• Title/Summary/Keyword: molecular distribution

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A Study on Coagulation and MF Membrane Process for the Reuse of Sewage Effluent (하수처리장 방류수의 응집 및 정밀여과 처리공정에 관한 연구)

  • Paik, Ke-Jin
    • Journal of environmental and Sanitary engineering
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    • v.20 no.3 s.57
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    • pp.36-43
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    • 2005
  • Prior to the study of the sewage treatment methods, water quality for Gwangju sewage of fluent was investigated from January to December, 2004 for sewage water reuse. Monthly mean values of BOD, SS, turbidity, total phosphorus and color were 4.1 mg/L, 2.9 mg/L, 0.8 NTU, 1.3 mg/L, and 27 unit, respectively. Jar-test was performed to investigate the removal efficiency of pollutants under the coagulation conditions of fast mixing for 5 min, slow mixing for 15 min and precipitation for 1hr. Here, alum and polyaluminium chloride (PAC) were used as coagulants to reduce color, turbidity, total phosphorus (TP) and total organic carbon (TOC) in sewage effluents. The results showed that PAC gave better efficiency in removing turbidity and dissolved phosphorus than alum. It was also found from the relative molecular weight (RMW) distribution analysis that organic matter over 1,000 Dalton (Da) was easily removed by coagulation and subsequently MF treatment, while it was not effective for less than 500 Da. Based on tis result, Natural organic matter (NOM) with lower molecular weight (< 500 Da) may cause harmful disinfectant by-product (DBP) after chlorine treatment. Thus, activated carbon adsorption seems to be required for the complete removal of DBP in the hybrid system.

Effects of Salinity on Chlorophyll Fluorescence from Porphyra Thalli and Comparison of Species with Different Intertidal Distribution

  • Hong Dang Diem;Kim Tae Hoon;Hwang Mi Sook;Chung Ik Kyo;Lee Choon-Hwan
    • Fisheries and Aquatic Sciences
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    • v.1 no.1
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    • pp.122-128
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    • 1998
  • Characteristic changes in chlorophyll fluorescence from thalli of red alga, Porphyra, under high salt stress and during subsequent recovery were investigated, and the differences in the sensitivity to the stress among four species of Porphyra with different intertidal distributions were compared. By the treatment of NaCl with $9\%$ or higher concentrations, photochemical efficiency (Fv/Fm) decreased in a biphasic pattern: a rapid decrease was observed within 1­3 h and followed by a slow decline. The decrease of Fv/Fm was mainly due to the increase of Fo without significant increases of Fm. When the thalli treated with $15\%$ NaCl for 6 h were returned to natural sea water for recovery, the increase of Fv/Fm also showed a biphasic pattern: a rapid increase of Fv/Fm was observed within 2 h and followed by a slow increase. Differences in the sensitivity to salt stress among the four species could be found during recovery after the treatment of severe salt stress. After the treatment of $20\%$ NaCl for 6 h, Fv/Fm decreased below 0.3 in all of the four Porphyra species, and the species living in upper parts of the intertidal zone (P. suborbiculata and P. pseudolinearis) could recover better compared with the species in lower parts of the intertidal zone (P. seriata and P. yezoensis), during recovery for 24 h. The species collected from the coast of the South Sea seemed to be more tolerant than those in the East Sea.

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Preparation of Pitch for Melt-electrospinning from Naphtha Cracking Bottom Oil (납사 크래킹 잔사유로부터 용융전기방사용 핏치 제조)

  • Kim, Jinhoon;Lee, Sung Ho;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.402-406
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    • 2013
  • In this study, a pitch for melt-electrospinning was prepared from naphtha cracking bottom (NCB) oil by the modification with heat treatment. The softening point and property of the modified pitch was influenced by modification conditions such as nitrogen flow rate, heat treatment temperature, and reaction time. Among these, the heat treatment temperature had a very strong influence on the distribution of molecular weight and softening point of the pitch. The C/H mole ratio and average molecular weight increased with increasing the heat treatment temperature due the decomposition and cyclization reaction of surface-functional groups. In addition, the values of benzene insoluble and quinoline insoluble also tends to decrease, and the width of molecular weight distribution seems to get more narrow. The carbon fiber with a diameter of $4.8{\mu}m$ was prepared from a modified pitch at the softening point of $155^{\circ}C$ by melt-electrospinning. It is believed that the melt-electro spinning method is much more convenient to get the thinner fiber than the conventional melt spinning method.

