• Title/Summary/Keyword: mineral balance

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Estimation of Alkali Overdosing in a Lime Neutralization Process for Acid Mine Drainage

  • Cheong, Young-Wook;Cho, Dong-Wan;Lee, Jin-Soo;Hur, Won
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.109-112
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    • 2022
  • Lime has been used for the neutralization of acidic waste because it is cheap and available in large quantities. The resulting sludge often contains a considerable amount of unreacted lime due to alkali overdosing, even during automatic neutralization processes, which mainly arises from the poor solubility of lime. The sludge cake from lime neutralization of Ilkwang Mine also contained high percentages of calcium and magnesium. The elemental content of the sludge cake was compared with those obtained from a simulation of the lime neutralization facility installed at Ilkwang Mine. A Goldsim® model estimated the degree of lime overdosing to be 19.1% based on the fractions of ferrous oxide. The analysis suggests that resolubilization of aluminum hydroxide could occur in the settling basin, in which pH exceeded 10 due to the continued dissolution of the overdosed lime. The present study demonstrated that chemical analysis of sludge combined with process simulation could provide a reasonable estimate of mass balance and chemistry in a neutralization facility for acid mine drainage.

The Responses of a Small Lake Watershed to an Inorganic Carbon Cycle (무기탄소 순환에 대한 소규모 호수 유역의 반응)

  • Cho, Youngil
    • Journal of Korean Society on Water Environment
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    • v.29 no.5
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    • pp.610-617
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    • 2013
  • Investigating the budgets of alkalinity and dissolved inorganic carbon (DIC) in lake water systems is significant for the examination of the behavior of a lake as a sink or a source with respect to the circulation of inorganic carbon chemistry. Budgets of total alkalinity ($Alk_T$) and DIC in Onondaga Lake, which was polluted by chronic calcium (Ca) loading in spite of the closure of soda ash ($Na_2CO_3$) facility, were determined by the analyses of inorganic carbon chemistry in tributary stream channels linked to the lake. AlkT and DIC fluxes of Onondaga Creek and Ninemile Creek occupied 65% and 54%, respectively, as larger tributary streams in comparison with other tributaries as well as different input sources. Budget calculations indicate that 18% of AlkT and 11% of DIC inputs to Onondaga Lake, respectively, remained immobilized in the Lake. This suggests that Ca chronically leached had been precipitated with inorganic carbon or remineralized by secondary mineral formation during the experimental period. In this study, the assumed mass balance calculation in Onondaga Lake with tributary streams resulted in exhibiting that the lake played a role of the sink for the inorganic carbon cycle.

Effect of Niacin Supplementation on Growth, Nutrient Utilization and Blood Biochemical Profile in Male Buffalo Calves

  • Kumar, Ravindra;Dass, R.S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.10
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    • pp.1422-1428
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    • 2006
  • In order to investigate the effect of different levels of niacin supplementation on growth, nutrient utilization, their balance and blood biochemical profile, 15 male buffalo calves (9-10 months of age, $88.4{\pm}4.37kg$ average body weight) were divided into 3 equal groups each of 5 calves, following a completely randomized design, and fed individually for 120 days with wheat straw and concentrate mixture to meet their nutrient requirements. In addition calves were supplemented with 0 ppm (control, group I), 100 ppm (group II) and 200 ppm (group III) niacin. After 90 days of experimental feeding a metabolism trial was conducted to estimate the digestibility of nutrients and their balance. Fortnightly body weights were recorded to assess their growth rate and blood was collected from the jugular vein at day 0 and subsequently at 30-day intervals from all the experimental buffalo calves to study blood biochemical parameters. Results showed that intake and digestibility of dry matter, organic matter, crude protein, ether extract, total carbohydrates, neutral detergent fibre, acid detergent fibre, cellulose and hemicelluloses were statistically similar in the 3 groups. Buffalo calves in all three groups were in positive nitrogen, calcium and phosphorus balance, without showing any significant effect of the treatments. Dry matter, crude protein, digestible crude protein and total digestible nutrient intake ($g/d/kgW^{0.75}$) were similar in the control and niacin supplemented groups. Digestible crude protein (%) and total digestible nutrients (%) in the ration of the 3 groups were 8.07, 7.99, 7.92 and 56.70, 56.63, 56.74, respectively, and were comparable among the groups. The average daily gain (g) in-group II (567.50) was not significantly (p>0.05) higher than group I (500.0) and group III (510.0). Blood biochemical constituents (glucose, total protein, albumin, globulin, urea-N, insulin) showed no significant effect of niacin supplementation. However, serum cholesterol (mg/100 ml) was significantly (p<0.01) lower in the 200 ppm niacin-supplemented group than in the control and 100 ppm niacin-supplemented groups. It can be concluded that supplementation of niacin at 100 and 200 ppm in the diet of buffalo calves had no significant beneficial effect on their growth and nutrient utilization.

