• Title/Summary/Keyword: mixture designs

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Design of Experiments for Enhanced Catalytic Activity: Cu-Embedded Covalent Organic Frameworks in 4-Nitrophenol Reduction

  • Sangmin Lee;Kye Sang Yoo
    • Applied Chemistry for Engineering
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    • v.35 no.4
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    • pp.346-351
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    • 2024
  • Chemical reduction using catalysts and NaBH4 presents a promising approach for reducing 4-nitrophenol contamination while generating valuable byproducts. Covalent organic frameworks (COFs) emerge as a versatile platform for supporting catalysts due to their unique properties, such as high surface area and tunable pore structures. This study employs design of experiments (DOE) to systematically optimize the synthesis of Cu embedded COF (Cu/COF) catalysts for the reduction of 4-nitrophenol. Through a series of experimental designs, including definitive screening, mixture method, and central composition design, the main synthesis parameters influencing Cu/COF formation are identified and optimized: MEL:TPA:DMSO = 0.31:0.36:0.33. Furthermore, the optimal synthesis temperature and time were predicted to be 195 ℃ and 14.7 h. Statistical analyses reveal significant factors affecting Cu/COF synthesis, facilitating the development of tailored nanostructures with enhanced catalytic performance. The catalytic efficacy of the optimized Cu/COF materials is evaluated in the reduction of 4-nitrophenol, demonstrating promising results in line with the predictions from DOE.

Improvisation and Fantasy: Beauvais Grotesque Tapestry (즉흥과 환상: 보베 제작소의 《그로테스크》 태피스트리)

  • Chung, Eunjin
    • Art History and Visual Culture
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    • no.21
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    • pp.126-147
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    • 2018
  • This paper is to find the theme and meaning of the Beauvais Grotesque tapestry considered a conundrum. The three works are chosen from Beauvais Grotesque consisting of six tapestries, which are The Offering to Pan, The Musician and Dancers, The Camel in the J. Paul Getty Museum. I analyzed these works by dividing them into grotesque ornaments, chinoiserie motifs, and scenography. The Offering to Pan shows the influence of Raphael's Grotesque tapestry, but Beauvais work followed the design of Jean Berain's Grotesque with arabesque. In The Musician and Dancers, chinese ceramics, textiles, and Chinese people in edge were noted. Especially, the Chinese with yellow skin in the border reveals the European gaze on China at that time. In the 18th century, Chinoiserie was prevalent through stage designs rather than books. The Camel, playing Brighella, makes it clear that this tapestry is a stage of Comedia dell'arte. The characteristic of Comedia is a mixture of genres such as music and dance, with no scripting 'improvisation.' Features of Comedia are 'improvisation' without a script and a mixture of genres such as music and dance. Thus, the Grotesque tapestry transfers the stage of the Comedia into threads woven. In addition, the horizontal stage decoration with the disappearance of the perspective vanishing point is related to the era of regent of Philippe d'Orl?ans (1674-1723). Above all, the grotesque, Chinoiserie, and scenography are all fantasies separated from reality. Therefore, the Beauvais Grotesque tapestry represents of 'improvisation' and 'fantasy' in which there is no narrative theme or meaning, as if the script of Comedia did not exist.

A Study of the Changes and the Types of Chinese Women's Clothing Resulted from the Introduction of European Culture (서구문화의 유입에 따른 중국 여성 복식의 변화와 그 유형에 대한 연구 - 20세기 전반기를 중심으로 -)

  • Cho, Yong-Ran;Lee, Keum-Hee
    • The Research Journal of the Costume Culture
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    • v.16 no.5
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    • pp.891-909
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    • 2008
  • The purpose of this study was to examines the changes in Chinese women's clothing resulted from the introduction of Western culture in the first hal# of the 20th century in terms of Chinese view of the world and their attitude towards European culture. The clothes are divided into four types according to their characteristics : traditional Chinese type, China-Europe adjustment type, China-Europe blend type and European type. As for the research method, both literature and visual data are examined. The traditional Chinese type showed changes only in the width and length retaining the features of the traditional qipao until the 1910s. The China-Europe adjustment type used the same flat pattern making of traditional Chinese dress while imitating only the appearances of European one-piece, two-piece and three-piece dresses. It also was presented with European accessaries and hair-styles. The China-Europe blend type, starting to appear with the introduction of the three-dimensional pattern making from the Europe in the 1930s, showed a perfect mixture of European and traditional Chinese costumes in the early 1940s when the Chinese learned and adapted the European pattern making. The European type was the most modernized designs using a variety of European-style details and constructions as the traditional clothing started to have unrestricted European-style changes. Great significance can be found in the fact that the Chinese modified their garments by themselves using the pattern mating they learned from the Europe.

