• Title/Summary/Keyword: mixed potential

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Assessment of Nitrogen Fate in the Soil by Different Application Methods of Digestate (혐기성 소화액의 농지환원에 따른 질소 거동)

  • Nkombo, Laure Lysette Chimi;Hong, Seong Gu
    • Journal of The Korean Society of Agricultural Engineers
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    • v.63 no.3
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    • pp.35-45
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    • 2021
  • Digestate or slurry produced from anaerobic digestion is mostly applied to crop lands for its disposal and recovering nutrients. However, minimizing nitrogen losses following field application of the digestate is important for maximizing the plant's nitrogen uptake and reducing environmental concerns. This study was conducted to assess the effects of three different biogas digestate application techniques (sawdust mixed with digestate (SSD), the hole application method (HA), and digestate injected in the soil (SD)) on nitrate leaching potential in the soil. A pot laboratory experiment was conducted at room temperature of 25 ± 2 ℃ for 107 days. The experimental results showed that sawdust application method turned out to be appropriate for quick immobilization of surplus N in the form of microbial biomass N, reflecting its lower total nitrogen and NH4-N contents and low pH. The NH4-N and total nitrogen fate in the soil fertilized with manure showed no statistically significant (p > 0.05) differences between the different methods applied during the incubation time under room temperature. In contrast, NO3-N concentration indicates significant reduction in sawdust treatment (p < 0.05) compared to the control and other application methods. However, the soil sawdust mixed with digestate was more effective than the other methods, because of the cumulative labile carbon contents of the amendment, which implies soil net N immobilization.

Purification of Biohydrogen Produced From Palm Oil Mill Effluent Fermentation for Fuel Cell Application

  • Rohani, Rosiah;Chung, Ying Tao;Mohamad, Izzati Nadia
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.469-474
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    • 2019
  • Fermentation of palm oil mill effluent (POME) produces biohydrogen in a mixture at a specific set condition. This research was conducted to purify the produced mixed biohydrogen via absorption and membrane techniques. Three different solvents, methyl ethanolamine (MEA), ammonia ($NH_3$) and potassium hydroxide (KOH) solutions, were used in absorption technique. The highest $H_2$ purity was found using 1M MEA solution with 5.0 ml/s feed mixed gas flow rate at 60 minutes absorption time. Meanwhile, the purified biohydrogen using a polysulfone membrane had the highest $H_2$ purity at 2~3 bar operating pressure. Upon testing with proton exchange membrane fuel cell (PEMFC), the highest current and power produced at 100% $H_2$ were 1.66 A and 8.1 W, while the lowest were produced at 50/50 vol% $H_2/CO_2$ (0.32 A and 0.49 W). These results proved that both purification techniques have significant potential for $H_2$ purification efficiency.

Antioxidant and Antibacterial Effects of Mixed Extracts of Phyllanthus emblica, Geranium (Pelargonium graveolens) and Commiphora myrrha: Possibility of Natural Materials for Acne Treatment

  • Mi Jeong Choi;Yu Ri Kim
    • Microbiology and Biotechnology Letters
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    • v.51 no.2
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    • pp.174-183
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    • 2023
  • Various skin diseases are occurring due to external factors such as urbanization and increase in environmental pollution and wearing masks due to COVID-19. Accordingly, various functional cosmetics are being released, but as some side effects are reported, research on functional cosmetics materials using natural plants is necessary. Therefore, in this study, the antioxidant, antibacterial and anti-inflammatory effects of Phyllanthus emblica, Geranium (Pelargonium graveolens), and Commiphora myrrha mixed extracts (PGC) that pharmacological efficacy has been verified were analyzed and their potential as functional cosmetics raw materials was examined. Four extracts (PGC-1~4) were prepared according to the extraction method. ABTS and DPPH radical scavenging activity experiments were conducted for the antioxidant efficacy of the extracts. In addition, paper disc experiments and LPS inflammation-inducing cytokine experiments were conducted to examine the antibacterial and anti-inflammatory effects. In addition, a cell viability test was performed to confirm cytotoxicity. As results of the study, all extracts showed antioxidant, antibacterial, and anti-inflammatory effects without cytotoxicity, and in particular, PGC-4, a fermentation and ultrasonic extract, showed the best efficacy. This means that the extraction yield of useful components varies depending on the extraction method.

Influence of Light, Osmotic Potential, pH and Rice Straw Mulching on Growth of Barley(Hordeum vulgare L.) and Water Foxtail(Alopecurus aequalis var. amurensis(Kom.) Ohwi) (보리와 독새풀의 생장에 대한 삼투압, pH 및 볏짚멀칭의 영향)

  • Lee, Choon-Woo;Kim, Yong-Wook;Koo, Bon-Cheol
    • Korean Journal of Weed Science
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    • v.17 no.3
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    • pp.310-313
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    • 1997
  • The seedling of barley and weed would be generally inhibited by rice straw residues in the field. This experiment was carried out to investigate the allelopathic effects of rice straw and environmental conditions of germination such as osmotic potential, pH on the seedling of barley and water foxtail. The pH did not affect the germination of barley and water foxtail. Osmotic potential to -2.9bar, -0.6bar did not affect the germination of barley and water foxtail, respectively. Rice straw mixed with soil at the concentration of 4%(w/w) reduced the dry weight of shoot and root, and volume of barley root, as compared to the untreated control. Dry weight of water foxtail by rice straw mulching was decreased by 87.1%, 86.2%, respectively.