A Study on Estimation of Initial Gas in Place for Coalbed Methane Field Using Production Data at Canada (생산자료를 이용한 캐나다 CBM 원시부존량 평가 연구)

  • Seo, Hyeongjun;Moon, Bryan;Kim, Kihong;Han, Jungmin;Kwon, Sunil
    • Journal of the Korean Institute of Gas
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    • v.22 no.1
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    • pp.64-77
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    • 2018
  • This paper presents the prediction of the original gas in place(OGIP) by using the material balance method and decline curve analysis method with production history and pressure transient test data for four coalbed methane wells in the Horseshoe Canyon field. In this study, the conventional gas equation and the Jensen and Smith(J&S) equation were used to material balance analysis, and the Arps' empirical correlation and Khaled method were applied to decline curve analysis. From the results, the OGIP estimated from the conventional gas and the J&S method was small in difference as under 12%. Also, in case of decline curve analysis, it was found that the Khaled method has appropriated to calculate the OGIP, because the OGIP was estimated as unlimited value by the Arps' equation from the decline exponent of 1 - 3.5. The OGIP difference between conventional gas method and Khaled method was calculated as 8.67% ~ 31.04%, and those between J&S method and Khaled method was 13.67% ~ 26.49%.

Impact of Climate Change on the Groundwater Recharge and Groundwater Level Variations in Pyoseon Watershed of Jeju Island, Korea (기후 변화에 따른 제주도 표선 유역의 함양률 및 수위변화 예측)

  • Shin, Esther;Koh, Eun-Hee;Ha, Kyoochul;Lee, Eunhee;Lee, Kang-Kun
    • Journal of Soil and Groundwater Environment
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    • v.21 no.6
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    • pp.22-35
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    • 2016
  • Global climate change could have an impact on hydrological process of a watershed and result in problems with future water supply by influencing the recharge process into the aquifer. This study aims to assess the change of groundwater recharge rate by climate change and to predict the sustainability of groundwater resource in Pyoseon watershed, Jeju Island. For the prediction, the groundwater recharge rate of the study area was estimated based on two future climate scenarios (RCP 4.5, RCP 8.5) by using the Soil Water Balance (SWB) computer code. The calculated groundwater recharge rate was used for groundwater flow simulation and the change of groundwater level according to the climate change was predicted using a numerical simulation program (FEFLOW 6.1). The average recharge rate from 2020 to 2100 was predicted to decrease by 10~12% compared to the current situation (1990~2015) while the evapotranspiration and the direct runoff rate would increase at both climate scenarios. The decrease in groundwater recharge rate due to the climate change results in the decline of groundwater level. In some monitoring wells, the predicted mean groundwater level at the year of the lowest water level was estimated to be lower by 60~70 m than the current situation. The model also predicted that temporal fluctuation of groundwater recharge, runoff and evapotranspiration would become more severe as a result of climate change, making the sustainable management of water resource more challenging in the future. Our study results demonstrate that the future availability of water resources highly depends on climate change. Thus, intensive studies on climate changes and water resources should be performed based on the sufficient data, advanced climate change scenarios, and improved modeling methodology.

