• Bulletin of the Korean Chemical Society
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• v.15 no.7
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• pp.576-581
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• 1994

The secondary deuterium kinetic isotope effects (SDKIE) involving deuterated aniline nucleophiles are reported for the reactions of benzyl bromides and chlorides and benzoyl chlorides in acetonitrile. The benzyl systems behave normally as to the trend of changes in SDKIE with the magnitude of ${\rho}X({\rho}_{nuc})$, whereas benzoyl system shows ananomaly; ${\mid}{\rho}_X{\mid}$ decreases with increase in the extent of bond making estimated by the SDKIE. This has been ascribed to the negative charge accumulation at the reaction center carbon in the transition state. The magnitude of ${\rho}_{XY}$ is found to decrease by ca. 0.03 with ten degree rise in the reaction temperature.

• International Journal of High-Rise Buildings
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• v.10 no.3
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• pp.173-178
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• 2021

In this paper we introduce Shinagawa HEART, located in Shinagawa district, Tokyo. It is a mixed-use building with residences on the upper floors, offices on the lower floors, and commercial uses on the first and second floors, and is intended to meet the various needs of a building on the border between residential and commercial areas. The upper floors of the building are made of reinforced concrete, while the middle and lower floors are made of steel with CFT columns. First, an overview of the structural plan of the building is presented. Next, the adoption of the middle layer seismic isolation and the switch between the lower steel structure and the upper reinforced concrete structure, which are the features of this building, are explained. Finally, the construction method adopted to achieve the design performance is explained.

• Journal of Korean Association for Spatial Structures
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• v.19 no.2
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• pp.109-116
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• 2019

In this study, the seismic response is investigated by using a relatively low-rise building under torsion-prone conditions and three seismic loads with change of the location of the seismic isolation system. LRB (Lead Rubber Bearing) was used for the seismic isolator applied to the analytical model. Fixed model without seismic isolation system was set as a basic model and LB models using seismic isolation system were compared. The maximum story drift ratio and the maximum torsional angle were evaluated by using the position of the seismic layer as a variable. It was confirmed that the isolation device is effective for torsional control of planar irregular structures. Also, it was shown that the applicability of the mid-story seismic isolation system. Numerical analyses results presented that an isolator installed in the lower layer provided good control performance for the maximum story drift ratio and the maximum torsional angle simultaneously.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2006.04a
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• pp.500-507
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• 2006

Recently, the structural design code has been changed and every buildings, which have more than three floors or wider area than 1,000m2, should be designed to be able to resist earthquakes. However, most structural engineers are working in some big cities and this physical distance would set a barrier between structural engineers and architects. As a result, most row-rise buildings in small cities are designed and constructed without structural design or the consulting by structural engineers. The purpose of this research is to develop an web-based structural design environment in which structural design and consulting can be performed efficiently through on-line communication without off-line meetings or documents. In addition to the on-line communication, the system has a integrated structural design module which supports all the process of structural design and can increases the productivity of structural design work.

• SUVANNABHUMI
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• v.15 no.1
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• pp.61-89
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• 2023

This research explores the fall of pre-independence Sultanates and its continued political, economic, and cultural influence in post-colonial Indonesia. By using qualitative and historical methods, this paper compares the Sultanates of Mataram in Yogyakarta and Al-Kadrie in Pontianak, which represent different historical paths supporting the struggle for independence during the mid-20th century. Sultan Hamid II of the Al-Kadrie was a supporter of federalism whereas Sultan Hamengkubowono IX of Yogyakarta was an advocate of the republican system. Eventually, Indonesia became a Republic, and the idea of federalism was sidelined, which led to the abolition of sultanates in the rise of the = Indonesian nation-state, except for the Sultanate of Yogyakarta. After the 1998 Reform, the current development of democracy created political opportunities for the Al-Kadrie to reclaim its authority through engagement with various civic organizations. Meanwhile, the Sultanate of Yogyakarta faces internal friction because of succession concerns.

• International Journal of High-Rise Buildings
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• v.9 no.3
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• pp.221-233
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• 2020

Based on past experiences of natural disasters and fires in Japan, it is stipulated by law that fire-resistant buildings larger than a certain size should be unique in the world. Recent interest in global environmental issues has led to the active introduction of wooden buildings also in Japan, and it is expected that wooden buildings will become larger and higher in size. This paper introduces the background of the development of fire-resistant laminated timber with a "Self-Charring-Stop layer", the contents of this development including other related developments, and the application of these technologies. In addition, towards the realization of much larger and higher buildings in the future, the current problems and issues to be solved are set and the necessity of the future technological development is described. Finally, a conceptual model of wooden high-rise building is proposed, which will be able to be constructed in 2025 by the further technological development.