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Study of the Librational Motion of $H_2$O Molecules in Hydrates by Neutron Inelastic Scattering

  • Kim, Huhn-Jun;Yoon, Byung-Gook
    • Nuclear Engineering and Technology
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    • v.11 no.1
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    • pp.1-20
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    • 1979
  • Neutron inelastic scattering studies on polycrystalline hydrates, NaBr-2$H_2O$ and BaCl$_2$-2$H_2O$ have been performed to observe librational modes. Assuming all observed peaks are from the $H_2O$ librational origin, the weighted frequency distribution functions are obtained by eliminating the contributions from the higher order processes. All of theoretical frequencies obtained using FG matrix method are dus to highly mixed modes, and therefore the modes identified as significant $H_2O$ librationat modes from their large potential energy distributions are assigned to the observed peaks. The H-bond interactions are estimated using a modified Lippincott Schroeder potential function, and the applicability of the potential function to the H-bond with highly bent or bifurcated configuration is examined on the basis of the shape of $H_2O$ librational potential energies. Some discussions are given on the usefulness of introducing O-H…Y bending terms in addition to the H…Y stretching in similar frequency calculation in order to obtain more information on the nature of H-bond. Also the purity and symmetry properties of the $H_2O$ librational modes are discussed using group theoretical analyses.

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Influence of EDZ on the Safety of a Potential HLW Repository

  • Hwang Yong-Soo;Kang Chul-Hyung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.4
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    • pp.253-262
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    • 2004
  • Construction of tunnels in a deep crystalline host rock for a potential High-Level Radioactive Waste(HLW) repository inevitably generates an excavation disturbed zone (EDZ). There have been a series of debates on whether a permeability in an EDZ increases or not and what would be the maximum depth of an EDZ. Recent studies show mixed opinions on permeability. However, there has been an international consensus on the thickness of an EDZ; 30 cm for TBM and 1 meter for controlled blast. One of the impacts of an EDZ is on determining the distance between adjacent deposition holes. The void gap by the excavation hinders relaxation of temperature profiles so that the current Korean reference designing distance between holes should be stretched out more to keep the maximum temperature in a buffer region below 100 degrees Celsius. The other impact of an EDZ is on the long-term post closure radiological safety. To estimate the impact, the reference scenario, the well scenario, is chosen. Released nuclides diffuse through a bentonite buffer region experiencing strong sorption and reach a fracture surrounded by a porous medium. Inside a fractured porous region, radionuclides migrate by advection and dispersion with matrix diffusion into a porous medium. Finally, they reach a well assumed to be a source of potable water for local residents. The annual individual dose is assessed on this well scenario to find out the significance of an EDZ. A profound sensitivity study was performed, but all results show that the impact is negligible. Even though the role of an EDZ turns out to be limited on overall safety assessment, still it is worthwhile to study the chemical role of an EDZ, such as a potential source for natural colloids, potential sealing of an open fracture by fine clay particles generated by the process of an EDZ, and alteration of a sorption mechanism by an EDZ in the future.

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Biocompatibility and bioactive potential of the NeoMTA Plus endodontic bioceramic-based sealer

  • Roberto Alameda Hoshino;Mateus Machado Delfino;Guilherme Ferreira da Silva;Juliane Maria Guerreiro-Tanomaru;Mario Tanomaru-Filho;Estela Sasso-Cerri;Paulo Sergio Cerri
    • Restorative Dentistry and Endodontics
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    • v.46 no.1
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    • pp.4.1-4.16
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    • 2021
  • Objectives: This study evaluated the biocompatibility and bioactive potential of NeoMTA Plus mixed as a root canal sealer in comparison with MTA Fillapex. Materials and Methods: Polyethylene tubes filled with NeoMTA Plus (n = 20), MTA Fillapex (n = 20), or nothing (control group, CG; n = 20) were inserted into the connective tissue in the dorsal subcutaneous layer of rats. After 7, 15, 30 and 60 days, the specimens were processed for paraffin embedding. The capsule thickness, collagen content, and number of inflammatory cells (ICs) and interleukin-6 (IL-6) immunolabeled cells were measured. von Kossa-positive structures were evaluated and unstained sections were analyzed under polarized light. Two-way analysis of variance was performed, followed by the post hoc Tukey test (p ≤ 0.05). Results: At 7 days, the capsules around NeoMTA Plus and MTA Fillapex had more ICs and IL-6-immunostained cells than the CG. However, at 60 days, there was no significant difference in the IC number between NeoMTA Plus and the CG (p = 0.1137) or the MTA Fillapex group (p = 0.4062), although a greater number of IL-6-immunostained cells was observed in the MTA Fillapex group (p = 0.0353). From 7 to 60 days, the capsule thickness of the NeoMTA Plus and MTA Fillapex specimens significantly decreased, concomitantly with an increase in the collagen content. The capsules around root canal sealers showed positivity to the von Kossa stain and birefringent structures. Conclusions: The NeoMTA Plus root canal sealer is biocompatible and exhibits bioactive potential.

