• Title/Summary/Keyword: molecular orientation

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Thermal behavior of the layered structure of decanesulfonate intercalated into the hydrated nickel compound (데칸술폰이 삽입된 니켈 화합물의 층상 구조의 열적 성질)

  • 허영덕;전태현;박용준
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.6
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    • pp.580-584
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    • 1999
  • The synthesis and characterization of intercalated compound of decansulfonate into hydrated nickel is presented. The compound shows a layered structure as determined by high temperature powder X-ray diffraction (HTXRD). The layer distance of the product is increased from 24.7 $\AA$ to 30.5 $\AA$ by increasing the temperature which is in turn accomplished by changing the structure of the intercalated nickel compound. From the X-ray diffraction data and the decanesulfonate size, the orientation of the decanesulfonate onto the nickel layer is determined. The molecular axis of the decanesulfonate with bilayer structure is tilted to the perpendicular of the nickel layer.

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IMPROVEMENT OF FLEXURAL STRENGTH OF BIODEGRADABLE POLYMERIC INTERNAL FIXATION DEVICE BY SOLID STATE EXTRUSION

  • Lim, Soo-Ho;Lim, Jung-Yul;Kim, Soo-Hyun
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.04a
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    • pp.23-26
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    • 2003
  • Solid-state extrusion technique was employed for the improvement of mechanical properties of polylactic acid (PLLA) widely used as biodegradable internal fixation devices currently. Cylindrical billets were machined out from the vacuum compression-molded PLLA to have various diameters, and solid-state extrusion of the billets was performed at various drawing rates and at the extrusion temperature of $130^{\circ}C$. Throughout the whole processes the decrease in molecular weight was significantly suppressed to be about $10\%$. Flexural modulus and strength of PLLA increased up to 8.3 GPa and 221 MPa, respectively. Studies on the orientation and crystallinity of extruded PLLA could reveal the effects of billet morphology, draw ratio, and drawing rate on the flexural strengths of PLLA.

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Synthesis and characterization of layered basic zine p-toluenesulfonates (층상구조의 염기성 zinc p-toluenesulfonate의 합성 및 성질에 관한 연구)

  • 김형동;조영식;허영덕
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.4
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    • pp.651-654
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    • 1998
  • The layered basic zinc p-toluenesulfonates has been directly synthesized by the surface modification. The chemical formula of layered basic zinc p-toluenesulfonate is determined by CHNS and TG-DTA. From the X-ray diffraction data and the guest size, the orientation of the p-toluenesulfonate onto the zinc hydroxide layer is determined. The molecular plane of the p-toluenesulfonate lies perpendicular to the zinc hydroxide layers.

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The structure and synthesis of intercalation compound between a layered double hydroxide and an organic compound (유기화합물이 삽입된 층상이중수산화물의 합성과 구조)

  • 우은경;허영덕
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.36-41
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    • 1998
  • Intercalation compounds of alkyl sulfonates into layered double hydroxides (LDH) have been directly synthesized. From the X-ray diffraction data and the alkyl sulfonates size, the orientation of the intercalated alkyl sulfonate into the layered double hydroxide was determined. The intercalated alkyl sulfonate is arranged with molecular chain perpendicular to the hydroxide layer with an antiparallel pattern.

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Thermotropic Liquid Crystal Polymer or Silica Nano-particle Filled Polyester Composite Fibers

  • Kim, Seong-Hun;Kim, Jun-Young;Ahn, Seon-Hoon
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.65-66
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    • 2003
  • Ternary blend fibers (TBFs) based on melt blends of PEN, PET, and TLCP were prepared by melt blending and spinning to achieve high performance fibers. The reinforcement effect and the TLCP fibrillar structure resulted in the improvement of mechanical properties for TBFs. Molecular orientation was an important factor in determining the tensile strength and modulus of TBFs. Another part of this research is silica nano-particle filled PEN composites were melt-blended to improve mechanical and physicalproperties, and processability. The tensile modulus and strength were improved adding silica nano-particles to the PEN. The decreased melt viscosity by the fumed silica resulted in the improvement of the processability. The fumed silica may act as a nucleating agent in the PEN matrix.

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The structure of intercalation compound between a layered double hydroxide and an ethyl orange (층상이중수산화물과 에틸오렌지의 삽입화합물의 구조)

  • Jung, Woo-Chan;Huh, Young-Duk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.1
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    • pp.137-142
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    • 1997
  • We synthesized the intercalation compound between a layered double hydroxide and an ethyl orange. The orientation of the intercalated ethyl orange into the layered double hydroxide was investigated. The molecular plane of the ethyl orange and its N=N axis lie nearly perpendicular to the hydroxide layers with an antiparallel pattern.

