• Title/Summary/Keyword: modified PET

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Development of Synthetic Sizing Agent Using Recycling Polyethylene Terephthalate and its Sizing Efficiency (Part 2) - Sizing efficiency of modified PET - (재활용 PET를 활용한 합성 사이즈제 개발 및 종이의 내수성 부여에 관한 연구 (제2보) - 개질 PET의 내수특성 평가 -)

  • Park, Jae-Seok;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.2
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    • pp.95-101
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    • 2010
  • For the development of higher-sizing performance of paper, a sizing agent using recycled PET was synthesised. Polyester resin was extracted from wasted PET by subcritical hydrolysis and finally modified to synthetic sizing agent by mixing water-disperse PET with triphenyl phosphite(TPP). The modified PET was considered as an internal sizing agent in different wet-end papermaking conditions. The optimum condition in sizing efficiency was obtained in initial pH of 6.5 in case of rosin+alum system, and 7.5 in case of rosin+alum+PET system, respectively, and in addition amount of PET 3%. The sizing efficiency was also closely related according to the fiber properties of wet-end slurry, such as virgin fibres from UKP and recycled fibres from KOCC. The application of modified PET was good in strength improvement of paper, specially in tensile strength.

Preparation of Polymer-modified Mortars with Recycled PET and Their Sound Absorption Characteristics (재활용 PET 를 이용한 고분자 몰타르의 제조 및 흡음 특성)

  • Hong, Byung-Pyo;Byun, Hong-Sik
    • Polymer(Korea)
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    • v.34 no.5
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    • pp.410-414
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    • 2010
  • Two different types of polymer-modified mortars(PMM) were prepared with recycled PET and fly-ash. One is rigid PMM and the other is flexible PMM which are based on the composition of recycled PET. Their mechanical properties including friction coefficient measurement and damping characteristics such as sound absorption were investigated and compared with the commercial PMM such as epoxy PMM and PET PMM. The result from mechanical properties indicated that the rigid PMM could be competitive with the commercial PET PMM. The measurement of sound absorption coefficient showed that both rigid PMM and flexible PMM had much better damping capacity than commercial PMM. However, the friction coefficient of rigid PMM revealed that it would be suitable for the use as floor material.

Development of Synthetic Sizing Agent Using Recycling Polyethylene Terephtahalate and its Sizing Efficiency (Part 1) - Manufacture of sizing agent with recycling PET - (재활용 PET를 활용한 합성 사이즈제 개발 및 종이의 내수성 부여에 관한 연구 (제1보) - 재활용 PET를 이용한 내수제 제조 -)

  • Park, Jae-Seok;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.4
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    • pp.27-33
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    • 2008
  • Polyethylene terephtahalate has been used in several areas such as fiber, film, bottle, and disposable products. Production of PET has been rapidly increasing these days. Since PET is a semi-permanent material, it has a non-biodegradable character in itself. Wasted PET products can cause serious environmental problems. Many countries around the world impose environmental legal restrictions over their abandonments. Many researches on the enviromental influence factors and treatment techniques of the wasted PET have been carried out. The main objective of this study is to develop a new sizing agent using recycling PET and improve its internal sizing effect. Dried powder of PET was used to make the modified PET. After extracting water-dispersible PET by subcritical hydrolysis, polyester resins have been extracted and triphenyl phosphate(TPP) has been added to obtain optimal internal sizing agent. It was found that the optimum dosage of TPP was 2% (per PET weight) and the hydrolysis temperature was independent on making the modified PET.

Crystallization Behavior of PET Modified by Pentanediol units (Pentanediol unit로 개질된 PET의 결정화 거동)

  • Lee, Sun-Hui;Sim, Mi-Ja;Kim, Sang-Wook
    • Korean Journal of Materials Research
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    • v.2 no.2
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    • pp.101-109
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    • 1992
  • Polyethylene terephthalate(PET) is a well known commercial polymer widely available as fibre and as a major polymer with diverse applications. In this experiment, for the modification of PET, the pentanediol isomers, 1,5-pentanediol(1,5-PD) and neopentyl glycol(NPG), were introduced as third monomers. Crystallization rate decreased by the added NPG of PET modified by NPG units. In the case of PET modified by 1,5-PD, crystallization rate had been slightly increased at all temperatures until the 1,5-PD was added about 10 mol%. The decreased crystallization rate is thought to be due to branched from methyl group of neopentyl, which greatly retards the crystallization by growing onto the crystal surface of the diffused polymer chain.

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Preparation of Poly(ethylene terephthalate) fibers containing Pely(hydroxy ether of bisphenol A) (Poly(hydroxy ether of bisphenol A)를 함유한 PET섬유 제조)

  • Lim, Sang Kyu;Park, Kwang Hyun;Son, Tae Won;Song, Jae Soo
    • Textile Coloration and Finishing
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    • v.9 no.2
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    • pp.17-24
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    • 1997
  • PET/PHE blends were prepared by the mixing of poly(ethylene terephthalate) and poly(hydroxyether of bisphenol A) at melt state above PET melting temperature and modified PET fibers having less than 5 wt% of PHE were also prepared by the melt spinning of the PET/PHE blends. The PET/PHE blends were able to prepare by means of physical mixing concept, except the chemical interaction between hydroxyl groups of PHE and ester groups of PET. It has been revealed that the modified PET fibers have some hydrophilic properties such as low contact angle and easy-dyeable characters.

