• Title/Summary/Keyword: modified slag

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An empirical relationship for compressive strength of preplaced aggregate concrete with modified binder

  • Kunal Krishna Das;Eddie Siu-Shu Lam;Jeong Gook Jang
    • Computers and Concrete
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    • v.31 no.6
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    • pp.545-559
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    • 2023
  • In this study, an experimental investigation was conducted to assess the influence of ground granulated blast furnace slag (GGBS) and silica fume (SF) on the fresh and hardened properties of grout specimens and preplaced aggregate concrete (PAC). Grout proportions were optimized statistically using a factorial design and were applied to 10 mm and 20 mm coarse aggregates to produce PAC. The results demonstrate that GGBS has a more significant effect on the compressive strength of grout compared to SF, with a small increase or decrease in the GGBS content having a greater influence on the compressive strength of grout than SF. The water to binder ratio had the most significant effect on the compressive strength of PAC, followed by the coarse aggregate size and sand to binder ratio. An empirical relationship to predict the compressive strength of PAC was proposed through an experimentally derived factorial design along with a statistical analysis of collectively obtained data and a deep literature review. The results predicted by the empirical relationship were in good agreement with those of PAC produced for verification.

Experimental Study on the Material Characteristics of Slag Cement with Various Phosphogypsum Materials (인산부산석고의 각 형태조건에 따른 슬래그 시멘트의 품질특성에 관한 실험적 연구)

  • Park, Jong-Tak;Oh, Hong-Seob
    • Journal of the Korea Concrete Institute
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    • v.21 no.6
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    • pp.729-735
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    • 2009
  • In this study, it is experimentally verified a feasibility of the wasted phosphogypsum ($CaSO_4/H_2O$) that is a byproduct from the phosphoric acid process of manufacturing fertilizers can be applied as an admixture in slag cement. For the test, phosphogypsum is modified as dihydrate, hemihydrate, type III anhydrite, and type II anhydrite, and then chemical characteristics and mechanical properties of various slag cements containing above mentioned gypsum materials were analyzed. The test results show that the gypsum made at high temperature has better quality with decrease of water-soluble phosphoric acid ($S-P_2O_5$) which has an effect on the quality of cement. And type II anhydrite shows superior quality in terms of drying shrinkage and the compressive strength of cement paste with hemihydrate at 56 days is higher than other gypsum material.

The Fundamental Study of Strength and Drying Shrinkage on Alkali-activated Slag Cement Mortar with Different Entering Point of Fine Aggregate (잔골재의 투입시점에 따른 알칼리 활성화 슬래그 모르타르의 강도와 건조수축에 대한 기초적 연구)

  • Kim, Tae-Wan;Eom, Jang-Sub;Seo, Ki-Young;Park, Hyun-Jae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.2
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    • pp.117-125
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    • 2014
  • This paper examines the fundamental properties of alkali-activated slag cement (AASC) activated by sodium hydroxide (NaOH). The water to binder (W/B) ratio was 0.4 and 0.5. And concentration of activator were 2M and 4M. Five mix design of each W/B ratios was considered. The N0 mixture was KS L 5109 method and N1~N4 were varied in different mixing time, mix step and entering points of fine aggregate. Test results clearly showed that the flow value, strength and drying shrinkage development of AASC were significantly dependent on the entering point of fine aggregate. The flow value tended to decreases with delaying entering point of fine aggregate. The compressive strength and flexural strength increases with delaying entering point. Moreover, the XRD analysis confirmed that there were sustain these results. The drying shrinkage increases with delaying entering point of fine aggregate. Futhermore, a modified mixing method incorporating all hereby experimentally derived parameters, is proposed to improvement the physical properties of AASC.