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Degeneration of Ocellar Photoreceptor System on Drosophila rdgC Mutant (초파리 rdgC 돌연변이체 단안 시각계의 퇴행현상)

  • Yoon, Chun-Sik
    • Applied Microscopy
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    • v.28 no.3
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    • pp.391-398
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    • 1998
  • The morphological phenotype on ocellus of Drosophila rdgC mutant was observed with electron microscope. The result showed the particular phenotype that was not found in other retinal degenarative mutants. The most distinct difference was the orientation of photoreceptor cells. The photoreceptor cells did not attached to corneagenous cells but dropped under corneagenous cells and assembled around newly formed space. Enormous multivesicle bodies caused by the degeneration of photoreceptor cells were frequently found. Rhabdomeres were also severely degenerated in consequence of the mutant. Another degeneration was found in a part of photoreceptor cell, but the degeneration of subrhabdomeric cisternae (SRC) was not found. It was a ovious difference of rdgC comparing with other two retinal degenerative mutants, rdgA and rdgB. As a result, rdgC mutant was affected on the attachment between photoreceptor cells and corneageneous cells, and it suggested the defect of cell-cell attachment. In addition, rdgC mutant was accompanied by the defect not only in retina but nerve system. The results were agreed to the reference discussion that the rdgC molecule is exist in the nerve.

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Shrinkage Behaviors of PA6 polymer according to Shape Ratio of Product in Injection Molding (PA6 사출성형품의 형상비에 따른 성형수축 거동)

  • 최윤식;한동엽;정영득
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.308-311
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    • 2004
  • Nowadays, plastic industry has needed to produce parts that require high precision and quality. To make a high precision and quality part, before injection molding, plastic material is investigated about their properties such as shrinkage, warpage, etc. In this study, experiments were conducted with PA6(polyamid) to figure out shrinkage behavior according to three type aspect ratio of samples. The injection speed that affects on shear rate, molecular orientation within plastic part was determined as main variable of experiment. As a result of experimental study, part shrinkage had a tendency to be decreased by increasing injection speed and aspect ratio of samples.

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The Dielectric Properties due to the Temperature and Applied Voltage of Oriented Polypropylene Film Irradiated by $^{60}/Co-${\gamma}$$ ($^{60}/Co-${\gamma}$$선으로 조사된 이축연신 폴리프로필렌 필림의 온도 및 전압에 따른 유전특성)

  • 홍진웅;이수원;김왕곤
    • Journal of the Korean Society of Safety
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    • v.9 no.1
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    • pp.48-55
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    • 1994
  • In this paper, It is studied that the variation of the dielectric absorption of the specimen according to the change with $^{60}$ Co-${\gamma}$ ray irradiation dose of the influence of temperature and applied voltage. In order to investigate the effect of irradiated oriented polypropylene film, we have observed dielectric properties within the temporature range of 30~130 ($^{\circ}C$) and voltage range of 100~250 (V). As for the dependency of temperature by tan $\delta$, the $\alpha$ peak which appears at high temperature increases accordingly to the increment of irradiation dose which is contributed by the crystal region and moves towards the high temperature. The $\beta$ peak which appears the orientation by dipoles and molecular motions in the amorphous region at low temperature. For the dependency of voltage by tan $\delta$ at low temperature, the peak of the tan $\delta$ shifts accordingly to the increment of irradiation dose towards the high temperature region.

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DNA Light-strand Preferential Recognition of Human Mitochondria Transcription Termination Factor mTERF

  • Nam, Sang-Chul;Kang, Chang-Won
    • BMB Reports
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    • v.38 no.6
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    • pp.690-694
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    • 2005
  • Transcription termination of the human mitochondrial genome requires specific binding to termination factor mTERF. In this study, mTERF was produced in E. coli and purified by two-step chromatography. mTERF-binding DNA sequences were isolated from a pool of randomized sequences by the repeated selection of bound sequences by gel-mobility shift assay and polymerase chain reaction. Sequencing and comparison of the 23 isolated clones revealed a 16-bp consensus sequence of 5'-GTG$\b{TGGC}$AGANCCNGG-3' in the light-strand (underlined residues were absolutely conserved), which nicely matched the genomic 13-bp terminator sequence 5'-$\b{TGGC}$AGAGCCCGG-3'. Moreover, mTERF binding assays of heteroduplex and single-stranded DNAs showed mTERF recognized the light strand in preference to the heavy strand. The preferential binding of mTERF with the light-strand may explain its distinct orientation-dependent termination activity.