Treatment of chronic kidney disease in children (소아의 만성신장질환의 치료)

  • Lee, Joo Hoon
    • Clinical and Experimental Pediatrics
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    • v.52 no.10
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    • pp.1061-1068
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    • 2009
  • The treatment of pediatric patients with chronic renal disease comprises management of nutritional imbalance, fluid, electrolyte, and acid-base disturbances, mineral bone disease, anemia, hypertension, and growth retardation. The treatment also includes administration of appropriate renal replacement therapy, if required. Adequate dietary intake of carbohydrates, fats, and proteins and caloric intake must be encouraged in such patients to ensure proper growth and development. In addition, fluid, electrolyte, and acid-base status must be regularly monitored and should be well maintained. Serum calcium, phosphorus, and parathyroid hormone levels must be maintained at their target range, which are determined on the basis of the glomerular filtration rate, to avoid the development of mineral bone disease. This can be achieved by using phosphorus binders and vitamin D analogues. An erythropoiesis-stimulating agent must be administered along with iron supplementation to maintain the hemoglobin level of the patients between 11-12 g/dL. Hypertension must be controlled with adequate water and sodium balance and appropriate antihypertensive agents. Administration of recombinant human growth hormone is recommended to improve the final adult heights.

The Influence of Diet, Body Fat, Menstrual Function, and Activity upon the Bone Density of Female Gymnasts (신체구성성분, 영양상태 및 월경기능이 여자체조선수의 골밀도에 미치는 영향(제2보))

  • 우순임
    • Journal of Nutrition and Health
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    • v.32 no.1
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    • pp.50-63
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    • 1999
  • This study was conducted with 20 female gymnasts and 23 age-matched controls to examine the relationship of diet, menstrual function and bone mineral density (BMD). The results obtained are summarized as follows : Energy intake of gymnasts was 968.9$\pm$421.4kcal, and energy expenditure was 2091.4$\pm$361kcal showing negative energy balance(-1,122.5$\pm$534.6kcal). The average intakes of calcium, iron, vitamin A, thiamin, riboflavin and niacin did not meet the Recommended Dietary Allowances for their age groups. Mean age at menarche in gymnasts is 15.8$\pm$1.2 years compared with 11.8$\pm$2.8 years in age-matched controls. The profile of estradiol, progesterone, and luteinizing hormone was lower than age-matched controls but not significant. Athletic amenorrheic gymnasts(n=12) have the menstrual irregularity(n=10) and amenorrhea(n=2). A number of variables as such nutritional deficiency in diet, negative energy blasnce and hypogonadotropic hormonal status were included. The bone mineral density (BMD) of female gymnasts were significantly higher than controls for the lumbar neck(p<0.001), trochanter(p<0.01), and Ward's triangle(p<0.001), but there were no significant differences for the lumbar spine and forearm. The lumbar spine BMD had a positive correlation with age and lean body weight. The femoral neck BMD was significantly associated with age, group and lean body mass. The trochanter BMD had significant relationship with group, body mass index, energy expenditure and follicular stimulating hormone. Ward's triangle BMD were related to body mass index and follicular stimulating hormone. The significant association was deterced between forearm BMD and age and lean body weight. The major finding of this investigation is that the BMD of gymnasts were higher than age-matched controls despite the fact that gymnasts as a group had inadequate dietary calcium and a higher propensity to have an interruption of their menstrual cycle. These data indicate that grymnsts involved in sports producing significant impact loading on the skeleton had greater femoral neck, trochanter and Ward's triangle bone density than age-matched controls.