Freeze-Thaw Resistance of Alkali Activated Ternary Blended Cement Incorporated with Ferronickel Slag (알칼리 활성화제를 첨가한 페로니켈슬래그 혼입 삼성분계 콘크리트의 동결융해 저항성)

  • Cho, Won-Jung;Park, Kwang-Pil;Ann, Ki-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.2
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    • pp.159-167
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    • 2022
  • The present study assessed the micro structure and durability characteristics of ternary blended cement with different types of alkali activators. Ground granulated blast furnace slag(GGBS) and ferronickel slag(FNS) was replaced until 50 % of the weight of cement. In addition, potassuim hydroxide and sodium hydroxide were used for comparing the properties of different type of alkali activator. Ternary blended cement with alkali activators showed higher peak portlandite peak than that of OPC(Ordinary Portlande Cement) and non activated ternary blended cement. Also, there was no new hydration products in ternary blended cement or/and alkali activators. Based on the mercury intrustion porosimetry(MIP) test result, ternary blended cement increased macro pore while alkali activated ternary blended cement modified pore structure and increased microp pore as compared to OPC as control. Combination with alkali activators is desirable to enhance the compressive strength and freeze thaw resistance.

Application of Alkali-Activated Ternary Blended Cement in Manufacture of Ready-Mixed Concrete (알칼리 활성화 3성분계 혼합시멘트의 레미콘 적용 시험)

  • Yang, Wan-Hee;Hwang, Ji-Soon;Lee, Sea-Hyun
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.1
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    • pp.47-54
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    • 2017
  • Cement industry is typical carbon-emission industry. If the industrial by-products(granulated blast-furnace slag (GGBFS), fly ash, etc.) are used a large amount, it might be able to reduce cement consumption and mitigate carbon emissions. In this case, however, decrease of early strength is relatively large. Therefore, there is a limitation in increase of the amount of substitute. Considering these circumstances, it would be a good solution to reduce carbon emissions in cement industry to improve the performances of mixed cement through proper alkali-activation in Portland blended cement using GGBFS or fly ash. Therefore, this study prepared concrete in ready-mixed concrete manufacturing facilities with an addition of a binder which used 2.0% modified alkali sulfate activator after mixing Portland cement, GGBFS and fly ash in the ratio of 4:4:2 and assessed its basic properties. The results found the followings: The use of modified alkali-sulfate activator slightly reduced slump and shortened setting time. As a result, bleeding capacity decreased while early strength improved. In addition, there is no big difference in carbonation resistance. It appears that there should be continued experiments and analyses on the related long-term aged specimens.

Investigation of Physical Properties and Self Healing of Hardener-Free Epoxy-Modified Mortars with GGBFS (고로슬래그미분말을 혼입한 경화제 무첨가 에폭시수지 모르타르의 물리적 성질 및 자기치유 검토)

  • Jo, Young-Kug;Kim, Wan-Ki
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.1
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    • pp.80-87
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    • 2020
  • The purpose of this study is to investigate the physical properties and self-healing effects of hardener-free epoxy-modified mortars(EMMs) using ground granulated blast furnace slag(GGBFS). The EMMs with GGBFS were prepared with various polymer-binder ratios and GGBFS contents, and tested for strengths, adhesion in tension, water permeation and self-healing effects. The conclusions obtained from the test results are summarized as follows. The compressive strength of the EMMs with GGBFS is reduced with increasing polymer-binder ratios because of reduction of the degree of hardening in the EMMs, and is somewhat inferior to that of unmodified mortars. In the flexural and tensile strengths, the flexural strength of the EMMs is almost constant with increasing polymer-binder ratios. However, the tensile strength of the EMMs is gradually increased with increasing polymer-binder ratios. Regardless of the GGBFS contents, the adhesion in tension of the EMMs increases sharply with increasing polymer-binder ratios. The water permeation of the EMMs is remarkably reduced with increasing polymer-binder ratios and GGBFS contents. The self-healing effect of the hardener-free EMMs with GGBFS is improved with increasing water immersion period at a GGBFS content of 20%.

