• Title/Summary/Keyword: modified epoxy

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Optimization of Slurry Preparation Process for Soft Magnetic Green Sheet (연자성 복합체 후막용 슬러리 제조공정의 최적화)

  • Oh, Sea Moon;Lee, Chang Hyun;Shin, Hyo Soon;Yeo, Dong Hun;Kim, Jin Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.12
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    • pp.792-796
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    • 2015
  • With high integration of electronic components, power inductors are also miniaturized. Recently, thick film processes for small size power inductors were developed and commercialized. However, the thick film process to prepare soft magnetic green sheets was not reported enough. In this study, we used Fe-Si magnetic and CIP (carbonyl iron powders) as starting materials to lead to a bimodal particle size distribution in the sheet. We proposed a newly developed 'Modified slurry preparation process' to get well dispersed condition even at high solid contents. Using the new process, it was possible to prepare a well dispersed slurry over 70 vol% of solid. BYK-103 was better than BYK-111 as dispersant in this slurry and the optimum amount was 0.6 wt%. The optimized slurry was formed into a sheet by tape casting process and then the sheet was laminated. We conformed that small size powder, large size powder, and epoxy resin were well dispersed in the green sheet.

Fabrication of Electrochemical Microbial Biosensor Based on MWNT Supports Prepared by Radiation-Induced Graft Polymerization (방사선 그래프트법에 의해 제조된 탄소나노튜브 지지체를 기반으로 한 전기화학 미생물 바이오센서의 제작)

  • Shin, Soo-Ran;Kwen, Hai-Doo;Choi, Seong-Ho
    • Polymer(Korea)
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    • v.35 no.3
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    • pp.216-222
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    • 2011
  • A multi-walled carbon nanotube (MWNT) support with dual properties, an ionic property via tetra-amine and unpaired electrons via tri-amine, was prepared by radiation-induced graft polymerization of glycidyl methacrylate (GMA) and the subsequent amination of its epoxy group. The electrochemical microbial biosensor (EMB) was then fabricated by immobilization of a microbe (Alkaligenes spp.) onto the dual property-modified electrode, which was prepared with the mixture of the MWNT support and a $Nafion^{(R)}$ solution on a glass carbon (GC) electrode surface by a hand-casting method. The sensing range of the prepared EMB for phenol in a phosphate buffer solution was 0.005~7.0 mM. The total concentration of phenolic compounds in a commercial red wine was also determined using the EMB.

Dynamic response of a laminated hybrid composite cantilever beam with multiple cracks & moving mass

  • Saritprava Sahoo;Sarada Prasad Parida;Pankaj Charan Jena
    • Structural Engineering and Mechanics
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    • v.87 no.6
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    • pp.529-540
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    • 2023
  • A novel laminated-hybrid-composite-beam (LHCB) of glass-epoxy infused with flyash and graphene is constructed for this study. The conventional mixture-rule and constitutive-relationship are modified to incorporate filler and lamina orientation. Eringen's non-local-theory is used to include the filler effect. Hamilton's principle based on fifth-order-layer-wise-shear-deformation-theory is applied to formulate the equation of motion. The analogous shear-spring-models for LHCB with multiple-cracks are employed in finite-element-analysis (FEA). Modal-experimentations are conducted (B&K-analyser) and the findings are compared with theoretical and FEA results. In terms of dimensionless relative-natural-frequencies (RNF), the dynamic-response in cantilevered support is investigated for various relative-crack-severities (RCSs) and relative-crack-positions (RCPs). The increase of RCS increases local-flexibility in LHCB thus reductions in RNFs are observed. RCP is found to play an important role, cracks present near the end-support cause an abrupt drop in RNFs. Further, multiple cracks are observed to enhance the nonlinearity of LHCB strength. Introduction of the first to third crack in an intact LHCB results drop of RNFs by 8%, 10%, and 11.5% correspondingly. Also, it is demonstrated that the RNF varies because of the lamina-orientation, and filler addition. For 0° lamina-orientation the RNF is maximum. Similarly, it is studied that the addition of graphene reduces weight and increases the stiffness of LHCB in contrast to the addition of flyash. Additionally, the response of LHCB to moving mass is accessed by appropriately modifying the numerical programs, and it is noted that the successive introduction of the first to ninth crack results in an approximately 40% to 120% increase in the dynamic-amplitude-ratio.