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Regional Groundwater Flow Characteristics due to the Subway System in Seoul, Korea (지하철에 의한 서울특별시 광역 지하수 유동 특성)

  • Shin, Esther;Kim, Hyoung-Soo;Ha, Kyoochul;Yoon, Heesung;Lee, Eunhee
    • Journal of Soil and Groundwater Environment
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    • v.20 no.3
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    • pp.41-50
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    • 2015
  • Hydrogeologic environment of the Mega City such as Seoul, suffers from rapid changes caused by urbanization, construction of underground subway or buildings, and contaminant loading by diverse anthropogenic activities. Understanding the present condition of groundwater environment and water budget is necessary to prevent natural and manmade disasters and to prepare for sustainable water resource management of urban environment. In this study, regional groundwater flow and water budget status of Seoul was analyzed using numerical simulation. Modeling result indicated that groundwater level distribution of Seoul generally followed the topography, but the significant decreases in groundwater level were observed around the subway network. Steady-state water balance analysis showed groundwater recharge by rainfall and leakage from the water supply network was about 550,495 m3/day. Surface water inflow and baseflow rate via Han River and major streams accounted for 799,689 m3/day and 1,103,906 m3/day, respectively. Groundwater usage was 60,945 m3/day, and the total groundwater leakage along the subway lines amounted to 114,746 m3/day. Modeling results revealed that the subway could decrease net groundwater baseflow by 40%. Our study result demonstrated that the subway system can have a significant influence on the groundwater environment of Seoul.

A catchment management experiences of the Evian natural mineral water (NMW) source site (에비앙 천연 광천수 수원의 유역 관리 사례)

  • Chung, Il-Moon;Lachassagne, Patrick
    • Journal of Korea Water Resources Association
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    • v.53 no.spc1
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    • pp.827-832
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    • 2020
  • The catchment management experiences of the Evian natural mineral water (NMW) bottling company were reviewed. Evian is among the leading brands of bottled NMW in France, exporting worldwide and becoming a role model for companies in many countries due to its long-term experiences in sustainably managing NMW source areas. Experiences of bottled water companies in France show that they are incessantly moving forward with proactive and advanced ideas to meet environmental challenges. For business sustainability, companies are dedicated to improving their environmental performance through effective and planned resource management. Evian has been working with the local community in a spirit of co-ownership to invent and preserve the water resource and fulfill its ambition of sustainable industrial functioning. The partnership aims to balance the protection of the NMW resource and sustainable agricultural development within the catchment.

Bone Mineral Density and Osteoporotic Vertebral Fractures in Traditional, Unassisted, Free-Diving Women (Haenyeos)

  • Seo, Jun-Yeong;Ha, Kee-Yong;Kim, Young-Hoon;Kim, Seong-Chan;Yoon, Eun-Ji;Park, Hyung-Youl
    • Journal of Korean Medical Science
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    • v.33 no.48
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    • pp.316.1-316.10
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    • 2018
  • Background: Water pressure and muscle contraction may influence bone mineral density (BMD) in a positive way. However, divers experience weightlessness, which has a negative effect on BMD. The present study investigated BMD difference in normal controls and woman free-divers with vertebral fracture and with no fracture. Methods: Between January 2010 and December 2014, traditional woman divers (known as Haenyeo in Korean), and non-diving women were investigated. The study population was divided into osteoporotic vertebral fracture and non-fracture groups. The BMD of the lumbar spine and femoral neck was measured. The radiological parameters for global spinal sagittal balance were measured. Results: Thirty free-diving women and thirty-three non-diving women were enrolled in this study. The mean age of the divers was $72.1{\pm}4.7$ years and that of the controls was $72.7{\pm}4.0$ years (P = 0.61). There was no statistical difference in BMD between the divers and controls. In divers, cervical lordosis and pelvic tilt were significantly increased in the fracture subgroup compared to the non-fracture subgroup (P = 0.028 and P = 0.008, respectively). Sagittal vertical axis was statistically significantly correlated with cervical lordosis (Spearman's rho R = 0.41, P = 0.03), and pelvic tilt (Spearman's rho R = 0.46, P = 0.01) in divers. Conclusion: BMD did not differ significantly between divers and controls during their postmenopausal period. When osteoporotic spinal fractures develop, compensation mechanisms, such as increased cervical lordosis and pelvic tilt, was more evident in traditional woman divers. This may be due to the superior back muscle strength and spinal mobility of this group of women.