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A Study on the Purchasing Practices of Pet Dog's Apparel (애완견 의류 구매 실태에 관한 연구)

  • Kim, Jung-Sook;Kweon, Soo-Ae;Choi, Jong-Myoung
    • Journal of the Korean Society of Clothing and Textiles
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    • v.31 no.2 s.161
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    • pp.189-196
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    • 2007
  • The purpose of this study was to find out the purchasing practices and consumer's needs for pet dog apparel to provide useful information for the manufacture of pet dog's apparel. Data were obtained from 203 consumers who have purchased dog apparel(55 male, 148 female). 57.9% of them were 20-30 years old, 27.9% were living in houses, 54.3% were apartment residents. The kinds of dog included were Shihtzu, Martise, and Yorkshireterrier, and 2/3 of the respondents own a single dog, the remainder have at least two dogs. The most important factor to consider when purchasing dog apparel was size, followed by comfort, design, and materials in that order, Most of the apparel was purchased with convenience as the primary consideration, and the average price was 10-30 thousands won, and the items were purchased at pet beauty shops or specialty shops. For materials, it showed that the majority preferred cotton or a cotton mixture which was woven or woven with knit. The survey revealed that the main purposes for the apparel were, in order, to protect the dog from cold weather and direct sunlight, to be good looks and to memorialize a special day. Consumers put the apparel on their dogs 1-3 times per week, on average, and also when they went out for a walk. They were satisfied with the design, color and quality of the material now on the market, but unsatisfied with size and price. They have a preference for cute, but simple designs and a functional style. The respondents wanted to have material that was mild or neutral, stain-resistant, and something that would repel insects.

Optimal Design for Heterogeneous Adder Organization Using Integer Linear Programming (정수 선형 프로그래밍을 이용한 혼합 가산기 구조의 최적 설계)

  • Lee, Deok-Young;Lee, Jeong-Gun;Lee, Jeong-A;Rhee, Sang-Min
    • Journal of KIISE:Computer Systems and Theory
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    • v.34 no.8
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    • pp.327-336
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    • 2007
  • Lots of effort toward design optimizations have been paid for a cost-effective system design in various ways from a transistor level to RTL designs. In this paper, we propose a bit level optimization of an adder design for expanding its design space. For the bit-level optimization, a heterogeneous adder organization utilizing a mixture of carry propagation schemes is proposed to design a delay-area efficient adder which were not available in an ordinary design space. Then, we develop an optimization method based on Integer Linear Programming to search the expanded design space of the heterogeneous adder. The novelty of the Proposed architecture and optimization method is introducing a bit level reconstruction/recombination of IPs which have same functionality but different speed and area characteristics for producing more find-grained delay-area optimization.

Modeling, Simulation and Optimization of Hydrogen Production Process from Glycerol using Steam Reforming (글리세롤로부터 수증기 개질에 의한 수소 생산공정의 모델링, 시뮬레이션 및 최적화)

  • Park, Jeongpil;Cho, Sunghyun;Lee, Seunghwan;Moon, Dong Ju;Kim, Tae-Ok;Shin, Dongil
    • Korean Chemical Engineering Research
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    • v.52 no.6
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    • pp.727-735
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    • 2014
  • For improved sustainability of the biorefinery industry, biorefinery-byproduct glycerol is being investigated as an alternate source for hydrogen production. This research designs and optimizes a hydrogen-production process for small hydrogen stations using steam reforming of purified glycerol as the main reaction, replacing existing processes relying on steam methane reforming. Modeling, simulation and optimization using a commercial process simulator are performed for the proposed hydrogen production process from glycerol. The mixture of glycerol and steam are used for making syngas in the reforming process. Then hydrogen are produced from carbon monoxide and steam through the water-gas shift reaction. Finally, hydrogen is separated from carbon dioxide using PSA. This study shows higher yield than former U.S. DOE and Linde studies. Economic evaluations are performed for optimal planning of constructing domestic hydrogen energy infrastructure based on the proposed glycerol-based hydrogen station.

An Analysis of Codes on Brand Image in Fashion Advirtsing (의류 광고에 나타난 상표 이미지의 코드 분석)

  • 한명숙;나수임
    • The Research Journal of the Costume Culture
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    • v.5 no.4
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    • pp.68-79
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    • 1997
  • In this thesis which takes fashion advertising that functions a marketing communication as an objective, I try to bear witness to the signifying system of garments though analyzing with semiotic methodology the signifying procedure on the base of the structural concept of Ferdinand de Saussure and the advertisement semiotic theory of Roland Barthes, to make clear their signifying structure and it meaning by understanding the characteristics of contemporary society and its cognitive system. Each sign of fashion advertising transfers the brand image through syntagmatic signification which contains the mythology of goods. Mannish style is encoded as tailored jacket, white shirt, H-silhouette and pants, non-color or being color, and it is presented as a clothing sign of casual wear for career women. Feminine style is encoded as X-silhouette, soutien collar suit style, various colors, and other details with womanly image, and it is presented as a clothing sign for maid or young wife 20\`s or 30\`s. Formal style is encoded as jacket vest, inner wear(blouse), two and three piece dress by pants or skirt and one-piece dress, and it is used in every age and class. Casual style is similar to formal style, but differs only in textile code. Clothing sign for housewives in middle age is encoded as H-silhouette of formal style, long jacket and pants and brown, being and grey colors. Contemporary popular phenomena in the signification of fashion advertising, and its temporal ideology reflected are as follows; According to the context of fashion advertising in the middle of 1990\`s, its fashion is that first, military look applied from the designs of various sort of military uniform and vest look and pant style applied from dandy-style imitated from man\`s wear are popuar. This mean that it reflects the change of point of view on woman\`s role in society today. That is, due to the equality between man and woman, it mirrors the ideology of feminism, and then, describes beautifully professional woman with carrer. Second, because that individualism is underlied for the change of consumer\`s consciousness, standardized popularity is disappeared, and in accordance with the mixture of various trends and personalities proposed every season, layered look that emphasizes individualism, easiness and naturalness is popular.

