Journal of the Mineralogical Society of Korea (한국광물학회지)
- Volume 8 Issue 1
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- Pages.13-22
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- 1995
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- 1225-309X(pISSN)
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- 2288-7172(eISSN)
Phases and Phase Relations of the System Pd-Sb
팔래듐-안티모니계의 화합물 및 상평형 연구
Abstract
Phase relations of the Pd-Sb system were investigated using the sealed-capsule technique; the quenched run products were studied by reflected light microscopy, X-ray diffraction, and electron microprobe analysis. Eight binary phases were confirmed to exist in the system: Pd20Sb7, Pd31Sb12, Pd8Sb3 (mertieite II), Pd5Sb2, Pd2Sb, Pd5Sb3, PdSb (sudburyite), and PdSb2, (unnamed PdSb2), The X-ray powder diffraction data of all the phases, except for Pd5Sb3, however, may be indexable on an orthorhombic cell, space group Cmc2, with a=3.362(1), b=17.484(7), c=6.934(2)
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