• 제목/요약/키워드: mixed potential

검색결과 992건 처리시간 0.032초

보리와 독새풀의 생장에 대한 삼투압, pH 및 볏짚멀칭의 영향 (Influence of Light, Osmotic Potential, pH and Rice Straw Mulching on Growth of Barley(Hordeum vulgare L.) and Water Foxtail(Alopecurus aequalis var. amurensis(Kom.) Ohwi))

  • 이춘우;김용욱;구본철
    • 한국잡초학회지
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    • 제17권3호
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    • pp.310-313
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    • 1997
  • 볏짚을 논에 환원하면 잡초의 발생이 억제되는 경향이 있다. 이는 볏짚의 멀칭효과에 의한 차광, 수분증가 또는 용탈물 등의 영향일수도 있다. 따라서 본 시험은 실내에서 pH, 수분포텐셜, 볏짚분말의 혼합정도 등에 따라 보리와 독새풀의 발아와 생육에 미치는 영향을 구명하고, 포장에서 볏짚멀칭이 잡초발생에 미치는 영향을 조사한 결과를 요약하면 아래와 같다. 1. pH 4-10의 범위에서 보리와 독새풀의 생장과 발아는 영향을 받지 않았다. 2. 삼투압이 각각 -2.9bar, -0.6bar 이상에서 보리와 독새풀의 발아에 영향을 미쳤다. 3. 볏짚분말의 혼합농도가 4% 이상에서 보리의 지상부와 지하부의 무게는 감소하였고 지상부보다 지하부의 생장억제가 심하였다. 4. 볏짚멀칭에 의하여 광이 99.8% 차광되었고 독새풀의 발생본수와 건물중이 각각 87.1%, 86.2% 억제되었다.

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Study of the Librational Motion of $H_2$O Molecules in Hydrates by Neutron Inelastic Scattering

  • Kim, Huhn-Jun;Yoon, Byung-Gook
    • Nuclear Engineering and Technology
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    • 제11권1호
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    • pp.1-20
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    • 1979
  • 수화물 결정에 있어서 $H_2O$ 분자의 외부 각 운동을 조사하고저 NaBr-2$H_2O$ 및 BaCl$_2$-2$H_2O$ 분말시료에 대한 중성자비탄성산란실험을 수행하였으며, 관측된 진동수를 모두 이 외부 각 운동에 의한 것으로 보고 다중 및 다준위산란효과를 제거하므로서 평균진동수 분포함수를 구하였다. FG 행열법에 의해서 계산된 진동수의 이론 값들은 모두 복합 mode에 의한 것이였으며 따라서 그 중 포텔샬.에너지분포가 큰 mode로서 관측치에 대한 assignment를 하였다. 소수결합력은 Lippincott-Schroeder 포텐샬함수에서 추산하였으며, 절선형 및 분기형수소결합에 대한 이 함수의 유용성을 $H_2O$ 외부 각 운동 포텐샬함수 모양에 의거하여 검토하였다. 수소결합력의 성질에 대하여 더욱 자세한 자료를 얻기 위해서는 진동수 계산에 H…Y 신축상호작용 운만 아니라 O-H…Y 변각상호작용의 도입이 필요함을 논의하였고 또 $H_2O$ 외부 각 운동에 인어서 mode의 순수성 및 대칭성을 군론을 작용한 방법에 의거하여 논의하였다.

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Influence of EDZ on the Safety of a Potential HLW Repository

  • 황용수;강철형
    • 방사성폐기물학회지
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    • 제2권4호
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    • pp.253-262
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    • 2004
  • Construction of tunnels in a deep crystalline host rock for a potential High-Level Radioactive Waste(HLW) repository inevitably generates an excavation disturbed zone (EDZ). There have been a series of debates on whether a permeability in an EDZ increases or not and what would be the maximum depth of an EDZ. Recent studies show mixed opinions on permeability. However, there has been an international consensus on the thickness of an EDZ; 30 cm for TBM and 1 meter for controlled blast. One of the impacts of an EDZ is on determining the distance between adjacent deposition holes. The void gap by the excavation hinders relaxation of temperature profiles so that the current Korean reference designing distance between holes should be stretched out more to keep the maximum temperature in a buffer region below 100 degrees Celsius. The other impact of an EDZ is on the long-term post closure radiological safety. To estimate the impact, the reference scenario, the well scenario, is chosen. Released nuclides diffuse through a bentonite buffer region experiencing strong sorption and reach a fracture surrounded by a porous medium. Inside a fractured porous region, radionuclides migrate by advection and dispersion with matrix diffusion into a porous medium. Finally, they reach a well assumed to be a source of potable water for local residents. The annual individual dose is assessed on this well scenario to find out the significance of an EDZ. A profound sensitivity study was performed, but all results show that the impact is negligible. Even though the role of an EDZ turns out to be limited on overall safety assessment, still it is worthwhile to study the chemical role of an EDZ, such as a potential source for natural colloids, potential sealing of an open fracture by fine clay particles generated by the process of an EDZ, and alteration of a sorption mechanism by an EDZ in the future.

