• Title/Summary/Keyword: mixed metal

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Biosorption of Heavy Metals by Saccharomyces uvarum (Saccharomyces uvarum에 의한 중금속 생체흡착에 관한 연구)

  • 안갑환;서근학
    • Journal of Environmental Science International
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    • v.4 no.5
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    • pp.527-534
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    • 1995
  • The waste biomass of Sacchromyces uvarum, used in fermentation industries to produce ethanol, were studied for their ability to absorb various heavy metal ions. Heavy metal ions studied in this research were Cd, Co, Cr, Cu, Ni and Pb. The order of the sorption capacity was Pb>Cu>Co=Cr=Cd>Ni. The living Sacchromyces uvarum exhibited higher metal-uptake capacity than the dead Sacchromyces uvarum. After we compare the uptake capacity of the Sacchromyces uvarum for individual metal ions with for a mixture of them, the following was observed: in the mixed heavy metal solution the uptake capacity was decreased than the one heavy metal solution. The selective uptake was observed when all . the heavy metal ions were dissolved in a mixed solution. The adsorption isotherm modelling was decribed with the Langmuir and Freundlich model. The results were in good agreement with the Langmuir model.

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Separation of Cr(VI) from Heavy Metal Salts Mixed Solution by using Hollow Fiber Module (실관막모듈에 의한 중금속염 혼합용액으로부터 Cr(VI) 분리)

  • 최대웅
    • Journal of Environmental Health Sciences
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    • v.27 no.3
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    • pp.107-112
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    • 2001
  • This work reports the application of a hollow fiber module(HFM) for Cr(VI) extraction from heavy metal salts mixed solution by using microporous hydrophobic hollow fiber module. In HFM configuration, the organic extraction used for the extraction of Cr(VI) was di-(2-ethyl hexyl) phosphoric acid(D2EHPA) diluted with n-heptane. The study of HFM includes the influence of hydrodynamic and chemical condition, i.e., the flow rate of feed solution, the time of reactive extraction, the concentration of feed solution, and the pH of aqueous phase solutions. Several experiments with synthetic solution of different mixed components system of Cr(VI) solutions established optimum condition to achieve a clean separation of Cr(VI). It was possible to separate Cr(VI) in the presence of metal salts mixed solution, such as Zn(II), Ni(II), Cu(II), and Cd(II) using the HFM technique.

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Enhancing Gas Response Characteristics of Mixed Metal Oxide Gas Sensors

  • Balamurugan, Chandran;Song, Sun-Ju;Kim, Ho-Sung
    • Journal of the Korean Ceramic Society
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    • v.55 no.1
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    • pp.1-20
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    • 2018
  • Semiconducting nanomaterials have attracted considerable interest in recent years due to their high sensitivity, selectivity, and fast response time. In addition, for portable applications, they have low power consumption, lightweight, simple in operation, a low maintenance cost. Furthermore, it is easy to manufacture microelectronic sensor structures with metallic oxide sensitive thin layers. The use of semiconducting metal oxides to develop highly sensitive chemiresistive sensing systems remains an important scientific challenge in the field of gas sensing. According to the sensing mechanisms of gas sensors, the overall sensor conductance is determined by surface reactions and the charge transfer processes between the adsorbed species and the sensing material. The primary goal of the present study is to explore the possibility of using semiconducting mixed metal oxide nanostructure as a potential sensor material for selective gases.

Stabilization for Heavy Metal Contamination Soils which Uses the Coal Mine Drainage Sludge (폐 석탄광산 배수처리 시 발생되는 슬러지를 이용한 오염토양 중금속 안정화)

  • Cui, Mingcan;Lim, Jung-Hyun;Son, Young-Gyu;Jang, Min;Shim, Yon-Sik;Khim, Jee-Hyeong
    • Journal of Environmental Science International
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    • v.18 no.2
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    • pp.239-244
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    • 2009
  • In this study, to stabilize the heavy metal in the contaminated soils, the column leaching test based on rainfall and pH value was performed by using coal mine drainage sludge(CMDS): which was generated during electrical purification of abandoned coal mine wastewater. Four types of testing column were used in this study. That were the CMDS and the heavy metal contaminated soils well mixed in 0 wt%, 1 wt%, 3 wt% and 3 wt% layered column. According to the investigation, when the influent pH was $5.5{\sim}6.2$, there were no heavy metal elution at all conditions, and when the influent pH was $3{\sim}3.3$, the order of Cu, Zn, Pb, Cr elution concentration was 3 wt% M(mixed)<3 wt% S(separation)<1 wt% M<0 wt% and the average elution concentration was quite low, the value was 0.005 mg/L. Therefore, CMDS can used as new stabilizer of the heavy metal in the contaminated soils.