Theory of NMR Spectoscopy and Its Application in Geoenvironmental Sciences (NMR 분광법의 원리와 지구환경과학에의 응용)

  • 김영규
    • The Journal of the Petrological Society of Korea
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    • v.10 no.3
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    • pp.233-245
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    • 2001
  • With the advent of super-conducting magnet, NMR spectroscopy becomes a very important tool in geology as well as in chemistry. $^{29}Si$ and $^{27}Al$ which are the main components of minerals and contain structural informations, are useful major targets for the NMR study in geology, but some other elements including alkali cations such as $^{23}Na$ are also one of them. NMR can be applied to many different fields. For example, it can be applied to study smaller range of structure (in molecular level) than XRD and TEM. NMR provides us with structural informations such as order-disorder in Al and Si distribution, oxygen coordination number, and distribution of other cations. Another important information that we can obtain from NMR is not only the static structural informations, but also the molecular dynamics. This dynamic informations of molecules also enable us to figure out the frequency of molecular motion and activation energy. Structure of amorphous minerals and chemistry and structure of natural organic materials are also studied by NMR.

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Is the MDR1 C3435T Polymorphism Responsible for Oral Mucositis in Children with Acute Lymphoblastic Leukemia?

  • Bektas-Kayhan, Kivanc;Kucukhuseyin, Ozlem;Karagoz, Gizem;Unur, Meral;Ozturk, Oguz;Unuvar, Aysegul;Devecioglu, Omer;Yilmaz-Aydogan, Hulya
    • Asian Pacific Journal of Cancer Prevention
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    • v.13 no.10
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    • pp.5251-5255
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    • 2012
  • Background and Aim: Although the functional consequences of MDR-1 polymorphisms have been the subject of numerous studies, to the best to our knowledge, associations with clinical side effects of anticancer drugs have yet to be assessed. Our aim was to clarify any role of the C3435T polymorphism of the MDR1 gene in oral mucositis and its relation with elevated reactive oxygen species (ROS) levels, in children with acute lymphoblastic leukemia (ALL). Materials and Methods: The distribution of the MDR-1 C3435T polymorphism in 47 patients with ALL was determined by RFLP and compared with that of 68 healthy controls. Results: There were no association in distribution of genotypes of MDR-1 C3435T polymorphism and the risk of ALL. Oral mucositis were detected in 78.7% (n=37) of the patients and significantly related to the MDR-1 CT genotype (p=0.042), as confirmed by logistic regression analysis. Conclusion: Our preliminary data suggest that children carrying the CT genotype are more prone to develop oral mucositis, which might mean that the heterozygous genotype leads to accumulation of more reactive oxygen species. Since a limited number of patients was investigated, further studies are needed to confirm these findings.

Molecular Identification and Morphological Description for Larvae and Juveniles of Deepwater Dragonet Bathycallionymus kaianus (Callionymidae, PISCES) from Korea (한국산 남방돛양태[Bathycallionymus kaianus (돛양태과)] 자치어의 분자 동정 및 형태 기재)

  • Kim, Jin-Seok;Kim, Jin-Koo;Park, Jeong-Ho;Ji, Hwan-Sung;Lee, Hae-Won
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.53 no.1
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    • pp.74-82
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    • 2020
  • Dragonet fish (Callionymidae), living in benthic upper 900 m of all subtropical, tropical and temperate oceans, comprises 200 species in 20 genera worldwide, of which 18 species in 6 genera occur in Korea. Although dragonet fish plays an important role in linking between top predators and lower trophic levels, there are only few studies about their early life history. Herein, we present molecular and morphological data on larvae and juveniles of Bathycallionymus kaianus (Günther, 1880) collected from the Korean waters. During 2016 to 2018, one preflexion larvae [2.69 in total length (TL)], three flexion larvae (3.65 and 4.77 mm TL), six postflexion larvae (6.07 and 7.94 mm TL), and three juveniles (10.81 and 12.26 mm TL) were collected in the East Sea, Korea Strait, and Jeju Island using Bongo net. Of them, 13 individuals were identified through molecular markers (COI or 16S rRNA) and morphologically described. The larvae of B. kaianus are well distinguished from other species of Callionymidae in melanophore distribution, body shape and development of preopercular spine. It was very similar to larvae of two Repomucenus species, R. valenciennei and R. virgis, but was clearly distinguished in melanophore distribution, preopercular spine development, and head shape.

Effect of Cadmium on Protein Synthesis of Cadmium-Ion Tolerant Hansenula anomala B-7 (카드뮴 내성 Hansenula anomala B-7의 단백질 합성에 미치는 카드뮴의 영향)

  • 유대식;송형익
    • Microbiology and Biotechnology Letters
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    • v.18 no.3
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    • pp.239-243
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    • 1990
  • In this study the authors investigated the distribution of cadmium accumulated in cadmium-iun tolerant Hansenula anomala B-7 cells and also the effect of cadmium on protein synthesis. 84.9% of the cadmium accumulated was distributed in the soluble fraction (cytosol, etc.). The intracellular protein content was decreased by cadmium (1,000 $\mu g$/ml), but the content of soluble protein preeipitated by ammonium sulfate (30-75% saturation) was increased compared with the content of it obtained from the cells grown without cadmium. Furthermore, in the cells grown with 1,000 $\mu g$/ml of cadmium t h higher molecular weight soluble protein was increased compared with the cells grown without caa, mium, but the lower molecular weight soluble protein was decreased. These results suggested that the protein synthesis was inhibited by cadmium, but synthesis of higher molecular weight soluble protein was remarkably stimulated by cadmium.

