• Title/Summary/Keyword: mixing speed

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Mechanism for Ni/YSZ Nano-composite Anode from Spherical Core-shell Formation

  • An, Yong-Tae;Choe, Byeong-Hyeon;Ji, Mi-Jeong;Gu, Ja-Bin;Hwang, Hae-Jin
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.31.2-31.2
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    • 2011
  • We studied a method of manufacturing an anode to restrict contraction in reducing NiO/YSZ by uniformly mixing. In order to mix Ni and YSZ, a sub-micron Ni core surface was coated at high-speed by a mixture of nano-sized YSZ and a spherical core-shell was subsequently formed. The micron-sized core-shell anode powder was then heat treated at $400{\sim}1,450^{\circ}C$ in an air atmosphere and Ni was extruded and synthesized in nano-size. Subsequently, when the nano-sized mixture of the anode was heat treated and maintained at a temperature of $1,450^{\circ}C$, the anode was manufactured, where Ni and YSZ were uniformly distributed with the nano-structure. According to the nano-sized anode powder synthesis process, Ni particles were oxidized at $400{\sim}500^{\circ}C$ and became spherical by surface tension. In the case of the spherical core Ni powder, the heat treatment temperature rose to $1,250^{\circ}C$ and then a gap between the internal and external pressures occurred due to thermal and tensile stresses. A crack subsequently appeared on the surface, and the heat treatment temperature was increased continuously to increase the pressure gap and then the core Ni extruded as a nano-sized powder, Ni and YSZ uniformly distributed. It was found that the anode of 50~200 nm with a consistent structure obtained in this study has electric conductivity that is approximately 3 times larger than that of a commercial anode.

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A Study on Physical Dechlorination of Mixed Plastics using Screw Reactor (스크류반응기를 이용한 흔합플라스틱의 물리적 탈염소에 관한 연구)

  • Kim Sang-Guk;Eom Yujin;Chung Soo-Hyun
    • Resources Recycling
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    • v.15 no.1 s.69
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    • pp.20-27
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    • 2006
  • PVC is the thermoplastic offering excellent material properties. PVC has been used in wide variety of applications, however, it causes environmental problems when it is discarded because of its high chlorine content. Since dechlorination reaction of PVC is taking place at relatively low temperature compared to the pyrolysis temperature of plastics, study on the dechlorination reaction has been carried out as a pre-treatment process. Twin screw reactor which shows excellent mixing capabilities is employed. Experimental variables are the first and second reactor temperature, PVC content in mixed plastics, viscosity of mixed plastics, feeding rate, rotational speed or the second reactor. Over $90\%$ of dechlorination ratio can be obtained under proper operation conditions. Chlorine gas evolved from reactor is absorbed in water and can be recovered as a hydrochloric acid. Analysis had been done on chlorine flows by taking material balance over realtor.

Impacts of Land Surface Boundary Conditions on the Short-range weather Forecast of UM During Summer Season Over East-Asia (지면경계조건이 UM을 이용한 동아시아 여름철 단기예보에 미치는 영향)

  • Kang, Jeon-Ho;Suh, Myoung-Seok
    • Atmosphere
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    • v.21 no.4
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    • pp.415-427
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    • 2011
  • In this study, the impacts of land surface conditions, land cover (LC) map and leaf area index (LAI), on the short-range weather forecast over the East-Asian region were examined using Unified Model (UM) coupled with the MOSES 2.2 (Met-Office Surface Exchange Scheme). Four types of experiments were performed at 12-km horizontal resolution with 38 vertical layers for two months, July and August 2009 through consecutive reruns of 72-hour every 12 hours, 00 and 12 UTC. The control experiment (CTRL) uses the original IGBP (International Geosphere-Biosphere Programme) LC map and old MODIS (MODerate resolution Imaging Spectroradiometer) LAI, the new LAI experiment (NLAI) uses improved monthly MODIS LAI. The new LC experiment (NLCE) uses KLC_v2 (Kongju National Univ. land cover), and the new land surface experiment (NLSE) uses KLC_v2 and new LAI. The reduced albedo and increased roughness length over southern part of China caused by the increased broadleaf fraction resulted in increase of land surface temperature (LST), air temperature, and sensible heat flux (SHF). Whereas, the LST and SHF over south-eastern part of Russia is decreased by the decreased needleleaf fraction and increased albedo. The changed wind speed induced by the LC and LAI changes also contribute the LST distribution through the change of vertical mixing and advection. The improvement of LC and LAI data clearly reduced the systematic underestimation of air temperature over South Korea. Whereas, the impacts of LC and LAI conditions on the simulation skills of precipitation are not systematic. In general, the impacts of LC changes on the short range forecast are more significant than that of LAI changes.

