• Ecology and Resilient Infrastructure
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• v.5 no.1
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• pp.1-10
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• 2018

We examined the effect of simultaneous application of phosphorus (P) and iron (Fe) on the phytotoxicity of lettuce in arsenic (As) contaminated soil using response surface methodology (RSM). To stabilize As and supply nutrient into soil, Fe and P were treated, respectively. Water soluble As and P was decreased by Fe application but increased by P application. Through phytotoxicity test, the result showed that only the addition of P affected lettuce root elongation even though both P and Fe were added. The correlation coefficients between root elongation and other indices indicated that the As content in the roots seemed to be the main reason that root growth was impeded. We could verify that the former result was not a passing phenomenon and Fe was necessarily needed to protect secondary pollution by exclusive usage of P fertilizer.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2006.04a
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• pp.224-225
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• 2006

점토성 오염토양을 원위치 정화하는데 효과적인 것으로 알려진 Electrokinetic정화기술을 이용하여 폐광산의 광미를 대상으로 실험을 수행하였다. 실험은 초기 인가 전류 0.01A, 170V의 정전압모드로 약 950시간동안 운전하였으며, 투입된 총전력량은 5671.455 WH으로시간당 5.97W의 전력이 투입되는 것이다. 중금속류(As,Pb,Cd,Zn,Cu,Ni)에 대하여 $50{\sim}90%$의 제거효율을 보였으며 중금속 농도는 점차 감소하고 중금속별로 $Zn{\cong}Cd>Ni>Cu{\cong}Pb{\cong}As$ 의 경향을 보였다.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2005.10a
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• pp.404-409
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• 2005

The reinforced concrete blocks for reinforced earth layer are combined with soil structures consisted of facing unit, reinforcing materials and soil. Those environmentally friendly facing units of reinforced concrete blocks are made of mine waste and tailing and that will be played a role of the effects of recycling use of wasted resources. The block are consisted of three types as curved or straight in order to control topography. The systems are also not limited to wall hight so that they are effectively used for protecting the slope of banking and cutting of earth works. The reinforced concrete blocks developed this time will be effectively applied for not only retaining wall, road, park, golf course, public office building constructions but also protecting of slope stabilization projects.

• The Journal of Engineering Geology
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• v.28 no.3
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• pp.411-429
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• 2018

Daeyoung mine (also called "Daema mine") produced gold and silver from mainly gold- and silver-bearing quartz veins. The mine tailings are a waste hazard, but most of the tailings were swept away or dispersed throughout the area around the mine long before the tailing dump areas were transformed into agricultural land. Soil liner and protection facilities, such as retaining walls, were constructed in the mine area to prevent the loss of tailings. The content of the tailings is 3,424.41~3,803.61 mg/kg, which exceeds the safety standard by a factor of 45. In addition, contamination was detected near agricultural areas and in the sediments in downstream drainage channels. A high level of As contamination was concentrated near the waste tailings yard; comparaable levels were detected in agricultural areas close to streams that ran through the waste dump yard, whereas the levels were much lower in areas far from the streams. The contamination in stream sediments showed a gradual decrease with distance from the mine waste yard. Based on these contamination patterns, we concluded that there are two main paths that affect the spread of contaminants: (1) loss of mine waste, and (2) the introduction of mine waste into agricultural areas by floods after transportation by streams. The agricultural areas contaminated by mass inflow of mine waste can act as contamination sources themselves, affecting other agricultural areas through the diffusion of contaminants. At present, although the measured effect in minimal, sediments in streams are contaminated by exposed mine waste and surface liners. It is possible for contaminants to diffuse or spread into nearby areas if heavy elements trapped in soil grains in contaminated agricultural areas leach out as soil solution or contaminant particles during diffusion into the water supply.