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A Study on the Chemical Powdering Process of Polypropylene Resin for Anti-slip Floor Paint (미끄럼 방지 바닥 도료용 폴리프로필렌 수지의 화학적 분쇄에 관한 연구)

  • Kim, D.I.;Chung, H.Y.;Hwang, S.H.;Cho, I.S.;Youn, K.J.;Cho, B.S.;Kim, K.K.;Yun, K.J.
    • Journal of the Korean Society of Safety
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    • v.27 no.6
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    • pp.78-83
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    • 2012
  • In this study, some experimental results of the peroxide-degradation process of polypropylene(PP) in a co-rotating twin-screw extruder to produce controlled rheology polypropylene(CRPP) are presented. The peroxide was dicumyl peroxide(DCP) and the concentration of DCP was in the range 0-0.3 wt%. It was found that the rheological properties of PP change significantly during reactive extrusion. Melt flow index(MFI) increased with DCP concentration. Intrinsic viscosity decreases with increasing DCP concentration. From dynamic rheological data, number average molecular weight(Mn), weight average molecular weight(Mn) and molecular weight distribution(MWD) were calculated. Results indicated that Mw decreases and MWD becomes narrower with increasing peroxide concentration. Especially, particle size distribution of CRPP decreases with increasing DCP concentration by chemical powdering process, and anti-slip floor paint, CRPP(DCP 0.2 wt%) powder by 10phr was friction coefficient 2.15 ${\mu}$, abrasion resistance 511.18%.

The Explicitly Quasi-linear Relation Between the Order Parameter and Normalized Birefringence of Aligned Uniaxially Anisotropic Molecules Determined Using a Numerical Method (수치해석적인 방법으로 규명한 정렬된 단축이방성 분자들의 질서변수와 상대 복굴절의 준선형 관계식)

  • Kim, Sang Youl
    • Korean Journal of Optics and Photonics
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    • v.27 no.6
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    • pp.223-228
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    • 2016
  • The birefringence of distributed, uniaxially anisotropic molecules like liquid crystals is calculated as the degree of ordering is varied. The relation between the normalized birefringence ${\Delta}n_{rel}$ and the orientational order parameter S is investigated. The distribution function, which enables one to monitor the degree of ordering of liquid crystals including randomly distributed ones, is introduced. Using this distribution function, a series of distributed liquid crystals with order parameters ranging from 0 to 1 are generated, and ${\Delta}n_{rel}$ and S of the correspondingly distributed liquid crystals are calculated. Based on the calculated data, it is revealed that ${\Delta}n_{rel}$ and S satisfy the quasi-linear relation of $S=(1+a){\Delta}n_{rel}-a{\Delta}n^2_{rel}$, where a can be approximated as $n_o{\frac{{\Delta}n}{4}}$. The anisotropy of molecular polarizability is also calculated, using the birefringence, and separately following Vuks' method and Neugebauer's method, and it is shown that the relations between S and the molecular-polarizability anisotropy are also quasi-linear.

Induced Charge Distribution Using Accelerated Uzawa Method (가속 Uzawa 방법을 이용한 유도전하계산법)

  • Kim, Jae-Hyun;Jo, Gwanghyun;Ha, Youn Doh
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.34 no.4
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    • pp.191-197
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    • 2021
  • To calculate the induced charge of atoms in molecular dynamics, linear equations for the induced charges need to be solved. As induced charges are determined at each time step, the process involves considerable computational costs. Hence, an efficient method for calculating the induced charge distribution is required when analyzing large systems. This paper introduces the Uzawa method for solving saddle point problems, which occur in linear systems, for the solution of the Lagrange equation with constraints. We apply the accelerated Uzawa algorithm, which reduces computational costs noticeably using the Schur complement and preconditioned conjugate gradient methods, in order to overcome the drawback of the Uzawa parameter, which affects the convergence speed, and increase the efficiency of the matrix operation. Numerical models of molecular dynamics in which two gold nanoparticles are placed under external electric fields reveal that the proposed method provides improved results in terms of both convergence and efficiency. The computational cost was reduced by approximately 1/10 compared to that for the Gaussian elimination method, and fast convergence of the conjugate gradient, as compared to the basic Uzawa method, was verified.