manganese have been investigated. Specimens were prepared by melting under $SF_6$ and $CO_2$ atmosphere and casting into a disc of 29 mm diameter with 7~10 mm thickness from the melt acquired at the top of crucible. Before casting, the molten metal was stirred for 3 minutes after each addition of alloying elements and maintained for 30 minutes for settling down. Results showed that zirconium did not significantly affect the content of nickel while aluminum remarkably reduced it by forming $Al_3Ni_2$ phase. When manganese are added to Mg-1wt%Ni alloy along with aluminum, both elements remarkably reduced the content of nickel. The addition of 1.5 wt% manganese to Mg-1wt%Ni alloy containing aluminum further reduced the content of nickel by more than 30%, during which an additional intermetallic phase $Al_{10}Mn_3Ni$ was precipitated in the molten magnesium.

• Journal of the Korean Electrochemical Society
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• v.18 no.3
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• pp.102-106
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• 2015

The performance of Li-B alloy as anode for molten salt electrolysis was firstly investigated. The crystalline phase of the prepared Li-B alloy was identified as $Li_7B_6$. The potential profile of Li-B alloy anode was monitored during the electrodeposition of $Nd^{3+}$ onto an LCC (liquid cadmium cathode) in molten LiCl-KCl salt at $500^{\circ}C$. The potential of Li-B alloy was increased from -2.0 V to -1.4 V vs. Ag/AgCl by increasing the applied current from 10 to $50mA{\cdot}cm^{-2}$. It was found that not only the anodic dissolution of Li to $Li^+$ but also the dissolution of the atomic lithium ($Li^0$) into the LiCl-KCl eutectic salt was observed, following the concomitant reduction of $Nd^{3+}$ by the $Li^0$ in Li-B alloy. It was expected that the direct reduction could be restrained by maintaining the anode potential higher that the deposition potential of neodymium.

• Korean Journal of Materials Research
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• v.12 no.1
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• pp.68-74
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• 2002

The lead has to be removed for the recycling of copper alloy. The lead cannot be removed from the copper alloy by oxidation. It can be removed by the evaporation because of its high vapor pressure. However, rare information is found on removal of lead from copper alloy. The purpose of present work is to provide a fundamental knowledges on the removal of lead from the copper alloy by evaporation. Gas injection was made in molten copper alloy, and the evaporation rate of lead was measured. The influence of Ar gas flow rata(2~4 L/min), initial contents of lead(2~4wt%Pb), temperature(1200~140$0^{\circ}C$) was investigated based on the thermodynamic and the kinetics. The rate constant is increased with increasing flow rate of Ar and temperature. Though amount of lead removed is increased with higher initial lead concentration, the rate constant is not changed significantly. The activation energy is estimated from the temperature dependence of the rate constant. Also removal of lead from the copper by adding chloride was made for the comparison.