Evaluating fermentation quality, in vitro digestibility and aerobic stability of a total mixed ration ensiled with different additives on Tibet plateau

  • Dong, Zhihao;Wang, Siran;Zhao, Jie;Li, Junfeng;Liu, Qinhua;Bao, Yuhong;Shao, Tao
    • Animal Bioscience
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    • v.34 no.2
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    • pp.223-232
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    • 2021
  • Objective: To investigate the improvement in utilization efficiency of total mixed ration (TMR) on Tibetan plateau, TMR were ensiled with different additives. Methods: A total of 150 experimental silos were prepared in a completely randomized design to evaluate the six treatments: i) control (without additive), ii) Lactobacillus buchneri (L. buchneri), iii) acetic acid, iv) propionic acid, v) 1,2-propanediol; and vi) 1-propanol. After 90 days of ensiling, silos were opened for fermentation quality and in vitro analysis, and then subjected to an aerobic stability test for 14 days. Results: Treating with L. buchneri, acetic acid, 1,2-propanediol and 1-propanol decreased propionic acid contents and yeast number, whereas increased (p<0.05) pH, acetic acid and ethanol contents in the fermented TMR. Despite increased dry matter (DM) loss in the TMRs treated with 1,2-propanediol and 1-pronanol, additives did not affect (p>0.05) all in vitro parameters including gas production at 24 h (GP24), GP rate constant, potential GP, in vitro DM digestibility and in vitro neutral detergent fibre digestibility. All additives improved the aerobic stability of ensiled TMR to different extents. Specially, aerobic stability of the ensiled TMR were substantially improved by L. buchneri, acetic acid, 1,2-propanediol, and 1-propanol, indicated by stable pH and lactic acid content during the aerobic stability test. Conclusion: L. buchneri, acetic acid, 1,2-propanediol, and 1-propanol had no adverse effect on in vitro digestibility, while ensiling TMR with the additives produced more acetic acid and ethanol, subsequently resulting in improvement of aerobic stability. There is a potential for some fermentation boosting additives to enhance aerobic stability of fermented TMR on Tibetan plateau.

Effects of Varying Levels of Fungal (Arachniotus sp.) Treated Wheat Straw as an Ingredient of Total Mixed Ration on Growth Performance and Nutrient Digestibility in Nili Ravi Buffalo Calves

  • Shahzad, F.;Abdullah, M.;Chaudhry, A.S.;Bhatti, J.A.;Jabbar, M.A.;Ahmed, F.;Mehmood, T.;Asim, M.;Ahmed, S.;Kamran, Z.;Irshad, I.;Tahir, M.N.
    • Asian-Australasian Journal of Animal Sciences
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    • v.29 no.3
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    • pp.359-364
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    • 2016
  • The study was carried out to explore the effects of replacing wheat straw with fungal treated wheat straw as an ingredient of total mixed ration (TMR) on the growth performance and nutrient digestibility in Nili Ravi buffalo male calves. Fungal treated wheat straw was prepared using Arachniotus sp. Four TMRs were formulated where wheat straw was replaced with 0 (TMR1), 33 (TMR2), 67 (TMR3), and 100% (TMR4) fungal treated wheat straw in TMR. All TMRs were iso-caloric and iso-nitrogenous. The experimental TMRs were randomly assigned to four groups of male calves (n = 6) according to completely randomized design and the experiment continued for four months. The calves fed TMR2 exhibited a significant improve in dry matter intake, average daily weight gain, feed conversion ratio and feed economics compared to other groups. The same group also showed higher digestibility of dry matter, crude protein, neutral-, and acid detergent fibers than those fed on other TMRs. It is concluded that TMR with 33% fungal-treated wheat straw replacement has a potential to give an enhanced growth performance and nutrient digestibility in male Nili Ravi buffalo calves.

The Effect of Water Activation on Chemical Modification of Cellulose and Characterization (Water activation에 기반한 셀룰로오스의 개질 및 특성)

  • Kim, Hae-Ri;Nam, Byeong-Uk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.2
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    • pp.977-982
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    • 2013
  • Cellulose mixed esters (CME), substituted by various fatty acyl chains, are renewable bio-based polyesters. It has lots of potential due to the biodegradable property. In this study, Alpha cellulose was activated for 2h at $40^{\circ}C$ in deionized water prior to synthesis. Homogeneous esterification of CME was accomplished with water-activated alpha cellulose, various saturated fatty acids and acetic anhydride in lithium chloride/N,N-dimethylacetamide (LiCl/DMAc) medium. CME was obtained after 5 hr at $120^{\circ}C$. The filtrated products were characterized using TGA, FT-IR, 1H-NMR and FE-SEM, and the influence of water activation on the total degree of substitution was investigated.