• Bulletin of the Korean Chemical Society
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• v.28 no.3
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• pp.417-420
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• 2007

Mononuclear mixed-anions Mn complex of TPAMn(η2-NO3)(η-ClO4), where TPA is tris(2-pyridylmethyl)-amine, has been synthesized and characterized. The neutral TPAMn(η2-NO3)(η-ClO4) was obtained from the reaction between Mn(NO3)2·4H2O and [H3TPA](ClO4)3 in MeOH. X-ray crystallographic structure of mononuclear TPAMn(η2-NO3)(η-ClO4) complex showed a seven-coordinated geometry with a tripodal tetradentate TPA, a terminal perchlorate and an η2-bound nitrate.

• The Korean Journal of Applied Statistics
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• v.22 no.1
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• pp.181-188
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• 2009

This paper discusses the covariance structures of data collected from an experiment with a nested design structure, where a smaller experimental unit is nested within a larger one. Due to the nonrandomization of repeated measures factors to the nested experimental units, compound symmetry covariance structure is assumed for the analysis of data. Treatments are given as the combinations of the levels of random factors and fixed factors. So, a mixed-effects model is suggested under compound symmetry structure. An example is presented to illustrate the nesting in the experimental units and to show how to get the parameter estimates in the fitted model.

• The Korean Journal of Applied Statistics
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• v.17 no.1
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• pp.145-151
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• 2004

PROC MIXED fits a variety of mixed models to data and enables one to use these fitted models to make statistical inferences about the data. However, the simulation study in this article shows that PROC MIXED using REML estimators provides one with a confidence interval, that does not keep the stated confidence coefficients, on sums of two variance components in the simple regression model with unbalanced nested error structure which is a mixed model.

• Steel and Composite Structures
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• v.19 no.6
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• pp.1449-1466
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• 2015

Mixed structures consist of two parts: a lower part and an upper part. The lower part is usually made of concrete while the upper part is made of steel. Analyzing these structures is complicated and code-based design of them has many associated problems. In this research, the seismic behavior of mixed structures which have reinforced concrete frames and shear walls in their lower storeys and steel frames with bracing in their upper storeys were studied. For this purpose, seventeen structures in three groups of 5, 9 and 15 storey structures with different numbers of concrete and steel storeys were designed. Static pushover analysis, linear dynamic analysis and incremental dynamic analysis (IDA) using 15 earthquake records were performed by OpenSees software. Seismic parameters such as period, response modification factor and ductility factor were then obtained for the mixed (hybrid) structures using more than 4600 nonlinear dynamic analysis and used in the regression analysis for achieving proper formula. Finally, some formulas, effective in designing such structures, are presented for the mentioned parameters. According to the results obtained from this research, the response modification factor values of mixed structures are lower compared to those of steel or concrete ones with the same heights. This fact might be due to the irregularities of stiffness, mass, etc., at different heights of the structure. It should be mentioned that for the first time, the performance and seismic response of such structures were studied against real earthquake accelerations using nonlinear dynamic analysis, andresponse modification factor was obtained by IDA.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.21 no.6
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• pp.571-578
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• 2008

Ubiquitous has spotlighted in the industry in these days, and automotive industry has tried to build ubiquitous environment like as 'intelligent driver assistance system' in BMW Inc. even though in shipbuilding industry. As the part of Ubiquitous Technology for visualization, Mixed Reality has been adopted in this paper. Augmented reality, a part of mixed reality, could show the mixed real world, overlapping virtual objects. Therefore, it is more realistic than virtual reality that all generated by computer and it is very useful for displaying information. For this reason, we tried to apply augmented reality to inspect marine structure and we developed the inspection assistance system based on mixed reality

• Proceedings of the Korean Statistical Society Conference
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• 2002.11a
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• pp.141-146
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• 2002

In this article we consider the problem of constructing confidence intervals for a linear regression model with nested error structure. A popular approach is the likelihood-based method employed by PROC MIXED of SAS. In this paper, we examine the ability of MIXED to produce confidence intervals that maintain the stated confidence coefficient. Our results suggest the intervals for the regression coefficients work well, but the intervals for the variance component associated with the primary level cannot be recommended. Accordingly, we propose alternative methods for constructing confidence intervals on the primary level variance component. Computer simulation is used to compare the proposed methods. A numerical example and SAS code are provided to demonstrate the methods.

• Proceedings of the Korean Geotechical Society Conference
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• 2005.03a
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• pp.1390-1395
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• 2005

To analyze the effects of oyster shell particles, inserted in the self-hardening matrix such as cement paste, on strength, homogenization analysis using micro structure was used to estimate and assess the apparent elastic modulus of oyster shell particle. DIB modeling technique was used to represent of the micro structure of oyster shell mixed concrete. The results showed that the apparent elastic modulus of LOS (large oyster shell particle) was changed with the amount of LOS inserted. In particular, when the amount of LOS was 200% of the weight of cement, the apparent elastic modulus of LOS tended to decrease rapidly. This could mean that the strength of oyster shell mixed concrete is much affected by LOS inserted material in mixed ratio of 200%.

• Water Engineering Research
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• v.3 no.3
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• pp.155-162
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• 2002

This study presents the theoretical approach for volume concentration, velocity profile, and granular discharge on the fluid-granule mixed flow downstream of the scour hole at the outlet of the hydraulic structure. Concept of dilatant model was applied for the stress-strain relationships of fluid-granule mixed flow since the flow downstream of the scour hole corresponds to debris flow, where momentum transfers through particle collisions. Mathematical formulations were derived using momentum equation and stress-strain relation of the fluid-granule mixture. Velocity profile under the assumption of uniform concentration over flowing layer showed the downward convex type. Deposition angle of downstream hump was found to be a function of an upstream slope angle, a dynamic friction angle and a volume concentration irrespective of flow itself, Granular discharge and the overflow depth were obtained with given values of inflow rates. Experimental results showed relatively good agreements with theoretical ones.

• Proceedings of the Korean Geotechical Society Conference
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• 2001.11a
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• pp.72-84
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• 2001

In order to utilize mass of oyster shells for a partial substitute material for reclamation, we investigate the shear characteristics of dredged sluge mixed with oyster shells. the apparent modulus of elasticity of the this mixture are obtained from the triaxial compression tests and is utilized to characterize the apparent modulus of elastic of the oyster shells by carrying out some numerical analysis based upon the homogenization theory. We got the conclusion by a series of experiment, 1) It is verified that modulus of elasticity of dredged clay is improved by mixing with oyster shells. 2) The homogenization method for deducing apparent modulus of elasticity of oyster shells, which can consider micro-structure of mixed soil, is introduced. The elastic modulus is affected from the skeleton structure of oyster shell. The effect of 49kPa is bigger than that of 98kPa.

• Bulletin of the Korean Chemical Society
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• v.23 no.4
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• pp.613-616
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• 2002