• Bulletin of the Korean Chemical Society
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• v.11 no.4
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• pp.297-302
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• 1990

Retention of mono-substituted phenols in reversed-phase liquid chromatography has been studied based on the linear solvation energy relationships using the solvatochromic mobile phase parameters, ${\pi}_m^{\ast}, {\alpha}_m$ and ${\beta}_m$. It has been observed that retention behavior of phenols in RPLC were well represented by regression equations vs. solvatochromic mobile phase parameters even though the equations may be incomplete due to lack of an explicit cavity term. Dependence of retention of monosubstituted phenols on the mobile phase properties were varied depending on the type of the organic cosolvent in the mobile phase, e.g., ${\beta}_m$ and {\alpha}_m$ in methanol-water system, but ${\pi}_m^{\ast} and ${\beta}_m$ in THF-water system. It has been suggested that retention of phenols in methanol-water system is controlled by the solvophobicity of the mobile phase.

• KSBB Journal
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• v.25 no.3
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• pp.205-214
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• 2010

Many successive liquid-liquid extractions occur enabling purification of the crude material to occur. In high performance counter-current chromatography (HPCCC), crude material is partitioned between two immiscible layers of solvent phases. The stationary phase (SP) is retained by hydrodynamic force field effect and the mobile phase (MP) is pumped through the column. Purification occurs because of the different solubility of the components in the liquid mobile and stationary phases. There are many key benefits of liquid stationary phases such as high mass and volume injection loadings, total sample recovery, and easy scale-up. Many researchers showed that predictable scale-up from simple test is feasible with knowledge of the stationary phase retention for the planned process scale run. In this review we review the recent advances in HPCCC research and also describe the key applications such as natural products and synthetics (small or large molecules).

• Smart Structures and Systems
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• v.13 no.3
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• pp.407-418
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• 2014

The purpose of this paper is to present an Integrated Life Cycle Bridge Information Modeling that can be used throughout different phases of the bridge life cycle including: design, construction, and operation and maintenance phases. Bridge Information Modeling (BrIM) has become an effective tool in bridge engineering and construction. It has been used in obtaining accurate shop drawings, cost estimation, and visualization. In this paper, BrIM is used as an integrated tool for bridges life cycle information modeling. In the design phase, BrIM model can be used in obtaining optimum construction methods and performing structural advanced analysis. During construction phase, the model selects the appropriate locations for mobile cranes, monitors the status of precast components, and controls documents. Whereas, it acts as a tool for bridge management system in operation and maintenance phase. The paper provides a detailed description for each use of BrIM model in design, construction, and operation and maintenance phases of bridges. It is proven that BrIM is an effective tool for bridge management systems throughout their life phases.

• International Journal of Computer Science & Network Security
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• v.22 no.9
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• pp.389-395
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• 2022

A Mobile Sensor Network is widely used in real time applications. A critical need in Mobile Sensor Network is to achieve energy efficiency during routing as the sensor nodes have scarce energy resource. The nodes' mobility in MWSN poses a challenge to design an energy efficient routing protocol. Clustering helps to achieve energy efficiency by reducing the organization complexity overhead of the network which is proportional to the number of nodes in the network. This paper proposes"EERA: Energy Efficient Routing Algorithm for Mobile Sensor Network" is divided into five phases. 1, Cluster Formation 2.Cluster head and Transmission head selection 3.Path Establishment / Route discovery and 4,Data Transmission. Experimental Analysis has been done and is found that the proposed method performs better than the existing method with respect to four parameters.

• Biotechnology and Bioprocess Engineering:BBE
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• v.9 no.1
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• pp.47-51
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• 2004

Ceramide III was prepared by the cultivation of Saccharomyces cerevisiae. Ceramide III was partitioned from the cell extracts by solvent extraction and analyzed by Normal Phase High Performance Liquid Chromatography (NP-HPLC) using Evaporative Light Scattering Detector (ELSD). We experimentally determined the mobile phase composition to separate ceramide III with NP-HPLC. Three binary mobile phases of n-hexane/ethanol, n-hexane/lsoprophyl Alcohol(IPA) and n-hexane/n-butanol and one ternary mobile phase of n-hexane/IPA/methanol were demonstrated. For the binary mobile phase of n-hexane/ethanol, the first mobile phase composition, 95/5(v/v), was step-increased to 72/23(v/v) at 3 min. In the binary mobile phase, the retention time of ceramide III was 7.87min, while it was 4.11 min respectively in the ternary system, where the mobile phase composition of n-hexane/IPA/methanol, 85/7/8(v/v/v), was step-increased to 75/10/15(v/v/v) at 3 min. However, in the ternary mobile phase, the more peak area of ceramide III was observed.