Tensile Properties of CERP Composite with Different Resin Composition under Cryogenic Temperature (극저온 환경에서 탄소섬유강화 복합재료의 수지조성변화에 따른 인장 물성 측정)

  • Kim, Myung-Gon;Kang, Sang-Guk;Kong, Cheol-Won;Kim, Chun-Gon
    • Composites Research
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    • v.20 no.4
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    • pp.1-8
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    • 2007
  • In this study, carbon fiber reinforced polymeric (CFRP) composites with different resin composition were manufactured and resin formulation in composite materials were presented through tensile tests for cryogenic use. Thermo-mechanical cyclic loading (up to 6 cycles) was applied to CFRP unidirectional laminate specimens from room temperature to $-150^{\circ}C$. Tensile tests were then performed at $-150^{\circ}C$ using an environmental test chamber. In addition, matrix-dominant properties such as the transverse and in-plane shear characteristics of each composite model were measured at $-150^{\circ}C$ to examine the effects of resin formulation on their interfacial properties. The tensile tests showed that the composite models with large amounts of bisphenol-A epoxy and CTBN modified rubber in their resin composition had good mechanical performance at cryogenic temperature (CT).

An Evaluation of Structural Integrity and Crashworthiness of Automatic Guideway Transit(AGT) Vehicle made of Sandwich Composites (샌드위치 복합재 적용 자동무인경전철 차체 구조물의 구조 안전성 및 충돌 특성 평가 연구)

  • Ko, Hee-Young;Shin, Kwang-Bok;Cho, Se-Hyun;Kim, Dea-Hwan
    • Composites Research
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    • v.21 no.5
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    • pp.15-22
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    • 2008
  • This paper describes the results of structural integrity and crashworthiness of Automatic Guideway Transit(AGT) vehicle made of sandwich composites. The applied sandwich composite of vehicle structure was composed of aluminum honeycomb core and WR580/NF4000 glass fabric/epoxy laminate composite facesheet. Material testing was conducted to determine the input parameters for the composite facesheet model, and the effective equivalent damage model fer the orthotropic honeycomb core material. The finite element analysis using ANSYS v11.0 was dont to evaluate structural integrity of AGT vehicle according to JIS E 7105 and ASCE 21-98. Crashworthiness analysis was carried out using explicit finite element code LS-DYNA3D with the lapse of time. The crash condition was frontal accident with speed of 10km/h at rigid wall. The results showed that the structural integrity and crashworthiness of AGT vehicle were proven under the specified loading and crash conditions. Also, the modified Chang-Chang failure criterion was recommended to evaluate the failure modes of composite structures after crashworthiness event.

A Study on Crashworthiness and Rollover Characteristics of Low-Floor Bus made of Honeycomb Sandwich Composites (하니컴 샌드위치 복합재를 적용한 저상버스의 충돌 및 전복 특성 연구)

  • Shin, Kwang-Bok;Ko, Hee-Young;Cho, Se-Hyun
    • Composites Research
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    • v.21 no.1
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    • pp.22-29
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    • 2008
  • This paper presents the evaluation of crashworthiness and rollover characteristics of low-floor bus vehicles made of aluminum honeycomb sandwich composites with glass-fabric epoxy laminate facesheets. Crashworthiness and rollover analysis of low-floor bus was carried out using explicit finite element analysis code LS-DYNA3D with the lapse of time. Material testing was conducted to determine the input parameters for the composite laminate facesheet model, and the effective equivalent damage model for the orthotropic honeycomb core material. The crash conditions of low-floor bus were frontal accident with speed of 60km/h. Rollover analysis were conducted according to the safety rules of European standard (ECE-R66). The results showed that the survival space for driver and passengers was secured against frontal crashworthiness and rollover of low-floor bus. Also, The modified Chang-Chang failure criterion is recommended to predict the failure mode of composite structures for crashworthiness and rollover analysis.

Adhesive Strength in Tension of SBR-Modified Cement Mortar with Self-Flowability Material for Floor-Finishing (자기 평활성 바닥 마감용 SBR 시멘트 모르타르의 인장부착강도)

  • Do, Jeong-Yun;Soh, Yang-Seob
    • Journal of the Korea Concrete Institute
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    • v.15 no.4
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    • pp.549-556
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    • 2003
  • Various researches on the application of polymer dispersions to the cement mortar and concrete have been practised in many countries like America, Japan and Germany and so on because of high performance and good modification effect of these. In this study, SBR, Polymer dispersion that widely used in situ is employed that the self-flowability may be induced in the cemen mortar. In order to comprehend and investigate the modification of cement mortar with self-flowability by SBR and properties and fracture mode of adhesive strength in tension of that, experimental parameter was set as SBR solid-Cement ratio(S/C) and Cement:Fine aggregate(C:F) and the experiments such as Unit weight, Flow, Consistency change, Crack resistance and Segregation that inform on the general properties have been done. In addition of that, Adhesion in tension is measured with a view to comprehending the properties and fracture mode in tensile load. Consistency change of cement mortar modified by SBR did grow better as the ratio of SBR solid-Cement increased and was much superior to that of resin based flooring such as polyurethane and epoxy which recorded the loss of consistency in 90min. after mixing. Adhesive strength in tension increased with continuity in the curing age and showed the maximum in case of C:F=1:1 and S/C=20%. As the increase of curing age, the fracture mainly happened in the concrete substrate and the interface between the specimen and concrete substrate.

