• Journal of the Mineralogical Society of Korea
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• v.8 no.1
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• pp.13-22
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• 1995

Phase relations of the Pd-Sb system were investigated using the sealed-capsule technique; the quenched run products were studied by reflected light microscopy, X-ray diffraction, and electron microprobe analysis. Eight binary phases were confirmed to exist in the system: Pd20Sb7, Pd31Sb12, Pd8Sb3 (mertieite II), Pd5Sb2, Pd2Sb, Pd5Sb3, PdSb (sudburyite), and PdSb2, (unnamed PdSb2), The X-ray powder diffraction data of all the phases, except for Pd5Sb3, however, may be indexable on an orthorhombic cell, space group Cmc2, with a=3.362(1), b=17.484(7), c=6.934(2)$\AA$. Some physical properties as well as re-determined cell parameters are newly established. A revised phase relations of the Pd-Sb system are presented.

• Proceedings of the Korean Geotechical Society Conference
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• 2007.09a
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• pp.542-557
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• 2007

Contamination of subsurface results in degradation of geomaterials (i.e., soils and rock mass), in the long run. This is mainly due to the presence of chemical and/or radiological materials in undesirable concentrations and at elevated temperatures. However, as contaminant-geomaterial interaction is an extremely slow and complex process, which primarily depends on their physical, chemical and mineralogical properties, it is quite difficult to study this interaction under laboratory or in situ conditions. In such a situation, accelerated physical modeling, using a geotechnical centrifuge, and finite element/difference based numerical modeling techniques are found to be quite useful. This paper presents details of various modeling techniques developed by the researchers at the Indian Institute of Technology Bombay, Mumbai, India, for studying heat migration, flow and interaction (fate) of reactive and non-reactive contaminants in the geoenvironment, under saturated and unsaturated conditions. In addition, paper presents details of the technique that can be employed for determining susceptibility of a material to undergo physico-chemico-mineralogical alterations due to its interaction with contaminants.

• Journal of the Korean Geotechnical Society
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• v.16 no.6
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• pp.51-58
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• 2000

울산지역에 널리 분포하고 있는 해성 퇴적토에 대하여 깊이별로 물리, 화학 그리고 광물학적 특성을 파악하였으며, 이 지역에서 채취된 시료에 대하여 깊이별로 퓨준압말시험을 실시하였다. 본 논문을 위하여 울산 해성 퇴적토의 생성과정을 추정하고, X-선 회절 분석, X-선 형광분석 및 에너지분산분광분석을 실시하여 깊이에 따른 변화를 비교하였다. 울산 해성 퇴적토의 점토광물에 대한 정량분석결과, 일라이트, 카올리나이트, 녹니석, 스멕타이트 순으로 많게 나타났음, 화학성분 분석결과, SiO$_2$, $Al_2$O$_3$그리고 Fe$_2$O$_3$가 대부분을 차지하는 것으로 나타났다. 주사전자현미경 관찰결과, 유공충과 규조류가 관찰되었다. 표준압밀시험 결과, 울산지역의 해성 퇴적 점토는 깊이에 따른 변형거동이 화학적, 광물학적 분석결과와 마찬가지로 깊이에 따른 변화를 보이지 않아 같은 시디에 퇴적인 것으로 판단된다.

• Journal of the Mineralogical Society of Korea
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• v.18 no.2
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• pp.93-107
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• 2005

The estuary of Nakdong River area including Noksan industrial complex and Busan New Port is composed of thick unconsolidified sediments containing abundant clay, and thus is a potential hazardous area of ground subsidence. We analyzed mineral compositions and geotechnical properties of the clay sediments that sampled from 4 boreholes of the area, and examined vertical variations and their correlations. The results showed correlations between some mineral constituents and geotechnical properties of clay sediments. A positive correlation showed between quartz content and wet unit weight, whereas a negative correlation showed between quartz content and liquid limit. Feldspar content and water content showed a negative correlation, whereas content of clay minerals and liquid limit showed a positive correlation. And also, there is a negative correlation between content of clay minerals and wet unit weight. Correlation equations are obtained from the multiple regression analyses among plastic index, content of clay mineral, smectite and clay fraction.

