• 제목/요약/키워드: mixed salts

검색결과 113건 처리시간 0.035초

EFFECTS OF CALCIUM SALTS OF LONG-CHAIN FATTY ACIDS ON RUMINAL DIGESTIBILITY, MICROBIAL PROTEIN YIELD AND LACTATION PERFORMANCE

  • Maeng, W.J.;Lim, J.H.;Lee, S.R.
    • Asian-Australasian Journal of Animal Sciences
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    • 제6권3호
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    • pp.395-400
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    • 1993
  • Four sheep per treatment were fed either control or 3% calcium salts of long-chain fatty acids (Ca-LCFA) in a total mixed ration (TMR). Feed and free water intakes were not different, but digestibilities of crude protein and crude fiber were lower (p<0.05) and that of crude fat was higher (p<0.05) for sheep fed Ca-LCFA than for control sheep. Dry matter digestibility, ruminal pH and microbial protein yield were not different between treatments and ammonia-N concentration in the rumen was higher for sheep fed Ca-LCFA than for control sheep. A 60-day milk production trial was conducted with thirty lactation Holstein cows. Fifteen cows per treatment were fed TMR containing either control or 3% Ca-LCFA ad libitum. Feed intake was not different between treatments, but milk yield was significantly higher (p<0.05) for cows fed Ca-LCFA than for control cows. Milk fat percentage was slightly higher and milk protein was lower for cows fed Ca-LCFA than for control cows. Lactose and total solid contents in milk were not different between treatments.

탄산칼슘 생성 균주의 분리 및 다양한 칼슘원에 따른 토양 고결화 (Isolation of Calcite Forming Bacteria and Soil Bio-consolidation with Various Calcium Salts)

  • 구탁용;강창호;신유진;소재성
    • KSBB Journal
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    • 제32권3호
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    • pp.206-211
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    • 2017
  • The physical method used to prevent a landslide has the risk of environmental pollution. Calcite forming bacteria (CFB) have been received increasing attention as a novel and environmental friendly strategy for the soil improvement. In this study, we selected 11 CFB strains with high calcite production. We also examined survivability and calcite productivity of the strains under various stress conditions to select strains with high resistance to various stresses. Two strains was selected by environment stress. Sphingobacterium sp. KJ-32 and Viridibacillus arenosi B-25 precipitate calcite more than other strains at pH 5 and $15^{\circ}C$ respectively. Bio-consolidated soil cakes were made using various calcium salts (calcium chloride, calcium acetate, calcium lactate, calcium gluconate) with mixed culture of 2 strains. Among them, the calcite made using calcium chloride was the largest. These observations demonstrate that this bio-consolidation technology has the potential for eco-friendly prevention of landslide and soil improvement.

Dehydration and pore swelling effects on the transfer of PEG through NF membranes

  • Escoda, Aurelie;Bouranene, Saliha;Fievet, Patrick;Deon, Sebastien;Szymczyk, Anthony
    • Membrane and Water Treatment
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    • 제4권2호
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    • pp.127-142
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    • 2013
  • In order to investigate the significance of "salting-out" and "pore swelling" effects on the nanofiltration of neutral solutes, rejection properties of two NF ceramic and polymeric membranes were studied with single polyethyleneglycol (PEG) solution and mixed PEG/inorganic electrolyte solutions. For both membranes, the rejection rate of PEG was found to decrease significantly in the presence of ions. In the case of the ceramic membrane (rigid pores), this phenomenon was imputed to the sole partial dehydration of PEG molecules induced by the surrounding ions. This assumption was confirmed by the lowering of the PEG rejection rates which followed the Hofmeister series. Experimental data were used to compute the resulting decrease in the Stokes radius of PEG molecules in the presence of the various salts. Concerning the polymeric membrane, the decrease in the rejection rate was found to be systematically higher than for the ceramic membrane. The additional decrease was then ascribed to the swelling of the pores. The experimental data of rejection rates were then used to compute the variation in the mean pore radius in the presence of the various salts. The pore swelling phenomenon due to accumulation of counterions inside pores was supported by electrokinetic charge density measurements.