• ETRI Journal
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• v.28 no.3
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• pp.275-281
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• 2006

A very simple and efficient scheme for jitter reduction is proposed for a carrier frequency recovery loop using phase differential frequency estimation, which estimates the current frequency offset based on the difference of the average phases of two successive intervals. Analytical and numerical results presented in this paper show that by simply overlapping the observation intervals by half for frequency offset estimations, both the steady-state and transient performances can be improved. The proposed scheme does not require any additional hardware circuitry, but results in improved performance even with reduced complexity.

• Bulletin of the Korean Chemical Society
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• v.34 no.9
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• pp.2623-2628
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• 2013

Three di-acyl chlolide reagents, adipoyl chloride, terephthaloyl chloride and isophthaloyl chloride, were used as spacer reagents to prepare bonded type of three cellulose (3,5-dimethylphenyl)carbamate (CDMPC) chiral stationary phases (CSPs). The CDMPC CSPs were prepared using these three acid chlorides as spacer agents at the 6-position of the primary hydroxyl group on the glucose unit of cellulose regioselectively. The chiral recognition ability of the prepared CSPs for five racemates was evaluated by normal-phase high-performance liquid chromatography (HPLC) with the following mobile phases: hexane/isopropanol (IPA), hexane/IPA/tetrahydrofuran (THF) and hexane/IPA/chloroform. The result showed that these prepared CSPs can be used in THF and chloroform solutions and the chiral recognition abilities of the CSPs were improved depending on the eluents and chiral samples.

• Macromolecular Research
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• v.15 no.2
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• pp.134-141
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• 2007

The direct chromatographic separation of enantiomers by chiral stationary phases (CSPs) has been extensively developed over the past two decades, and has now become the most popular method for the analytical and preparative separations of enantiomers. Polysaccharide derivatives coated onto silica gel, as CSPs, playa significantly important role in the enantioseparations of a wide range of chiral compounds using high-performance liquid chromatography (HPLC). Unfortunately, the strict solvent limitation of the mobile phases is the main defect in the method developments of these types of coated CSPs. Therefore, the immobilization of polysaccharide derivatives onto silica gel, via chemical bonding, to obtain a new generation of CSPs compatible with the universal solvents used in HPLC is increasingly important. In this article, our recent studies on the immobilization of polysaccharide derivatives onto the silica gel, as CSPs, through radical copolymerization with various vinyl monomers are reported. Polysaccharide derivatives, with low vinyl content, can be efficiently fixed onto silica gel with high chiral recognition.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.8 no.3
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• pp.857-872
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• 2014

Recent researches reveal that great benefit can be achieved for data gathering in wireless sensor networks (WSNs) by employing mobile data collectors. In order to balance the energy consumption at sensor nodes and prolong the network lifetime, a multi-track large-scale mobile data collection mechanism (MTDCM) is proposed in this paper. MTDCM is composed of two phases: the Energy-balance Phase and the Data Collection Phase. In this mechanism, the energy-balance trajectories, the sleep-wakeup strategy and the data collection algorithm are determined. Theoretical analysis and performance simulations indicate that MTDCM is an energy efficient mechanism. It has prominent features on balancing the energy consumption and prolonging the network lifetime.

• Journal of Institute of Control, Robotics and Systems
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• v.16 no.11
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• pp.1110-1116
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• 2010

This paper present an effective complementary filtering method using encoder and gyro sensors for the self-localization(including heading and velocity) of indoor mobile robot. The main idea of the proposed approach is to find the pros and cons of each sensor through a various maneuvering tests and to design of an adaptive complementary filter that works for the entire maneuvering phases. The proposed method is applied to an indoor mobile robot and the performances are verified through extensive experiments.