Low cost 2.4-GHz VCO design in 0.18-㎛ Mixed-signal CMOS Process for WSN applications (저 가격 0.18-㎛ 혼성신호 CMOS공정에 기반한 WSN용 2.4-GHz 밴드 VCO설계)

  • Jhon, Heesauk;An, Chang-Ho;Jung, Youngho
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.24 no.2
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    • pp.325-328
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    • 2020
  • This paper demonstrated a voltage-controlled oscillator (VCO) using cost-effective (1-poly 6-metal) mixed signal standard CMOS process. To have the high-quality factor inductor in LC resonator with thin metal thickness, patterned-ground shields (PGS) was adopted under the spiral to effectively reduce the ac current of low resistive Si substrate. And, because of thin top-metal compared with that of RF option (2 ㎛), we make electrically connect between the top metal (M6) and the next metal (M5) by great number of via array along the metal traces. The circuit operated from 2.48 GHz to 2.62 GHz tuned by accumulation-mode varactor device. And the measured phase noise of LC VCO has -123.7 dBc/Hz at 1MHz offset at 2.62 GHz and the dc-power consumption shows 2.07 mW with 1.8V supply voltage, respectively.

Dissolution Phenomenon of the Base Metal during TLP Bonding Using the Modified Base Metal Powder and Ni Base Filler Metal Powder (유사 조성의 모재분말과 Ni기 삽입금속 혼합분말을 사용한 천이액상확산 접합 시 모재의 용해현상)

  • Song, Woo-Young;Ye, Chang-Ho;Kang, Chung-Yun
    • Journal of Welding and Joining
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    • v.25 no.3
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    • pp.64-71
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    • 2007
  • The dissolution phenomenon of the solid phase powder and base metal by liquid phase insert metal during Transient Liquid Phase bonding using the mixed powder composed of the modified GTD111(base metal) powder and the GNi3 (Ni-l4Cr-9.5Co-3.5Al-2.5B) powder was investigated. In case of the mixed powder contains modified GTD111 powder 50wt%, all of the powder was melted by liquid phase at 1423K. At the temperature between solidus and liquidus of GNi3, liquid phase penetrated into the boundary of the modified GTD111 powder and solid particle separated from powder was melted easily because area of reaction was increased. With increasing mixing ratio of the modified GTD111, it needed the higher temperature to melt all of the modified GTD111 powder. During Transient Liquid Phase bonding using the mixed powder composed of the modified GTD111 50wt% and GNi3 50wt% as insert metal, width of the bonded interlayer was increased with increasing bonding temperature by reaction of the base metal and liquid phase in insert metal. Dissolution of the base metal and modified powder by liquid phase progressed all together and after all of the powder was melted nearly, the dissolution of the base metal occurred quickly.

A Densification Model for Mixed Metal Powder under Cold Coompaction (냉간압축하에서 혼합금속분말의 치밀화 모델)

  • 조진호
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2000.04a
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    • pp.112-118
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    • 2000
  • Densification behavior of mixed copper and tool steel powder under cold compaction was investigated. By mixing the yield functions proposed by Fleck et al. and by Gurson for pure powder in terms of volume fractions and contact numbers of Cu powder new mixed yield functions were employed for densification of powder composites under cold compaction. The constitutive equations were implemented into a finite element program (ABAQUS) to compare with experimental data for densificatiojn of mixed powder under cold isostatic pressing and cold die compaction. finite element calculations by using the yield functions mixed by contact numbers of Cu powder agreed better with experimental data than those by volume fractions of Cu powder.