Electrochemical Properties of Binary Electrolytes for Lithium-sulfur Batteries

  • Kim, Hyung-Sun;Jeong, Chang-Sik
    • Bulletin of the Korean Chemical Society
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    • 제32권10호
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    • pp.3682-3686
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    • 2011
  • The electrochemical properties of lithium-sulfur batteries with binary electrolytes based on DME and DOL, TEGDME and DOL mixed solvent containing $LiClO_4$, LiTFSI, and LiTF salts were investigated. The ionic conductivity of 1M LiTFSI and $LiClO_4$ electrolytes based on TEGDME and DOL increased as the volume ratio of DOL solvent increased, because DOL effectively reduces the viscosity of the above electrolytes medium under the same salts concentration. The first discharge capacity of lithium-sulfur batteries in the DME and DOL-based electrolyte followed this order: LiTFSI (1,000 mAh/g) > LiTF (850 mAh/g) > $LiClO_4$ (750 mAh/g). In case of the electrolyte based on TEGDME and DOL, the first discharge capacity of batteries followed this order: $LiClO_4$ (1,030 mAh/g) > LiTF (770 mAh/g) > LiTFSI (750 mAh/g). The cyclic efficiency of lithium-sulfur batteries at 1M $LiClO_4$ electrolytes is higher than that of batteries at other lithium salts-based electrolytes. Lithium-sulfur battery showed discharge capacity of 550 mAh/g until 20 cycles at all electrolytes based on DME and DOL solvent. By contrast, the discharge capacity of batteries was about 450 mAh/g at 1M LiTFSI and LiTF electrolytes based on TEGDME and DOL solvent after 20 cycles.

Turbidimetric and Nephelometric Studies on Aggrregation of Cationic-Anionic Surfactants$^\dag$

  • Park, Joon-Woo;Chung, Myung-Ae;Ahn, Byung-Tae;Lee, Hoo-Sung
    • Bulletin of the Korean Chemical Society
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    • 제8권6호
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    • pp.462-465
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    • 1987
  • The aggregation between cationic and anionic surfactants was studied by turbidimetric and nephelometric methods with emphasis on facile analysis of the surfactants and understanding of the mixed micellization. The turbidimetric titration of sodium dodecylsulfate (SDS) with cetyltrimethylammonium bromide (CTAB) or cetylpyridinium bromide (CPB) showed maximum turbidity at equimolar composition in the SDS concentration range of 0.1-0.9 mM. The nephelometric titration of the same systems extended the limit of analysis to 0.001 mM. The sodium salts of decylsulfate and sulfonate gave similar maxima, but not at equimolar composition. The coexistence of equimolar aggregates and mixed micelles were shown over broad composition range. The aggregation and mixed micellization of the anionic/cationic surfactants mixtures depended sensitively on the hydrophobic character of the surfactants.

혼합 실크 피브로인막의 투명도 (Transparency of various silk fibroin membranes)

  • 조유영;권해용;여주홍;이광길
    • 한국잠사곤충학회지
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    • 제51권2호
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    • pp.197-200
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    • 2013
  • 실크는 천연고분자 단백질로 생체친화적이며, 최근 조직공학 연구가 활성화 되면서 각광받는 생체재료이다. 하지만 실크 단독으로 실크막을 제작하였을 때, 얇은 막은 투명도가 있지만 두께가 두꺼워지게 되면 실크막은 매우 불투명한 막으로 바뀌게 된다. 인체조직에서 사용되는 막중 각막이나 뇌경막 등 투명도가 반드시 필요한 생체막에 실크막을 이용하기 위해서는 실크막의 투명도가 반드시 요구된다. 따라서, 본 연구에서는 실크 피브로인 수용액에 다양한 무기염류와 고분자물질을 혼합하여 혼합 실크막을 제작하고 그 투명도를 분석하였다. 제작된 혼합 실크막은 혼합된 물질에 따라 투명도가 매우 달랐다. 무기 염류가 혼합된 실크막의 경우 고분자물질과 혼합된 실크막에 비해 더 투명도가 높았으며, 특히 염화칼슘이 혼합된 실크막의 투명도는 매우 투명하였다. 따라서, 각막 등 완벽한 투명도를 요구하는 생체막으로 실크막을 사용할 수 있는 가능성을 확인할 수 있었다. 향후 혼합 실크막의 물리적 특성 규명을 통해 좀 더 물성이 개선된다면, 투명한 실크막이 다양한 용도로 이용될 수 있을 것으로 기대된다.

N-Dodecanoyl, N-Methyl Glucamine(GL 12)과 음이온 계면활성제 혼합물의 Dynamic Surface Tension에 관한 연구 (Studies on the Dynamic Surface Tension of GL12 and Anionic Mixtures)

  • 안호정;최규석
    • 공업화학
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    • 제7권1호
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    • pp.101-108
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    • 1996
  • 본 연구에서는 수용액 내에서 생분해도가 우수하고 인체에 mild한 비이온성 계면활성제 GL12와 범용 음이온성 계면활성제인 linear laurylbenzene sulfonate(LAS) 또는 sodium polyoxyethylene(3) glycol lauryl ether sulfate(SLES) 각각 용액의 dynamic surface tension과 이들 계면활성제 혼합용액의 dynamic surface tension이 혼합비에 따라 어떻게 변화되는지 maximum bubble pressure method를 이용하여 조사하였다. 또한 salting-cut 효과가 있는 NaCl, CsCl과 salting-in 효과가 있는 요소를 계면활성제 용액에 첨가하여 이들 염들이 용액의 dynamic surface tension에 미치는 영향에 대하여도 연구하였다. 비이온성 계면활성제인 GL12의 dynamic surface tension은 염의 존재에 영향을 크게 받지 않았으나 음이온성인 SLES와 LAS는 크게 영향을 받았다. 또한 GL12/SLES와 GL12/LAS 혼합계에서도 GL12의 함량이 많을수륵 용액의 dynamic surface tension에 대한 염의 영향이 감소하였으나 LAS 또는 SLES의 함량이 증가할수록 염의 영향은 증가하였다.