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Biocompatibility and bioactive potential of the NeoMTA Plus endodontic bioceramic-based sealer

  • Roberto Alameda Hoshino;Mateus Machado Delfino;Guilherme Ferreira da Silva;Juliane Maria Guerreiro-Tanomaru;Mario Tanomaru-Filho;Estela Sasso-Cerri;Paulo Sergio Cerri
    • Restorative Dentistry and Endodontics
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    • 제46권1호
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    • pp.4.1-4.16
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    • 2021
  • Objectives: This study evaluated the biocompatibility and bioactive potential of NeoMTA Plus mixed as a root canal sealer in comparison with MTA Fillapex. Materials and Methods: Polyethylene tubes filled with NeoMTA Plus (n = 20), MTA Fillapex (n = 20), or nothing (control group, CG; n = 20) were inserted into the connective tissue in the dorsal subcutaneous layer of rats. After 7, 15, 30 and 60 days, the specimens were processed for paraffin embedding. The capsule thickness, collagen content, and number of inflammatory cells (ICs) and interleukin-6 (IL-6) immunolabeled cells were measured. von Kossa-positive structures were evaluated and unstained sections were analyzed under polarized light. Two-way analysis of variance was performed, followed by the post hoc Tukey test (p ≤ 0.05). Results: At 7 days, the capsules around NeoMTA Plus and MTA Fillapex had more ICs and IL-6-immunostained cells than the CG. However, at 60 days, there was no significant difference in the IC number between NeoMTA Plus and the CG (p = 0.1137) or the MTA Fillapex group (p = 0.4062), although a greater number of IL-6-immunostained cells was observed in the MTA Fillapex group (p = 0.0353). From 7 to 60 days, the capsule thickness of the NeoMTA Plus and MTA Fillapex specimens significantly decreased, concomitantly with an increase in the collagen content. The capsules around root canal sealers showed positivity to the von Kossa stain and birefringent structures. Conclusions: The NeoMTA Plus root canal sealer is biocompatible and exhibits bioactive potential.

Evaluating fermentation quality, in vitro digestibility and aerobic stability of a total mixed ration ensiled with different additives on Tibet plateau

  • Dong, Zhihao;Wang, Siran;Zhao, Jie;Li, Junfeng;Liu, Qinhua;Bao, Yuhong;Shao, Tao
    • Animal Bioscience
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    • 제34권2호
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    • pp.223-232
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    • 2021
  • Objective: To investigate the improvement in utilization efficiency of total mixed ration (TMR) on Tibetan plateau, TMR were ensiled with different additives. Methods: A total of 150 experimental silos were prepared in a completely randomized design to evaluate the six treatments: i) control (without additive), ii) Lactobacillus buchneri (L. buchneri), iii) acetic acid, iv) propionic acid, v) 1,2-propanediol; and vi) 1-propanol. After 90 days of ensiling, silos were opened for fermentation quality and in vitro analysis, and then subjected to an aerobic stability test for 14 days. Results: Treating with L. buchneri, acetic acid, 1,2-propanediol and 1-propanol decreased propionic acid contents and yeast number, whereas increased (p<0.05) pH, acetic acid and ethanol contents in the fermented TMR. Despite increased dry matter (DM) loss in the TMRs treated with 1,2-propanediol and 1-pronanol, additives did not affect (p>0.05) all in vitro parameters including gas production at 24 h (GP24), GP rate constant, potential GP, in vitro DM digestibility and in vitro neutral detergent fibre digestibility. All additives improved the aerobic stability of ensiled TMR to different extents. Specially, aerobic stability of the ensiled TMR were substantially improved by L. buchneri, acetic acid, 1,2-propanediol, and 1-propanol, indicated by stable pH and lactic acid content during the aerobic stability test. Conclusion: L. buchneri, acetic acid, 1,2-propanediol, and 1-propanol had no adverse effect on in vitro digestibility, while ensiling TMR with the additives produced more acetic acid and ethanol, subsequently resulting in improvement of aerobic stability. There is a potential for some fermentation boosting additives to enhance aerobic stability of fermented TMR on Tibetan plateau.