Tower-based Flux Measurement Using the Eddy Covariance Method at Ieodo Ocean Research Station (이어도해양과학기지에서의 에디 공분산 방법을 이용한 플럭스 관측)

  • Lee, Hee-Choon;Lee, Bang-Yong;Kim, Joon;Shim, Jae-Seol
    • Ocean and Polar Research
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    • v.26 no.2
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    • pp.145-154
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    • 2004
  • Surface energy and $CO_2$ fluxes have been measured over an ocean at Ieodo Ocean Research Station of KORDI since May 2003. Eddy covariance technique, which is a direct flux measurement, is used to quantitatively understand the interaction between the ocean surface and the atmospheric boundary layer. Although fluxes were continuously measured during the period from May 2003 to February 2004, the quality control of these data yielded <20% of data retrieval. The atmospheric stability did not show any distinct dirunal patterns and remained near-neutral to stable from May to June but mostly unstable during fall and winter in 2003. Sensible heat flux showed a good correlation with the difference between the sea water temperature and the air temperature. The maximum fluxes of sensible heat and latent heat were $120Wm^{-2}$ and $350Wm^{-2}$ respectively, with an averaged Bowen ratio of 0.2. The ocean around the tower absorbed $CO_2$ from the atmosphere and the uptake rates showed seasonal variations. Based our preliminary results, the daytime $CO_2$ flux was steady with an average of $-0.1 mgCO_2m^{-2}s^{-1}$ in summer and increased in winter. The nighttime $CO_2$ uptake was greater and fluctuating, reaching up to $-0.1 mgCO_2m^{-2}s^{-1}$ but these data require further examination due to weak turbulent mixing at nighttime. The magnitude of $CO_2$ flux was positively correlated with the half hourly changes in horizontal mean wind speed. Due to the paucity of quality data, further data collection is needed for more detailed analyses and interpretation.

Seasonal Variation of Planktonic Foraminifera Assemblage in response to Seasonal Shift of Inter-Tropical Convergence Zone in the Northeastern Equatorial Pacific (적도수렴대의 위치변화에 따른 북동태평양 적도해역의 부유성 유공충 군집의 계절변동)

  • Lee, Yuri;Asahi, Hirofumi;Woo, Han Jun;Kim, Hyung Jeek;Lee, Seong-Joo;Khim, Boo-Keun
    • Ocean and Polar Research
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    • v.36 no.4
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    • pp.437-445
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    • 2014
  • A time-series sediment trap was operated at a water depth of 4950 m from July 2003 to May 2004 at KOMO station ($10^{\circ}30^{\prime}N$, $131^{\circ}20^{\prime}W$) in the northeastern equatorial Pacific, with the aim of understanding the temporal variation of planktonic foraminifera assemblages in response to the seasonal shift of Inter-Tropical Convergence Zone (ITCZ). A total of 22130 planktonic foraminifera specimens belonging to 30 species and 11 genera were identified, which shows a distinct seasonal variation with high values (125~288 specimens $m^{-2}day^{-1}$) in the winter to spring (December-May) and low values (16~23 specimens $m^{-2}day^{-1}$) in the fall (September-November). In addition, seasonal ecological differences of foraminifera assemblages are distinctly recognizable: omnivorous foraminifera occurred predominantly during the summer season, whereas herbivorous ones were dominant during the winter season. Such seasonal variations correspond to the seasonal shift of the ITCZ. Enhanced occurrence of herbivorous species during the winter-spring season seems a result of surface water mixing generated by the southward shift of the ITCZ. The increase in omnivorous species during the summer season may be due to the northward movement of the ITCZ caused by weakened wind speed, resulting in the intensification of water column stratification and nutrient-poor environment. A significant reduction of planktonic foraminifera specimens during the fall is attributed to heavy precipitation and reduction in light intensity.

Simulation of Atmospheric Dispersion over the Yosu Area -II. Diurnal Variations by Solar Radiation- (여수지역 대기확산의 수치 모사 -II. 일사에 의한 일변화-)

  • 오현선;김영성
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.3
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    • pp.225-236
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    • 2000
  • Diurnal variations of wind field and pollutant dispersion over the Yosu area under the insolation conditions of summer and winter were investigated by using the Regional Atmospheric Modeling System (RAMS). Initially, horizontally homogeneous wind field were assumed on the basis of sounding data at the Kwangju upper-air station for days whose morning wind speeds were below 2m/s. In these days, the sea breeze prevailed in summer while the land breeze lasted for a few hours in the morning; the effect of synoptic winds was strong in winter with some inclusion of wind variations owing to the interaction between sea and land. The predicted wind direction at the location of the Yosu weather station captured an important change of the sea-land breeze of the observed one. The predicted wind speed and the air temperature agreed with observed ones in a reasonable range. In the morning, both in summer and winter, winds around the source location were diverged and became weak between the mountainous area to the southeast and the Kwangyang Bay to the north. Winds, however, accelerated while blowing to the east and south and blowing on the mountainous area. Complicated wind fields resulted in high pollutant concentrations at almost all receptors considered. These high concentrations in the morning were even comparable to the ISCST3 calculations with the worst-case and typical meteorological conditions designated by USEPA(1996). On the other hand, in the afternoon, the wind field was rather uniform even in the mountainous area with development of mixing layer and the concentration distributions being close to the Gaussian distributions.

