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http://dx.doi.org/10.5012/bkcs.2007.28.3.417

Structure of Mixed-Anions Tris(2-pyridylmethyl)amine Mn Complex, TPAMnη2-NO3)(η-CIO4)  

Shin, Bok-Kyu (Metalloenzyme Research Group, BET Research Institute and Department of Biotechnology, Chung-Ang University)
Kim, Mi-Hyang (Metalloenzyme Research Group, BET Research Institute and Department of Biotechnology, Chung-Ang University)
Han, Jae-Hong (Metalloenzyme Research Group, BET Research Institute and Department of Biotechnology, Chung-Ang University)
Publication Information
Bulletin of the Korean Chemical Society / v.28, no.3, 2007 , pp. 417-420 More about this Journal
Abstract
Mononuclear mixed-anions Mn complex of TPAMn(η2-NO3)(η-ClO4), where TPA is tris(2-pyridylmethyl)-amine, has been synthesized and characterized. The neutral TPAMn(η2-NO3)(η-ClO4) was obtained from the reaction between Mn(NO3)2·4H2O and [H3TPA](ClO4)3 in MeOH. X-ray crystallographic structure of mononuclear TPAMn(η2-NO3)(η-ClO4) complex showed a seven-coordinated geometry with a tripodal tetradentate TPA, a terminal perchlorate and an η2-bound nitrate.
Keywords
Mixed-anions; Seven-coordinated manganese complex; Tripodal ligand; Crystal structure; Nitrate binding;
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