Effects of Varying Levels of Fungal (Arachniotus sp.) Treated Wheat Straw as an Ingredient of Total Mixed Ration on Growth Performance and Nutrient Digestibility in Nili Ravi Buffalo Calves

  • Shahzad, F.;Abdullah, M.;Chaudhry, A.S.;Bhatti, J.A.;Jabbar, M.A.;Ahmed, F.;Mehmood, T.;Asim, M.;Ahmed, S.;Kamran, Z.;Irshad, I.;Tahir, M.N.
    • Asian-Australasian Journal of Animal Sciences
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    • 제29권3호
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    • pp.359-364
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    • 2016
  • The study was carried out to explore the effects of replacing wheat straw with fungal treated wheat straw as an ingredient of total mixed ration (TMR) on the growth performance and nutrient digestibility in Nili Ravi buffalo male calves. Fungal treated wheat straw was prepared using Arachniotus sp. Four TMRs were formulated where wheat straw was replaced with 0 (TMR1), 33 (TMR2), 67 (TMR3), and 100% (TMR4) fungal treated wheat straw in TMR. All TMRs were iso-caloric and iso-nitrogenous. The experimental TMRs were randomly assigned to four groups of male calves (n = 6) according to completely randomized design and the experiment continued for four months. The calves fed TMR2 exhibited a significant improve in dry matter intake, average daily weight gain, feed conversion ratio and feed economics compared to other groups. The same group also showed higher digestibility of dry matter, crude protein, neutral-, and acid detergent fibers than those fed on other TMRs. It is concluded that TMR with 33% fungal-treated wheat straw replacement has a potential to give an enhanced growth performance and nutrient digestibility in male Nili Ravi buffalo calves.

Water activation에 기반한 셀룰로오스의 개질 및 특성 (The Effect of Water Activation on Chemical Modification of Cellulose and Characterization)

  • 김해리;남병욱
    • 한국산학기술학회논문지
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    • 제14권2호
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    • pp.977-982
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    • 2013
  • 다양한 종류의 지방산 아실 체인으로 치환된 Cellulose mixed esters(CME)는 재생 가능한 bio-based 폴리머이다. 셀룰로오스 에스터는 생분해성 고분자로써, 분해되지 않는 석유계 플라스틱을 대체할 미래 고분자 소재이다. 본 연구에서는 개질 실험에 앞서 alpha 셀룰로오스를 $40^{\circ}C$의 증류수에 2시간동안 activation하였다. Water-activated 셀룰로오스와, 다양한 불포화 지방산, 무수 아세트산을 $120^{\circ}C$의 lithium chloride/N,N-dimethylacetamide (LiCl/DMAc)용매에서 5시간동안 반응시켜 CME를 합성했다. 세척과 감압을 반복한 후, TGA, FT-IR, 1H-NMR과 FE-SEM를 통해 특성을 관찰하였고, water activation이 셀룰로오스의 수산기 치환에 미치는 영향에 대하여 조사하였다.