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A Study on Physical Dechlorination of Mixed Plastics using Screw Reactor (스크류반응기를 이용한 혼합플라스틱의 물리적 탈염소에 관한 연구)

  • Kim, Sang-Guk;Eom, Yu-Jin;Chung, Soo-Hyun
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.10a
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    • pp.83-96
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    • 2005
  • PVC is the thermoplastic offering excellent material properties. PVC is used in wide variety of applications, however, it causes environmental problems when it is discarded because of its high chlorine content. Since dechlorination reaction of PVC is taking place relatively low temperature compared to the pyrolysis temperature of plastics, study on the dechlorination reaction has been carried out as a pre-treatment process. Twin screw reactor which shows excellent mixing capabilities is employed. Experimental variables are first and second reactor temperature, PVC content in mixed plastics, viscosity of mixed plastics, feeding rate, rotational speed of the second reactor. Over 90% of dechlorination rate can be obtained under proper operation conditions. Chlorine gas evolved from reactor is absorbed in water and can be recovered as a hydrochloric acid. Analysis had been done on chlorine flows by taking material balance over reactor.

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Vertical Distribution and Potential Risk of Particulate Polycyclic Aromatic Hydrocarbons in High Buildings of Bangkok, Thailand

  • Pongpiachan, Siwatt
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.3
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    • pp.1865-1877
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    • 2013
  • Vertical variations of polycyclic aromatic hydrocarbon (PAH) concentrations in $PM_{10}$ were investigated in order to assess the factors controlling their behavior in the urban atmosphere of Bangkok City, Thailand. Air samples were collected every three hours for three days at three different levels at Bai-Yok Suit Hotel (site-1 and site-2) and Bai-Yok Sky Hotel (site-3) in February $18^{th}-21^{st}$, 2008. The B[a]P concentration showed a value 0.54 fold, lower than the United Kingdom Expert Panel on Air Quality Standard (UK-EPAQS; i.e. 250 pg $m^{-3}$) at the top level. In contrast, the B[a]P concentrations exhibited, at the ground and middle level, values 1.50 and 1.43 times higher than the UK-EPAQS standard respectively. PAHs displayed a diurnal variation with maximums at night time because of the traffic rush hour coupled with lower nocturnal mixing layer, and the decreased wind speed, which consequently stabilized nocturnal boundary layer and thus enhanced the PAH contents around midnight. By applying Nielsen's technique, the estimated traffic contributions at Site-3 were higher than those of Site-1: about 10% and 22% for Method 1 and Method 2 respectively. These results reflect the more complicated emission sources of PAHs at ground level in comparison with those of higher altitudes. The average values of incremental individual lifetime cancer risk (ILCR) for all sampling sites fell within the range of $10^{-7}-10^{-6}$, being close to the acceptable risk level ($10^{-6}$) but much lower than the priority risk level ($10^{-4}$).

Implementation of counterfeit banknote detection counter using RTOS (RTOS를 이용한 위폐검출 계수기의 구현)

  • 정원근;신태민;이건기
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.6 no.2
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    • pp.364-370
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    • 2002
  • A banknote counter is a machine that automates counting the money in some agencies to treat much banknotes as well as general banking agencies. The banknote counter materialized in this paper is the machine that adds the function of banknote sorting, detecting plural banknote and detecting counterfeit banknote to an existing banknote counter. The technique of sensor signal processing are used for banknote sorting. The technique of sensor application and data processing are used for detecting counterfeit banknote. The technique of precision equipment design and microprocessor application are used for high speed count. Software improved in debugging and difficulties to link with additional hardware. It was materialized through effective control algorithm and real-time signal processing with C-language on the basis of RTOS(real-time operating system) Photodiode, its applications and a magnetic resistance sensor are used as a sensor device with regard to hardware cost -cutting and process velocity. PCF80C552-24 of Philips using Intel I8051 core is used as a control microprocessor. As the results so far achieved, counterfeit banknotes made by the use of a color duplicator and a color Printer, are distinguished from real banknotes through mixing an optical with a magnetic sensor. and, in case that there are some different banknotes while counting, it is prevented for them to be counted without discriminating from the same kind of banknotes in addition to the fu notion of banknote sorting.

A Study on Basic Properties of the Reinforced-roadbed Material Using Water Quenched Blast Furnace Slag (수재슬래그를 이용한 강화노반재료의 기초적 특성 연구)

  • 이선복;윤지선
    • Journal of the Korean Geotechnical Society
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    • v.19 no.1
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    • pp.103-110
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    • 2003
  • The development of reinforced-roadbed material in substitute for existing roadbed is necessary to protect its failure from the dynamic stress and vibration caused by the traveling of the high-speed and heavy trains. The water quenched blast furnace slag having potential hydraulic reactivity is one of the materials in substitute for soil reinforced-roadbed. We carried out the study of basic properties of roadbed material using Portland cement and CSA(calcium sulphoaluminate) as the activator for the evaluation of its application. As the result of the strength test, this material satisfied design criterion for reinforced-roadbed. Optimum mixing ratio of this reinforced-roadbed material was 15 ~ 17.5 percent of cement and 2.5 percent of CSA by weight of the blast furnace slag. Especially, as permeability is above $10^{-3}$cm/sec, this material proved to have functions of both reinforced roadbed and drainage layer.