• The Bulletin of The Korean Astronomical Society
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• v.36 no.2
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• pp.122.2-122.2
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• 2011

For more than a decade, NEA (Near-Earth Asteroid) survey teams equipped with 1 meter-class telescopes discovered thousands of NEAs in the northern sky. As of August 2011, some 8,200 NEAs have been cataloged, yet only five percent of them has been investigated for their physical and chemical properties. In order to improve current situation, we propose a deep ecliptic survey utilizing KMTNet, for detection and characterization of NEAs in the southern sky. Thanks to the wide-field capability (four square degrees) of the telescopes, we will be able to considerably expand the search volume carrying out precision photometry down to 21.5th magnitude. We plan to focus our survey on opposition and two "sweet spots" in the ecliptic belt. Since SDSS colors characterize mineralogical properties of NEAs, g', r', i', z' filters will be employed. Based on the round-the-clock observation, we will study their rotational properties; for multiple systems, mass, density and other physical parameters can be obtained. We plan to maintain a dedicated database of the physical and mineralogical properties of NEAs. With this archive, it is expected that our understanding on the population will see a drastic change. We also plan to participate in the GAIA Follow-Up Network for ground based observation of the Solar System Objects (GAIA-FUN-SSO). The follow- up astrometry will be performed upon alerts issued by the GAIA-FUN-SSO Central Node in France.

• Journal of Conservation Science
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• v.35 no.6
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• pp.600-611
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• 2019

Yellow to reddish brown soil is generally referred to as hwangto and is used in various industries in Korea. Despite the fact that it is used as an inorganic pigment in dancheong, limited studies have been conducted on the properties of pigments associated with soil and on the mineralogical characteristics of hwangto. This study examines how the pedological and mineralogical features of hwangto affect pigment properties. Results indicate that reddish and yellowish soils have differences in terms of soil texture, mineral composition, oil absorption and stability under light. Reddish soil is mostly found in clay regions, whereas Ulleungdo hwangto is found in loam regions. Yellowish soil is mostly present in the clay loam to loam zones. whereas Haenam hwangto exists in the sandy clay loam zone. As a result of a mineralogical analysis, reddish soil is classified into the feldspar group and clay soil. The major minerals in the yellowish soils are similar however these soils differ in terms of clay mineral compositions. results of the characteristics of pigments prepared by the traditional method revealed that the average particle size is in the range of 10-20 ㎛, reddish soil has an average of 20 ml/100 g higher oil absorption than yellowish soil. In addition, reddish soil is more susceptible to discoloration and deterioration under light than yellowish soil. This study confirms that the soil and mineral characteristics of hwangto affect the physical properties and stability of produced pigments. These result can be used as basic data in future studies natural inorganic pigments using hwangto.

• Journal of the Mineralogical Society of Korea
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• v.28 no.2
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• pp.147-163
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• 2015

Chemical and mineralogical properties of coal ash samples from the nine thermal power plants of Korea were investigated to acquire basic data for estimating the potential of rare metal recovery. Chemical compositions of coal ash were consistent with those of average shale and foreign coal ashes. However, there were small differences between the metal contents of domestic anthracitic and imported bituminous coal ashes. Unburned coal particles were much abundant in the ash of domestic anthracitic coal. Chalcophile elements were relatively enriched in the fly ash compared to bottom ash. Silicate glass was the major component of coal ash with minor minerals such as quartz, illite (muscovite), mullite, magnetite, lime, and anhydrite. Al and Si were the major components of the glass with varying contents of Ca, Fe, K, and Mg. Glass occurred in a form of porous sphere and irregular pumace-like grain often fused with iron oxide spheres or other glass grains. Iron oxide spheres were fine intergrowth of fast-grown iron oxide crystals in the matrix of silicate glass. Chemical, microstructural, and mineralogical properties would guide successful rare metal recovery from coal ash.