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Physical Properties and Low Temperature Resistance of Recycled Binder (재생 아스팔트 바인더의 물리적 특성과 저온균열 저항성 연구)

  • Lee, Young-Gwan;Kim, J.E.;Do, Young-Soo;Kim, Kwang-Woo
    • International Journal of Highway Engineering
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    • v.6 no.4 s.22
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    • pp.1-12
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    • 2004
  • This study evaluated the asphalt binder characteristics for the hot-recycled asphalt mixture in which RAP was added in ambient temperature for surface course as well as for base course. RAPs were collected from four sources and their physical properties were evaluated. Mix designs were performed using 10 and 20% RAP contents for surface courses and 10, 20 and 30% for base courses. A virgin asphalt with the penetration grade of 60-80 was used for mixing recycled mixtures. Physical properties of recycled binders, including penetration, absolute viscosity, GPC, BBR and penetration after TFO were measured. From the results, regression analysis of absolute viscosity versus LMS in GPC showed $R^2$ being over 0.95, showing that GPC results estimate the absolute viscosity with relative accuracy. In BBR test, the resistance of recycled mixtures at low service temperature was inferior to the control, because the low temperature PG of recycled binder was one grade higher than that of the control binder.

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A study of characteristics and historical backgroud of modem furniture design in Italy (이탈리아 현대 가구디자인의 특성 및 그 배경 -1945년부터 현재를 중심으로-)

  • 정은미
    • Archives of design research
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    • v.14 no.1
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    • pp.119-134
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    • 2001
  • It can be said that Italian designs are unrestrained, aesthetic and art for arts sake, and they come to stylize their character based on geographical features, racial traits and culture. The Italian architects work for the reconstruction of their devastated country and spare no pains to produce competitive goods on international markets since the second wend war. In spite of a inherent scarcity of resources, Italian furniture is the product of mixture of aesthetic material and new material with creative gifts. A lot of companies succeed in finding and training capable designers and devote themselves to modem furniture industry. As a result, Italy becomes one of the worlds most eminent furniture industrial countries now. And the fame is owed to Italy's national awareness of the importance of the matter and endeavor without sparing systematic support. This research is to find out which factors have an influence on the progress of furniture design in Italy and to analyze how these factors build up formative arts combining with historical background in Italy. Moreover, this research suggests how to make contributions to the cause of furniture design growth when considering our geographical features, racial characteristics, culture and industrial circumstances, by analyzing the process of development and strategy in Italian design industry.

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Development of a Spray-Injection Patching System and a Field Performance Evaluation of 100% RAP Asphalt Mixtures using a Rapid-Setting Polymer-Modified Asphalt Emulsion (아스팔트 긴급보수용 스프레이 패칭 장비 개발 및 현장 적용성 평가)

  • Han, Soo Hyun;Lee, Sang Yum;Rhee, Suk Keun;Kwon, Bong Ju
    • International Journal of Highway Engineering
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    • v.20 no.1
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    • pp.77-85
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    • 2018
  • PURPOSES : The purpose of this study was to develop an urgent road-repair system and perform a field applicability test, as well as discover the optimum mix design for machine applications compared to the optimum mix design for lab applications. METHODS : According to reviews of the patent and developed equipment, self-propelled and mix-in-place equipment types are suitable for urgent pavement repair, e.g., potholes and cracks. The machine-application mix design was revised based on the optimum lab-test mix design, and the field application of a spray-injection system was performed on the job site. The mixture from the machine application and lab application was subjected to a wet-track abrasion test and a wheel-tracking test to calibrate the machine application. RESULTS and CONCLUSIONS : This study showed that the binder content could differ for the lab application and the machine application in the same setting. Based on the wet-track abrasion test result, the binder contents of the machine application exceeded the binder contents of the lab application by 1-1.5% on the same setting value. Moreover, the maximum dynamic stability value for the machine application showed 1% lower binder contents than the maximum lab-application value. Collectively, the results of the two different tests showed that the different sizes and operating methods of the machine and lab applications could affect the mix designs. Further studies will be performed to verify the bonding strength and monitor the field application.