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A Finite Element Analysis for Densification Behavior of Mixed Metal Powder under Cold Compaction (냉간압축하에서 혼합 금속분말의 치밀화 거동에 관한 유한요소해석)

  • Cho, Jang-Hyug;Cho, Jin-Ho;Kim, Ki-Tae
    • Proceedings of the KSME Conference
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    • 2000.04a
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    • pp.393-398
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    • 2000
  • Densification behavior of mixed copper and tool steel powder under cold compaction was investigated. By mixing the yield functions originally proposed by Fleck-Gurson for pure powder, a new mixed yield functions In terms of volume fractions and contact numbers of Cu powder were employed in the constitutive models. The constitutive equations were implemented into a finite element program (ABAQUS) to compare with experimental data. and with calculated results from the model of Kim et at. for densification of mixed powder under cold isostatic pressing and cold die compaction. Finite element calculations by using the yield functions mixed by contact numbers of Cu powder agreed better with experimental data than those by volume fractions of Cu powder.

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AN EXPERIMENTAL STUDY OF THE EFFECTS OF ION BEAM HIKING ON CERAMO-METAL BONDING (이온선 혼합법이 도재와 금속의 결합에 미치는 영향에 관한 실험적 연구)

  • Hong, Joon-Pow;Woo, Yi-Hyung;Choi, Boo-Byung
    • The Journal of Korean Academy of Prosthodontics
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    • v.29 no.2
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    • pp.245-265
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    • 1991
  • The purpose of this study was to observe the changes of the elemental transmission and bond strength between the metal and porcelain according to various kinds of ion beam mixing method. ion beam mixing of $meta1/SiO_2$ (silica), $meta1/Al_2O_3$(alumina) interfaces causes reactions when the $Ar^+$ was implanted into bilayer thin films using a 100KeV accelerator which was designed and constructed for this study. A vacuum evaporator used in the $10^{-5}-10^{-6}$ Torr vacuum states for the evaporation. For this study, three kinds of porcelain metal selected, -precious, semiprecious, and non-precious. Silica and alumina were deposited to the metal by the vacuum evaporator, separately. One group was treated by two kinds of dose of the ion beam mixing $(1\times10^{16}ions/cm^2,\;5\times10^{15}ions/cm^2)$, and the other group was not mixed, and analyzed the effects of ion beam mixing. The analyses of bond strength, elemental transmissions were performed by the electron spectroscopy of chemical analysis (ESCA), light and scanning electron microscope, scratch test, and micro Vickers hardness tests. The finding led to the following conclusions. 1. In the scanning electron and light microscopic views, ion beam mixed specimens showed the ion beam mixed indentation. 2. In the micro Vickers hardness and scratch tests, ion beam mixed specimens showed higher strength than that of non mixed specimens, however, nonprecious metal showed a little change in the bond strength between mixed and non mixed specimens. 3. In the scratch test, ion beam mixed specimens showed higher shear strength than that of non treated specimens at the precious and semiprecious groups. 4. In the ESCA analysis, Au-O and Au-Si compounds were formed and transmission of the Au peak was found ion beam mixed $SiO_2/Au$ specimen, simultaneously, in the higher and lower bonded areas, and ion beam mixed $SiO_2/Ni-Cr$ specimen, oxygen, that was transmitted from $SiO_2\;to\;SiO_2/Ni-Cr$ interface combined with 12% of Ni at the interface.

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Study on the Adsorption of Heavy Metal Ions by Biomaterials (생물질재료에 의한 중금속 흡착에 관한 연구)

  • 정석희;김상규;이민규
    • Journal of Environmental Science International
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    • v.2 no.4
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    • pp.357-365
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    • 1993
  • This study was conducted for the efficient utilization of biomaterials such as starch residue, tangerine skin, and green tea residue, which are agricultral by-products discarded in Cheju Province annually, as adsorbents and biomaterials were examined for their removal ability of heavy metal ions in waste water by batch adsorption experiments. The removal efficiency of biomaterials for heavy metal ions was above 80-90% and almost similar to activated carbon and the adsorption ability of those treated with 포르말린 was improved in the green tea residue only for $Pb^{2+}$, $Cu^{2+}$, and $Zn^{2+}$. In the conditions of pH, the removal efficiency of heavy metal ions was high in the range of 5-7. In the solutions which heavy metal ions were mixed, the removal efficiency was similar at $Ag^+$, $Pb^{+2}$ and reduced to about 10% at the other ions, as compared with the solutions they were not mixed. Adsorption isotherm of biomaterials was generally obeyed to Freundlich formular than Langmuir formular and Freundlich constant, 1/n were obtained in the range of 0.1-0.5.

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