• The Journal of Engineering Geology
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• v.32 no.4
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• pp.685-696
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• 2022

Although the use of pottery-making soils has a long history, its use in the pottery industry requires that physical and geotechnical properties of the materials be established to define the suitability for various purposes. The main purpose of this study is to identify the different types of clays and mineral composition and to perform the geotechnical evaluation of the clays for making pottery products. Soils investigated in this study include raw materials used for making Baekja (white porcelains), Chungja (celadons), Buncheong, Sancheong, and Johyung. Pottery-making soils are manufactured by using different types of soils and sold by individual ceramic clay company. This study includes physical tests of soil and chemical analysis of major elements using XRF and XRD instrumentation. Grain size distributions, mineralogical composition, and a range of plasticities of soils for making different types of potteries are presented. Correlations between specific type of pottery clays and geotechnical and mineralogical characteristics are determined by comparing the test results. Since quantitative research using laboratory tests for pottery-making soils are rarely performed in Korea, further research should be done in the future to improve the Korean pottery industry.

• Nuclear Engineering and Technology
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• v.55 no.3
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• pp.1191-1198
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• 2023

Bentonite buffer material is a critical component in an engineered barrier system (EBS) for disposing high-level radioactive waste (HLW). The bentonite buffer material protects the disposal canister from groundwater penetration and releases decay heat to the surrounding rock mass; thus, it should possess high thermal conductivity, low hydraulic conductivity, and moderate swelling pressure to safely dispose the HLWs. Bentonite clay is a suitable buffer material because it satisfies the safety criteria. Several additives have been suggested as mixtures with bentonite to increase the thermal-hydraulic-mechanical-chemical (THMC) properties of bentonite buffer materials. Therefore, this study investigated the geotechnical, mineralogical, and THMC properties of several candidate additives such as sand, graphite, granite, and SiC powders. Datasets obtained in this study can be used to select adequate additives to improve the THMC properties of the buffer material.

• Journal of the Mineralogical Society of Korea
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• v.16 no.1
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• pp.33-47
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• 2003

Various applied-mineralogical characterization including measurements of surface area, size distribution, swelling index, and viscosity were done for some domestic bentonites in order to decipher the rheological properties and their controlling factors. The bentonites, which are Ca-type and relatively low-grade (rnontmorillonite contents: 30 ∼ 75 wt%), occur mostly as subhedral lamellas with the size range of 2 ∼ 4 $\mu\textrm{m}$. The size distribution of mineral fractions in bentonite suspension is dominant in the range of 10 ∼ 100 $\mu\textrm{m}$, and though rather complicated, exhibits roughly bimodal patterns. The feature is more conspicuous in the case of zeolitic bentonite. The bentonites have surface areas ranging 269 ∼ 735 $\m^2$/g, which are measured by EGME adsorption method. The EGME surface areas are nearly proportional to the rnontmorillonite contents, moisture contents, or total CEC. In the surface area measurements, zeolitic bentonites have slightly higher values than those zeolite- free types. The measured swelling index and viscosity of domestic bentonites are comparatively low in values. The swelling values of bentonites were measured to be 250∼500% at maximum by progressively mixing amounts of 2 ∼ 5 wt% Na$_2$CO$_3$, which varies depending on the contents of rnontmorillonite and other impurities, especially zeolite. Much amount of sodium carbonate is required for optimum swelling property of zeolitic bentonited which has usually strong Na- exchanged capacity. The bentonites, which are comparatively feldspar-rich and low in size and crystallinity, tend to be higher in viscosity values. Tn addition, the viscosity is largely higher in case of the bentonites with higher pH in suspension. However, the rheological properties of bentonites such as swelling index and viscosity do not show any obvious relationships with rnontmorillonite contents and mean particle size in suspension. In contrast, roughly speaking, the swelling index of bentonites is reversely proportional to the values of surface area which can be regarded as a collective physico-chemical parameter encompassing all the effects caused by mineral composition, surface charge, particle size, morphological farm, and etc. in bentonites. Thus, the rheological properties in bentonite suspension appear to be rather complicated characteristics which mainly depend on the flocculation of clay particles and the mode of particle association, i.e. quasicrystals, controlled by surface charge, morphology, size, and texture of rnon-tmorillonite, and which partly affected by the finer impurities such as zeolite.