• Korean Journal of Soil Science and Fertilizer
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• v.41 no.3
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• pp.223-227
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• 2008

This experiment was conducted to describe the distribution of stable isotope Cd in the mine tailing and uncultivated soils derived from different parent rocks (Igneous rock, Metamorphic rock, and Sedimentary rock) as well as the movement of Cd isotopes from soil to plants, soybean and pepper. The results showed that there was no significant difference in isotopic ratios in soil among the eight kinds of stable isotope of Cd. However the relationship among isotopic ratios of stable isotope of Cd in soils were classified to four types, linear type between $Cd^{106}/Cd^{111}$ and $Cd^{108}/Cd^{111}$, quadratic type between $Cd^{114}/Cd^{108}$ and $Cd^{111}/Cd^{110}$, reverse quadratic type between $Cd^{110}/Cd^{116}$ and $Cd^{108}/Cd^{116}$, and cluster type between $Cd^{110}/Cd^{113}$ and $Cd^{116}/Cd^{113}$. While the individual stable isotopes of Cd in root were remained except on the plot of pepper without mine tailing application. $Cd^{116}$, $Cd^{114}$, and $Cd^{112}$ played active roles among other stable isotopic Cds in bean and red pepper, and $Cd^{116}$ was ranked the highest abundance ratio. Contrary to crop itself, the abundance ratios of $Cd^{116}$ in bean and read pepper roots were decreased, and the ones of other Cds were relatively increased.

• Korean Journal of Environmental Agriculture
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• v.31 no.2
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• pp.122-128
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• 2012

BACKGROUND: Mine drainage from metal mining districts is a well-recognized source of environmental contamination. Oxidation of metal sulfides in mines, mine dumps and tailing impoundments produces acidic, metal-rich waters that can contaminate the local surface water and soil. METHODS AND RESULTS: This experiment was carried out to investigate the pollution assessment of heavy metal on the water quality of mine drainage, paddy soils and sediment in lower watershed affected by mine drainage of the Sambo mine. The average concentrations of dissolved Cd (0.018~0.035 mg/L) in mine drainage discharged from the main waste rock dumps(WRD) was higher than the water quality standards (0.01 mg/L) for agricultural water in Korea. Also, the average concentrations of dissolved Zn, Fe and Mn were higher than those of recommended maximum concentrations (Zn 2.0, Fe 5.0, Mn 0.2 mg/L) of trace metal in irrigation water proposed by FAO (1994). The average contents of Pb and Zn in paddy soils was higher than those of standard level for soil contamination(Pb 200, Zn 300 mg/kg) in agricultural soil by Soil Environmental Conservation Act in Korea. Also, the concentrations of Cd, Pb and Zn in sediment were higher than those of standard level for soil contamination (Cd 10, Pb 400, Zn 600 mg/L) in waterway soil by Soil Environmental Conservation Act in Korea. The enrichment factor (EFc) of heavy metals in stream sediments were in the order as Cd>Pb>Zn> As>Cu>Cr>Ni. Also, the geoaccumulation index (Igeo) of heavy metals in stream sediments were in the order as Zn>Cd>Pb>Cu>As>Cr>Ni, specially, the geoaccumulation index (Igeo) of Zn (Igeo 3.1~6.2) were relatively higher than that of other metals in sediment. CONCLUSION(s): The results indicate that stream water and sediment were affected by mine drainage discharged from the Sambo mine at least to a distance of 1 km downstream (SN-1, SN-2) of the mine water discharge point.

• Korean Journal of Environmental Agriculture
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• v.27 no.4
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• pp.328-336
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• 2008

Metal mining district drainage is a well recognized source of environmental contamination. Oxidation of metal sulfides produces acidic and metal-rich waters that contaminate local surface water and ground water in mines, mine dumps, and tailing impoundments. This monitoring study was carried out to investigate the stream water quality and pollution as affected by the Sambo mine drainage in relation to the relative distance from the mine. It obvious that pH values of the mine drainage ranged from 5.8 to 6.9, while the average concentrations of the dissolved chemical constituents for EC, $SO_4^{2-}$, $K^+$, $Ca^{2+}$, and $Mg^{2+}$ were $1.77\;dS\;m^{-1}$, 929, 14.6, 263.3, and 46.9 mg/L in mine drainage discharged from the main waste rock dumps (WRD), respectively. Furthermore, EC values and sulfate concentrations exceeded the critical toxicity levels in agricultural water for rice plant ($1.0\;dS\;m^{-1}$ for EC and 54.0 mg/L for $SO_4^{2-}$). Also, the average of dissolved cadmium concentrations ($0.016{\sim}0.021\;mg/L$) was higher than water quality standard (0.01 mg/L) for agricultural water in Korea, in addition to Zn, Fe and Mn were higher than trace metals maximum concentrations which recommended by FAO for irrigation water. The results indicate that mine drainage discharged from the Sambo mine affected stream water at least to distance of 1 km downstream of the mine water discharge point. EC values, $SO_4^{2-}$ and $Ca^{2+}$ concentrations in discharged water positively correlated with dissolved Cd, Zn, Al and Mn concentrations, while the pH values negatively correlated. In addition, EC values, $SO_4^{2-}$ and $Ca^{2+}$ concentrations were negatively correlated with pH values.