침지형 분리막을 사용한 오수처리

  • 최광호
    • 한국막학회:학술대회논문집
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    • 한국막학회 1998년도 제6회 하계 Workshop (98 한국막학회, 국립환경연구원 국제 Workshop, 수자원 보전과 막분리 공정)
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    • pp.113-133
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    • 1998
  • In activated sludge process, sludge settling condition is affected by organic loading rate or operation condition, and if settling condition is getting worse, it is common that overall process fails due to wash-out of biomass causing low concentration in the aeration tank. Also activated sludge process has such several problems as requiring large area, consuming a lot of power and producing large volume of sludge. Increased public concern over health and the environment combined with a strong desire to reduce capital, operating and maintenance costs, have created a need for innovative technologies for building new high quality effluents which vail meet 21st century crkeria. MBR(Membrane Bioreactor) process consists of a biological reactor and ultrafiltration(UF) membrane system that replaces the conventional clarifier of an activated sludge process. The main operating advantages of this system are that the quality of the effluent is independent of the settleability of the mixed liquor and that the effluent is free of suspended solids in any operating condition. It is possible to eliminate clarifier and to reduce the volume of aeration tank because it can afford to accumulate high biomass concentration in the bioreactor(20, 000~30, 000mg/L), which would not be possible in a conventional activated sludge process. Therefore, this process reduces overall treatment plant area. In addition to those advantages, Longer SRT condition enables higher sludge digestion in MBR process so the sludge volume produced is 50 to 70% lower than that of conventional activated sludge process There are two kinds of MBR process according to the allocations of membrane. One is cross flow type MBR of which module is located outside of the bioreactor and mixed liquor is driven into the membrane module. The other is submerged type MBR process of which module is submerged in the bioreactor and mixed liquor is generally sucked from the lumen side. addition to that the cake layer is often removed by the uplifting flow of bubbling air. A submerged MBR process is superior to a crossflow MBR in regard to the power consumption because suction pressure of a submerged MBR is generally lower than that of a crossflow MBR which has recirculation pump. A submerged MBR, therefore, has the potential to be applied to small wastewater treatment plants that need low cost treatment systems.

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Carbamate-Based Surface Reactions for Release of Amine Molecules from Electroactive Self-Assembled Monolayers

  • Hong, Dae-Wha;Kang, Kyung-Tae;Hong, Seok-Pyo;Shon, Hyun-Kyong;Lee, Tae-Geol;Choi, In-Sung S.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.208-209
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    • 2011
  • In this work, we developed self-assembled monolayers (SAMs) of alkanethiols on gold that can release amine groups, when an electrical potential was applied to the gold. The strategy was based on the introduction of the electroactive carbamate group, which underwent the two-electron oxidation with simultaneous release of the amine molecules, to alkanethiols. The synthesis of the designed thiol compounds was achieved by coupling isocyanate-containing compound with hydroquinone. The electroactive thiols were mixed with hydroxyl-containing alkanethiol [$HS(CH_2)_{11}OH$] to form mixed monolayers, and cyclic votammetry was used for the characterization of the release. The mixed SAMs showed a first oxidation peak at +540 mV (versus Ag/AgCl reference electrode), demonstrating irreversible conversion from carbamate to hydroqinone with simultaneous release of the amine groups. The second and third cycles showed typical reversible redox reaction of hydroquinone and quione: the oxidation and reduction occurred at +290 mV and -110 mV, respectively. The measurement of ToF-SIMS further indicates that electrochemical-assisted chemical reaction successfully released amine groups. This new SAM-based electrochemistry would be applicable for direct release of biologically active molecules that contain amine groups.

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Corrosion Behavior of Inconel X-750 for Carbon Anode Oxide Reduction Application

  • Jeon, Min Ku;Kim, Sung-Wook;Lee, Sang-Kwon;Choi, Eun-Young
    • 방사성폐기물학회지
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    • 제18권3호
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    • pp.355-362
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    • 2020
  • The corrosion behavior of the Inconel X-750 alloy was investigated for its potential application under a Cl2-O2 mixed gas flow in an Ar atmosphere. The corrosion rate was found to be negligible at temperatures up to 400℃ under a flow rate of 30 mL·min-1 Cl2 + 170 mL·min-1 Ar, whereas an exponential increase was observed in the corrosion rate at temperatures greater than 500℃. The suppression of the corrosion reaction due to the presence of O2 was verified experimentally at flow rates of 30 mL·min-1 Cl2 (4.96 g·m-2·h-1), 20 mL·min-1 Cl2 + 10 mL·min-1 O2 (2.02 g·m-2 ·h-1), and 10 mL·min-1 Cl2 + 20 mL·min-1 O2 (1.34 g·m-2·h-1) under a constant Ar flow rate of 170 mL·min-1 at 600℃ for 8 h. The surface morphology analysis results revealed that porous surfaces with tunnel-type holes were produced under the Cl2-O2 mixed-gas condition. Furthermore, the effects of the Cl2 flow rate on the corrosion rate were investigated, indicating that its impact was negligible within the range of 5-30 mL·min-1 Cl2 at 600℃.