• 제목/요약/키워드: molecular gas

검색결과 869건 처리시간 0.028초

The Affects of Molecular Properties of Motive Gas on Supersonic Ejection

  • Jin, Jung-Kun;Kwon, Se-Jin;Kim, Se-Hoon
    • International Journal of Aeronautical and Space Sciences
    • /
    • 제9권2호
    • /
    • pp.98-106
    • /
    • 2008
  • The motive gas of a supersonic ejector is supplied from different sources depending on the application. The performance of an ejector that is represented by the secondary flow pressure, starting and unstarting pressures heavily depends on the molecular properties of the motive gas. The effects of specific heat ratio of the motive gas were investigated experimentally for an axi-symmetric annular injection type supersonic ejector. Both the starting pressure and unstarting pressure, however, decreased with the increase of the specific heat ratio of the motive gas. It was discovered that the secondary flow pressure increased as the specific heat ratio of the motive gas decreased even if the stagnation pressure of the motive flow was invariant. However, when the motive gas flow nozzle area ratio is large enough for the motive gas to be condensed, different tendency was observed.

A Molecular Dynamics Study on the Gas Permeation of Glassy Polymer

  • Goo, Hyung Seo;Kim, In Ho;Ha, SeongYong;Cho, Dae Myeong;Rhim, Ji Won;Nam, SangYong
    • Korean Membrane Journal
    • /
    • 제6권1호
    • /
    • pp.30-36
    • /
    • 2004
  • The gas permeation performance of commercially available polyetherimide (Ultem$\^$/) is simulated by means of molecular dynamics methods. By the observation of trajectory, long distance hopping of gas molecules is needed to transverse from top to bottom of membrane. Two possibilities mechanism of diffusion phenomena through glassy polymers can be issued. Diffusion coefficients were calculated by Einstein relation equation. In solubility simulation, the value of the constants C'$\_$H/ and b for O$_2$ at 300 K were calculated. The diffusion and solubility coefficient of He for PEI were simulated in this simulation work. the permeability coefficient is 9.88 Barrer. This value is closed to experimental value of 9.4 Barrer.

Radiation-hydrodynamic simulations of ram pressure strippin on star-forming galaxies

  • Lee, Jaehyun;Kimm, Taysun;Katz, Haley
    • 천문학회보
    • /
    • 제43권2호
    • /
    • pp.54.1-54.1
    • /
    • 2018
  • Recent observational studies suggest that the environmental effects can shape the evolution of galaxies in clusters. In an attempt to better understand this process, we perform idealized radiation-hydrodynamic simulations of RAM pressure stripping on star-forming galaxies using RAMSES-RT. We find that extended HI disks are easily stripped by moderate ICM winds, while there is no significant decrease in the total mass of molecular gas. RAM pressure tends to compress the molecular gas, leading to enhanced star formation especially when the gaseous disk is hit by edge-on winds. On the other hand, strong ICM winds that are expected to operate at the centre of clusters strip both HI and molecular gas from the galaxy. Interestingly, we find that the strong ICM winds can induce the formation of relatively dense (~1H/cc) HI gas clouds at a distance from the disk.

  • PDF

Gas Separation of Pyrolyzed Polymeric Membranes: Effect of Polymer Precursor and Pyrolysis Conditions

  • Jung, Chul-Ho;Kim, Gun-Wook;Han, Sang-Hoon;Lee, Young-Moo
    • Macromolecular Research
    • /
    • 제15권6호
    • /
    • pp.565-574
    • /
    • 2007
  • In this study, five representative, commercially available polymers, Ultem 1000 polyetherimide, Kapton polyimide, phenolic resin, polyacrylonitrile and cellulose acetate, were used to prepare pyrolyzed polymer membranes coated on a porous {\alpha}-alumina$ tube via inert pyrolysis for gas separation. Pyrolysis conditions (i.e., final temperature and thermal dwell time) of each polymer were determined using a thermogravimetric method coupled with real-time mass spectroscopy. The surface area and pore size distribution of the pyrolyzed materials derived from the polymers were estimated from the nitrogen adsorption/desorption isotherms. Pyrolyzed membranes from polymer precursors exhibited type I sorption behavior except cellulose acetate (type IV). The gas permeation of the carbon/{\alpha}-alumina$ tubular membranes was characterized using four gases: helium, carbon dioxide, oxygen and nitrogen. The polyetherimide, polyimide, and phenolic resin pyrolyzed polymer membranes showed typical molecular sieving gas permeation behavior, while membranes from polyacrylonitrile and cellulose acetate exhibited intermediate behavior between Knudsen diffusion and molecular sieving. Pyrolyzed membranes with molecular sieving behavior (e.g., polyetherimide, polyimide, and phenolic resin) had a $CO_2/N_2$ selectivity of greater than 15; however, the membranes from polyacrylonitrile and cellulose acetate with intermediate gas transport behavior had a selectivity slightly greater than unity due to their large pore size.

CENSUS AND ANALYSIS OF GALACTIC MOLECULAR CLOUDS

  • HOJAEV, A.S.
    • 천문학논총
    • /
    • 제30권2호
    • /
    • pp.107-108
    • /
    • 2015
  • In this project, all available databases of molecular and gas-dust clouds in the Galaxy were cross-identified by taking into account available properties, including position, angular dimensions, velocity, density, temperature and mass. An initial list of about 7000 entries was condensed into a cross-identified all-sky catalogue containing molecular and gas-dust clouds. Some relationships were studied between the main physical features of clouds. Finally, we prepared a complex observing program and address future work for filling in the gaps.