ASR Resistance of Ternary Cementitious Systems Containing Silica Fume-Fly Ash Using Modified ASTM C 1260 Method

  • Shon, Chang-Seon;Kim, Young-Su;Jeong, Jae-Dong
    • Journal of the Korea Concrete Institute
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    • v.15 no.3
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    • pp.497-503
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    • 2003
  • Supplementary cementitious materials (SCM) such as fly ash, ground granulated blast furnace slag and silica fume are now being extensively used in concrete to control expansion due to alkali-silica reactivity (ASR). However, the replacement level of a single SCM needed to deleterious ASR expansion and cracking may create other problem and concerns. For example, incorporating silica fume at levels greater than 10% by mass of cement may lead to dispersion and workability concerns, while fly ash can lead to poor strength development at early age, The combination of silica fume and fly ash in ternary cementitious system may alleviate this and other concerns, and result in a number of synergistic effects. The aim of the study was to enable evaluation of more realistic suitability of a silica fume-fly ash combination system for ASR resistance based on an in-house modification of ASTM C 1260 test method. The modification can be more closely identified with actual field conditions. In this study three different strengths of NaOH test solution(1N, 0.5N, and 0.25N) were used to measure the expansion characteristics of mortar bar made with a reactive aggregate. The other variable included longer testing period of 28 days instead of a conventional 14 days.

Bridge Deck Overlay Technology Using High Performance Concrete (고성능 콘크리트를 활용한 교량 교면포장 기술)

  • Park, Hae-Geun;Won, Jong-Pil
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.1113-1116
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    • 2008
  • The application of High Performance Concrete (HPC) for protecting bridge deck concrete with micro-silica, fly-ash and ground granulated blast-furnace slag was introduced to North America in the early 1980's. This report introduces the literature reviews of high performance concrete for protecting concrete bridge deck and explains 2-different types of construction methods using this materials. One is high performance concrete overlay method and the other is full depth bridge deck method. Both methods have been successfully applied and demonstrated in north america. Especially, modified high performance concrete overlay method including silica-fume and PVA fiber has been successfully applied in korea also. Therefore, both methods that high performance concrete overlay and full depth bridge deck are considered as reasonable bridge deck protecting methods compared with the conventional bridge deck system using asphalt modified materials.

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The mechanical properties of Reactive Powder Concrete using Ternary Pozzolanic Materials exposed to high Temperature (3성분계 포졸란재를 이용한 반응성 분체 콘크리트(RPC)의 고온특성)

  • Janchivdorj, Khulgadai;So, Hyoung-Seok;Yi, Je-Bang;So, Seung-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.11a
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    • pp.68-71
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    • 2013
  • Reactive Powder Concrete (RPC) is an ultra high strength and high ductility cement-based composite material and has shown some promise as a new generation concrete in construction field. It is characterized by a silica fume-cement mixture with very low water-binder (w/b) ratio and very dense microstructure, which is formed using various powders such as cement, silica fume and very fine quartz sand (0.15~0.4mm) instead of ordinary coarse aggregate. However, the unit weight of cement in RPC is as high as 900~1,000 kg/㎥ due to the use of very fine sand instead of coarse aggregate, and a large volume of relatively expensive silica fume as a high reactivity pozzolan is also used, which is not produced in Korea and thus must be imported. Since the density of RPC has a heavy weight at 2.5~3.0 g/㎤. In this study, the modified RPC was made by the combination of ternary pozzolanic materials such as blast furnace slag and fly ash, silica fume in order to economically and practically feasible for Korea's situation. The fire resistance and structural behavior of the modified RPC exposed to high temperature were investigated.

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Investigation on the Method of Evaluating the Resistance to Freezing and Thawing of Concrete Subjected Initial Frost Damage (초기동해를 받은 콘크리트의 내동해성 평가법에 대한 검토)

  • 고경택;장일영
    • Journal of the Korea Concrete Institute
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    • v.11 no.4
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    • pp.117-127
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    • 1999
  • In concrete incorporating high volume ground granulated blast-furnace slag that has frozen at early age, to evaluated the results of resistance to freezing and thawing is very difficult because the hydration of the concrete increases over the duration of rapid freezing and thawing test. Hence, the dynamic modulus of elasticity of specimens after freezing and thawing will be favorable results unless the hydration effect is taken into consideration. In this study, a method of evaluating to the resistance to freezing and thawing of concrete subjected freezing at early age, in which the effect of hydration is modified for its increase during rapid freezing and thawing test, is investigated.