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분말성제제(粉末性製劑)의 안정성(安定性)에 관(關)한 연구(硏究) -제제중(製劑中)의 Ascorbic Acid의 분해(分解)에 미치는 Talc의 영향(影響)- (Study on the Effect of Talc on the Degredation of Ascorbic Acid in its Diluted Preparation)

  • 정기화;이민화;우종학;김신근
    • Journal of Pharmaceutical Investigation
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    • 제2권1호
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    • pp.52-57
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    • 1972
  • There are many reports on the stability of drugs in powders and various dosage forms. The author studied on the stability of ascorbic acid mixed with talcs. From the result of this experiment, it was considered that talcs markedly accelerated oxidative degredation of ascorbic acid in powders and the acceleration rate depends on the varieties of crude talcs. Iron salts seem to be the principal factor influencing the degradation of ascorbic acid Degradation rate of ascorbic acid mixed with purified talc is significantly slower than that with the crnde talcs. The more the concetration of ascorbic acid is diluted, the faster the degradation rate and degredation rate of Ascorbic acid is the function of tme.

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글리옥살을 이용한 마직물의 무포름알데히드 방추가공(제 1보)-촉매의 영향 (Nonformaldehyde Anti-crease Finish of Ramie with Glyoxal (Part I))

  • 오경화;홍경화
    • 한국의류학회지
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    • 제22권8호
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    • pp.1060-1068
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    • 1998
  • The effects of various catalysts and softners on the anti-crease finish of ramie with glyoxal were investigated. A number of metal salts commonly used as Lewis acid catalysts in DP finishing of cotton with formaldehyde and N-methylol agents were screened for glyoxal treatment of ramie fabric. Various organic and inorganic acids were mixed with Lewis acid catalyst as co-catalysts to improve catalytic activity. As a result, the combination of aluminum sulfate and citric acid was proven highly effective in catalyzing the crosslinking of ramie cellulose by glyoxal under lower curing temperature. With a mixed catalyst, performance properties, such as whiteness and tearing strength as well as wrinkle recovery of treated ramie fabric were improved as compared with that treated with aluminum sulfate alone. Additional improvement of tearing strength and wrinkle recovery was achieved by applying silicons softner in the treatment bath.

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소결법에 의한 다공질 결정화유리의 제조 (Preparation of Porous Glass-Ceramics by the Sintering)

  • 박용완;이준영
    • 한국세라믹학회지
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    • 제31권10호
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    • pp.1218-1230
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    • 1994
  • In manufacturing process of porous glass-ceramics by the filler method, the sintering behaviour of crystallizable glass powder mixed with various salts was studied and also the effects of precipitated crystal phases on the properties of porous glass-ceramics were investigated. Fine-grained crystallizable glass powder was homogeneously mixed with various slat having grain size 100~200 ${\mu}{\textrm}{m}$ and sintered for densification. After washing out the inorganic salt with distilled water, the porous sintered body was heat treated additionly for crystallization. The MgO-Al2O3-SiO2 base glass was used as crystallizable glass powder and the water soluble salts such as K2SO4 and MgSO4 were used as filler. When K2SO4 was used, leucite crystal phase was formed as a result of the ion exchange and porous glass-ceramics which exhibit high temperature resistance and high thermal expansion coefficient of 17$\times$10-6/$^{\circ}C$ could be obtained. On the contrary, when MgSO4 was used, only slight ion exchange is observed and $\mu$-cordierite and $\alpha$-cordierite crystal phases were formed and porous glass-ceramics which exhibit low thermal expansion coefficient schedule were determined with the results of DTA curves, thermal shrinkage curves and XRD patterns analysis. From DTA curves and thermal shrinkage curves, it was found that the sintering densification have been completed at the temperature range of exothermic peak for crystallization. The pore size distributions and pore diameters were measured by mercury porosimeter. The pore diameter of porous glass-ceramics was 10~15 ${\mu}{\textrm}{m}$ when 100~200${\mu}{\textrm}{m}$ grain size of K2SO4 was used and it was 25~30 ${\mu}{\textrm}{m}$ when the same grain size of MgSO4 was used. The porous glass-ceramics K2SO4 used shows bimodal pore size distribution and its porous skeleton structure was ascertained by SEM observation.

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