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Determination of Tensile Modulus of PHB/PEN/PET Fiber Using Modified Halpin-Tsai Equation (변형 Halpin-Tsai식에 의한 PHB/PEN/PET 섬유의 탄성률 예측)

  • 정봉재;김성훈;이승구;전한용
    • Polymer(Korea)
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    • v.24 no.6
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    • pp.810-819
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    • 2000
  • Poly(p-hydroxybenzoate) (PHB)/poly(ethylene terephthalate) (PET) 8/2 thermotropic liquid crystalline copolyester, poly(ethylene 2,6-naphthalate) (PEN), and PET ternary blend was spun to fiber by melt spinninB process, and tensile properties of the fibers were measured. The matrix of the fibers, PET and PEN, were dissolved in ο-chlorophenol at 55$^{\circ}C$ for 2 hours, and the liquid crystalline polymer fibrils were observed using a scanning electron microscope. Halpin-Tsai equation for modulus calculation of short fiber reinforced composite and the rule of mixture for continuous reinforcement composite were modified, and the tensile modulus were calculated and compared with experimental modulus. To minimize difference between the theoretical and the experimental moduli, dimensionless viscosity constant (K) was given and used to modify two equations. The theoretical tensile modulus using the newly modified equations presentel a similar to the experimental tensile modulus of composite, and the modified equations presented a unique way to determine the tensile modulus of the liquid crystalline polymer reinforced thermoplastic composites.

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Estimation of Paddy Rice Crop Coefficients for FAO Penman-Monteith and Modified Penman Method (논벼에 대한 Penman-Monteith와 FAO Modified Penman 공식의 작물 계수 산정)

  • Yoo Seung-Hwan;Choi Jin-Yong;Jang Min-Won
    • Journal of The Korean Society of Agricultural Engineers
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    • v.48 no.1
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    • pp.13-23
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    • 2006
  • In 1998, Food and Agriculture Organization addressed that FAO Modified Penman method possibly over-estimates consumptive use of water comparing to the measured reference crop evapotranspiration (PET) and Penman-Monteith method can be better choice for accurate PET estimation. Nevertheless it is still difficult to find research efforts about paddy rice crop coefficient for Penman-Monteith method. This study aims to estimate paddy rice crop coefficients for Penman-Monteith and FAO modified Penman methods in the manner of comparing two equations. To estimate the crop coefficients, measured evapotranspiration data during 1982-1986 and 1995-1997 were used. The average Penman-Monteith crop coefficients ranged from 0.78 to 1.58 for translated paddy rice and from 0.87 to 1.74 for flood-direct seeded paddy rice. The average FAO Modified Penman crop coefficients ranged from 0.65 to 1.35 for translated paddy rice and from 0.70 to 1.58 for flood-direct seeded paddy rice.

Effect of Compatibilizer Types on the Properties of Linear PPS/PET Blends (상용화제의 종류가 선형 PPS/PET 블렌드의 물성에 미치는 영향)

  • Kim, Sungki;Hong, In-Kwon;Lee, Sangmook
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.500-506
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    • 2013
  • The effect of compatibilizer types on the properties of polyphenylene sulfide (PPS)/polyethylene terephthalate (PET) blends was investigated. The blends were extruded by a single screw extruder attached with a Maddock mixing zone and their molded properties were examined. As a basic blend composition, a linear PPS/PET (40/60) blend was selected based on cost efficiency. Three types of compatibilizer, SEBS, modified SEBS, and modified PS were added to the basic blend to improve the properties. The thermal, rheological, mechanical properties and the morphology of the ternary blends were analyzed. The maximum mechanical properties of blends was found at 1 phr of m-SEBS or m-PS content, whose values were almost the same as the theoretical values of miscible blend system. It seemed to by the case that the partial reaction between compatibilizer and the basic blend caused the enhancement of compatibility between linear PPS and PET phases. These ternary blends would be applicable as economic linear PPS alloys.

Study on the Hydrophilicity of Modified Polyester (개질시킨 폴리에스테르 중합체의 친수성 연구)

  • Jung, Byung-Ok
    • Applied Chemistry for Engineering
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    • v.9 no.6
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    • pp.930-934
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    • 1998
  • The modified poly(ethylene terephthalate) (PET) was synthesized by copolymerizing dimethyl terephthalate with ethylene glycol, polyethyleneglycol, and dodecylbenzene sulfonate as a surfactant. After characterization of viscosity, color, and contant angle, hydrophilic characteristics of the modified PET depending on additives was discussed.

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Efficiency of Median Modified Wiener Filter Algorithm for Noise Reduction in PET/MR Images: A Phantom Study (PET/MR 영상에서의 팬텀을 활용한 노이즈 감소를 위한 변형된 중간값 위너필터의 적용 효율성 연구)

  • Cho, Young Hyun;Lee, Se Jeong;Lee, Youngjin;Park, Chan Rok
    • Journal of radiological science and technology
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    • v.44 no.3
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    • pp.225-229
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    • 2021
  • The digital image such as medical X-ray and nuclear medicine field mainly contains noise distribution. The noise degree in image degrades image quality. That is why, the noise reduction algorithm is efficient for medical image field. In this study, we confirmed effectiveness of application for median modified Wiener filter (MMWF) algorithm for noise reduction in PET/MR image compared with median filter image, which is used as conventional noise redcution algorithm. The Jaszczak PET phantom was used by using 18F solution and filled with NaCl+NiSO4 fluids. In addition, the radioactivity ratio between background and six spheres in the phantom is maintained to 1:8. In order to mimic noise distribution in the image, we applied Gaussian noise using MATLAB software. To evlauate image quality, the contrast to noise ratio (CNR) and coefficient of variation (COV) were used. According to the results, compared with noise image and images with MMWF algorithm, the image with MMWF algorithm is increased approximately 33.2% for CNR result, decreased approximately 79.3% for COV result. In conclusion, we proved usefulness of MMWF algorithm in the PET/MR images.