SHOCKED INTERSTELLAR GAS IN THE W51 COMPLEX

  • KOO BON-CHUL
    • 천문학회지
    • /
    • 제29권spc1호
    • /
    • pp.183-186
    • /
    • 1996
  • We report the results of H I 21-cm and molecular line studies of the shocked interstellar gas in the W51 complex. We present convincing evidences suggesting that the shocked gas has been produced by the interaction of the W51C supernova remant (SNR) with a large molecular cloud, Our results show that W51C is the second SNR with direct evidences for the shocked cloud material.

  • PDF

Molecular Connectivity法을 이용한 有機化合物과 二成分 混合物에 對한 物理化學的 性質에 關한 硏究 (Ⅱ) (The Study of Physical Properties for the Organic Compounds and their Binary Mixture according to Molecular Connectivity Method)

  • 김의락;민경섭;이명재;김상해;정봉진
    • 대한화학회지
    • /
    • 제36권4호
    • /
    • pp.485-495
    • /
    • 1992
  • 기체 및 액체 상태의 여러가지 유기화합물(alcohol, acetate, alkane, acid 및 substituted NH$_2$)과 이성분계 혼합용액(n-alkane/1-chloroalkane)에 대한 점성도를 계산하기 위하여, 분자의 크기, 가지의 형태, 환상구조, 불포화의 정도, 분극성 등이 분자의 성질에 미치는 영향을 잘 설명하여 주는 molecular connectivity index, Wiener index 및 ad hoc descriptor 방법을 이용하였다. 그 결과 기체 상태에 대해서는 Wiener index 방법이, 액체 상태에 대해서는 ad hoc descriptor 방법이 그리고 이성분계에 대해서는 molecular connectivity index 방법이 우수한 방법임을 알 수 있었으며, 각각의 방법으로 구한 최적 상관관계식을 이용하여 점성도를 계산하였고, 이와 같이 구한 이론치와 점성도의 실측치를 비교할 때, 매우 잘 일치하는 결과를 얻을 수 있었다.

  • PDF

AC Impedance Study of the Electrochemical Behavior of Hydrogen/Oxygen Gas Mixture at Nafion/Catalyst Electrode Interface

  • Song, S.M.;Lee, W.M.
    • 한국수소및신에너지학회논문집
    • /
    • 제11권4호
    • /
    • pp.179-188
    • /
    • 2000
  • The anodic reaction of hydrogen/oxygen gas mixture at platinum or palladium electrode interfacing with a solid polymer electrolyte was investigated using AC impedance method. The impedance spectrum of the electrode reactions of the mixture depends on the gas composition, electrode roughness, the mode of electrochemical operation and the cell potential. For electrolysis mode of operation, the spectrum taken for the reaction on a rough platinum electrode for the gas mixture revealed clearly that the local anodic reduction of oxygen gas takes place concurrently with the anodic oxidation of hydrogen gas.

  • PDF

Analytical Application of Glow Discharge Atomic Absorption Spectroscopy (GD-AAS) Using Three Types of Jet Configurations Under Power Mode

  • Hwang, Jun Ho;Lee, Ki Beom;Kim, Min Su;Lee, Seong Ro;Kim, Hasuck;Kim, Hyo Jin;Lee, Gae Ho
    • 분석과학
    • /
    • 제8권4호
    • /
    • pp.443-448
    • /
    • 1995
  • Three anode configurations of six-jet, cone-jet and cylindrical-jet are tested for their analytical performance under power mode operation. The effect of pressure, power and gas flow rate on atomic absorption signals have been studied. The increase of atomic absorption signal of sample element is observed at a fixed pressure in all configurations as the gas flow rate increase up to 300-600 seem, and as the power dissipated in the glow discharge cell increase. The lower the pressure is in the glow discharge cell at a fixed discharge power and argon flow rate, the greater the absorbance of sample element is. The optimum conditions are taken from these data and a calibration curve of Cu in low-alloy steel sample is obtained. In this calibration curve, six-jet configuration shows the best analytical results varies as the sample element.

  • PDF

Selective 3,4-Dihydroxyphenylalanine Analysis in Human Urine as Ethoxycarbonyltert-butyldimethylsilyl Derivatives by Gas Chromatography-Mass Spectrometry

  • Paik, Man-Jeong;Nguyen, Duc-Toan;Yoon, Jae-Hwan;Cho, In-Seon;Shim, Woo-Young;Kim, Kyoung-Rae;Cho, Ki-Hong;Choi, Sang-Dun;Lee, Gwang
    • Bulletin of the Korean Chemical Society
    • /
    • 제32권3호
    • /
    • pp.977-980
    • /
    • 2011
  • A new analytical method for measurement of 3,4-dihydroxyphenylalanine (DOPA) in human urine was developed. DOPA from an aqueous solution was converted into an ethoxycarbonyl (EOC) derivative. A tertbutyldimethylsilyl (TBDMS) reaction under anhydrous conditions was then attempted for analysis by gas chromatography-mass spectrometry in selected ion monitoring mode. A new mass spectral data on DOPA as a tri-EOC/mono-TBDMS derivative was built. This method showed good linearity (r ${\geq}$ 0.999), precision (% relative standard deviation = 3.1-9.2), and accuracy (% relative error = -7.2-8.8), with a detection limit of 0.05 ng/mL. This selective and accurate method of DOPA analysis will be useful for biochemical monitoring of various neurological disorders including Parkinson's disease in biological fluids.