• Economic and Environmental Geology
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• v.46 no.6
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• pp.535-544
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• 2013

Influence of sulfate on the early hydration in the solidification treatment of abandoned mine tailings was characterized. Solidified specimens using hydrated lime as a binder were prepared with various amounts of added $Na_2SO_4$ and different curing days. Unconfined compressive strength measurement, heavy metal leaching test, XRD analysis were performed after 7-, 14- and 28-days curing. According to curing days strength of solidified specimens using only distilled water increased but those with addition of $Na_2SO_4$ decreased. External cracks of specimens developed definitely with increasing $Na_2SO_4$ concentration and curing days. Concentrations of Cu, Cd, Zn, and As in the leached solutions from solidified specimens decreased significantly but Pb was leached readily in cases of hydrated lime dosage more than 10 wt%. Gypsum and $MgSO_4$ were identified in the cracked solidified specimens by XRD analysis, and pillar-shaped crystals of SEM image were identified as gypsum in reference with EDS analysis. Crystallization of sulfate in the process of lime-tailing solidification caused cracking, which should be supplemented for solidification treatment of highly sulfur-contained tailing.

• The Journal of Engineering Geology
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• v.26 no.4
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• pp.473-484
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• 2016

This study aims to establish a monitoring method for managing the effective maintenance of tailings dams. The monitoring of a tailings dump area involves several parameters and their investigation through a selection of evaluation items. The extents of defects and progressive failures also need to be effectively estimated. Therefore, the monitoring items can be subdivided into categories relating to the retaining wall structure (concrete wall, reinforcing stone wall, mesh gabions) and general facilities (liner, covering soil, slope, tailings, rain protection facility, leachate, planting), and quantitative evaluations can then be conducted for each condition. In doing so, we developed a systematic monitoring method that assesses the dam maintenance condition with grades and scores. The field application of the monitoring method results showed it to provide a more detailed evaluation than existing monitoring methods: the method detected an additional 16 defects missed by conventional methods. The evaluation gave scores of 89.3, 22.2, and 27.8 to the Geumjang mine tailings dam, the Gupoong mine tailings dam, and the Hwachun mine tailings dam, respectively. The advanced method can provide quantitative evaluation and perform detailed monitoring of the dams. This quantitative evaluation can be used to decide on maintenance priorities, select the main management items, and establish schedules of maintenance.

• Economic and Environmental Geology
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• v.28 no.5
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• pp.455-467
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• 1995

In order to investigate the dispersion patterns and speciations of Cu, Pb, Zn and Cd in soils, stream sediments and stream waters, geochemical studies of soil, stream sediment and stream water samples collected in the vicinity of the Shi-Heung Cu-Pb-Zn mine was carried out Cation exchange capacity measurement, size analysis, X-ray diffraction analysis and batch test were performed to select applicable soil for adsorption treatment The average content of Cu, Pb, Zn and Cd in soils collected from tailings and ore dressing plant is 1084 ppm, 2292 ppm, 3512 ppm and 29.2 ppm, respectively, and therefore, tailings and ore dressing plant site may be the major contamination sources in this study area. The mean content of Cu, Pb, Zn and Cd in stream sediments is extremely high up to 794 ppm, 1633 ppm, 2946 ppm and 25.2 ppm, respectively. Tailing particles and heavy metal ions are dispersed along the tributary system. Results from the sequential extraction analysis indicate; (1) most of Cu is bound to organic matters and sulphides, (2) fraction of Pb is mainly bound to Fe and Mn oxides. Most of Zn is largely bound to Fe and Mn oxides and residual fraction. Ion exchangeable fraction of Cd is relatively higher than those of Cu, Pb and Zn. Batch test on soils collected from the kaolinite and/or pyrophyllite mines and from the control areas was carried out to select an applicable soil samples for adsorption treatment The sample, S10, collected from the control area 2 (clay content 33.2%) shows the highest $K_d$ (distribution coefficient). Organic content in soils and several clay minerals shows relatively good correlation with $K_d$. It means that applicable soils for adsorption treatment of heavy metals show high organic and clay content.