An analytical Study for the Development of Highly Elastic Material applicable for Joint in Modular Pavement (모듈러 포장에 적용가능한 고탄성 연결재료 개발을 위한 해석적 연구)

  • Lee, Young-Ho;Kang, Su-Tae;Song, Jae-Joon;Lee, Sang-Yoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.11
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    • pp.5947-5955
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    • 2013
  • This study was intended to estimate the axial deformation of joint between pavement modules in the rapid-constructible modular pavement system, and to investigate the applicability of two-phase composites for a joint material, which was composed of cement paste, epoxy, or polyurethane as a matrix and sand as particles. A case which had supports under the pavement module as well as a case which the module was put on roadbed directly were considered in FEM analysis for the axial deformation. The effect of self-weight, live load, thermal change, and drying shrinkage were estimated and the thermal change was found to cause the largest deformation compared to the others. Deformation capacity of two-phase composites was predicted using the modified shear-lag model. In the analytical results for the elastic modulus and maximum tensile strain with different volume fractions of sand, 20~30 % replacement of sand was revealed to satisfy the required strain capacity with economy when if the width of joint was designed to be 15~20 mm.

Effects of Fiber Surface Modification on the Flow Characteristics and Wettability in the Resin Transfer Molding Process (섬유의 표면개질이 수지이동 성형공정에서의 유동특성 및 젖음성에 미치는 영향)

  • 김세현;이건웅;이종훈;김성우;이기준
    • The Korean Journal of Rheology
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    • v.11 no.1
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    • pp.34-43
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    • 1999
  • Flow-induced voids during resin impregnation and poor fiber wetting have known to be highly detrimental to the performance of composite parts manufactured by resin transfer molding(RTM) process. In this study, in order to overcome these serious problems encountered in RTM, the effects of surface modification by using silane coupling agent as a surface modifier on the flow characteristics, the wetting between resin and fiber, and void content were investigated. For the experiments of microscopic flow visualization and curing in a beam mold, glass fiber mats having plain weaving structure and epoxy resin were used. Modifying the fiber surface was found to result in a significant decrease of dynamic contact angle between resin and fiber and increase of wicking rate. Therefore, it was confirmed that the surface modification employed in this study could improve the wettability of reinforcing fibers as well as micro flow behavior. In addition, It was revealed that high temperature and low penetration rate of the resin are more favorable processing conditions to reduce the dynamic contact angle. However, surface modified fiber mat was found to have lower permeability than the unmodified one, which may be explained in terms of the decrease of contact time between resin and fiber owing to improvement of wetting. It was also exhibited that surface modification had a significant influence on void formation in RTM process, resulting in a decrease of overall void content due to the improvement of wetting in cured composite parts.

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Development and Performance Evaluation of Anti-cavitation Paint with a Lamella Glass-flake (판상형 Glass-flake를 이용한 내캐비테이션 도료 개발 및 성능평가)

  • Park, Hyeyoung;Kim, Sung-gil;Kim, Sang-suk;Choi, I-chan;Kim, Byungwoo;Kim, Seung-jin
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.145-151
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    • 2016
  • In response to the cavitation caused by the partial vacuum caused by the fluid flow, a paint was developed by dispersing the lamella-shaped glass-flake in resin for anti-cavitation. This composite paint was developed by using the inorganic filler (lamella shaped glass-flake) and the NBR (Acrylonitrile-butadiene rubber) which was modified epoxy resin. Especially, the glass-flake was a thin film with a thickness of about 100~200 nm and length of about $20{\sim}30{\mu}m$, the aspect ratio was about 200 to 300 times that of the plate-shaped. So the paint for anti-cavitation have shown excellent performance in corrosion resistance. The results of evaluating anti-cavitation performance was below, tensile strength $4.8{\sim}6N/mm^2$ or more, rupture elongation 30% or higher, abrasive speed $10mm^2/h$ or less. In particular, it showed more than twice the superior performance compared to existing advanced foreign products in anti-cavitation performance evaluation.