• Structural Engineering and Mechanics
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• v.42 no.5
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• pp.609-629
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• 2012

This study deals with the assessment of low and mid rise multi-story buildings made of stone and /or brick, composite steel and masonry slabs from the sixties, known to be vulnerable to seismic hazard using the "vulnerability index" method based on buildings survey following Ain Temouchent (1999) and Boumerdes (2003) earthquakes, from where vulnerability curves are constructed using the translation method. The results obtained for the case study confirm what has been observed in situ.

• Journal of the Korean Institute of Rural Architecture
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• v.24 no.2
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• pp.21-28
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• 2022

Focusing on the creation of a new han ok, especially a mid-rise hybrid-structured Han-ok, this study proposes a middle-rise (four-story) Han-ok on one and two lots located in Seoun-dong, the existing Han-ok intensive housing site in downtown Cheongju. 1) In terms of layout and function, according to the existing L-shaped Han-ok corresponding to the road and the direction, the parking lots and shops on the 1st floor, the business facility on the 2nd floor, the Han-ok on the 3rd and 4th floors are placed. There are yards, open roof yards, and semi-open Daecheong(大廳, main hall), which can be shared by residents. 2) In terms of structure and form, one or two floors (some 3 floors) are 5.4m square and 5.4×6.6m modules of the RC(Reinforced Concrete) group, and the upper floor reflects the 2.7m module, size and shape of the existing Han-ok. By extending the outer wall of the RC group in the lower floors (1st to 3rd floors) to the wooden exterior of the upper floors (2nd to 4th floors), it is attempted to avoid the awkward appearance of the RC group being exposed to wooden structures. And it is also attempted to reflect the wooden shape and design elements through the elevation elements such as horizontal windows, corner windows, picture frames, and vertical slits. 3) In environmental control and facilities, it is attempted to smooth the ventilation of the building by forming a vertical upward airflow from the dark space of the low floor to the positive of the upper floor. This doubles the effect through a vertical rise of cold air generated in a narrow alleyway, piloti parking lot, and the various voids. In addition to the Daecheong and Numaru(loft) of Han ok, the rooftop yard, the terrace, and the balcony, horizontal natural ventilation is generated through divided doors and transom windows.

• Ocean and Polar Research
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• v.40 no.1
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• pp.1-13
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• 2018

Previous studies have indicated a great regional difference in Sea Level Rise (SLR) in the Pacific and it has been suggested that this is linked to climate variability over the past two decades. In this study, we seek to identify the possible linkage between regional sea level and Pacific climate variability from altimetry-based sea level data (1993-2012) and further investigate how the Pacific sea level has changed spatially and temporally over the past 60 years from long-term sea level reconstruction data (1953-2008). Based on the same method as Zhang and Church (2012), the Inter-annual Climate Index (ICI) associated with the El $Ni{\tilde{n}}o-Southern$ Oscillation (ENSO) and the Decadal Climate Index (DCI) associated with Pacific Decadal Oscillation (PDO) are defined and then the multiple variable linear regression is used to analyze quantitatively the impact of inter-annual and decadal climate variability on the regional sea levels in the Pacific. During the altimeter period, the ICI that represents ENSO influence on inter-annual time scales strongly impacts in a striking east-west "see-saw mode" on sea levels across the tropical Pacific. On the other hand, the decadal sea level pattern that is linked to the DCI has a broad meridional structure that is roughly symmetric in the equator with its North Pacific expression being similar to the PDO, which largely contributes to a positive SLR trend in the western Pacific and a negative trend in the eastern Pacific over the two most recent decades. Using long-term sea level reconstruction data, we found that the Pacific sea levels have fluctuated in the past over inter-annual and decadal time scales and that strong regional differences are presented. Of particular interest is that the SLR reveals a decadal shift and presents an opposite trend before and after the mid-1980s; i.e., a declining (rising) trend in the western (eastern) Pacific before the mid-1980s, followed by a rising (declining) trend from the mid-1980s onward in the western (eastern) Pacific. This result indicates that the recent SLR patterns revealed from the altimeters have been persistent at least since the mid-1980s.

• Journal of the Korean earth science society
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• v.36 no.6
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• pp.520-532
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• 2015

In order to understand the Holocene sea level changes in the eastern Yellow Sea, the west coast of Korea, and to compare the rates of sea level rise in each period of time, the geological proxy records for pre-instrumental era and measurement data for the present day were combined and analysed. The sea level in the Yellow Sea rose fast with a rate of about 10 mm/yr during the early Holocene, and decelerated down to 1 mm/yr since the mid to late Holocene. The rising rates of sea level in the 20th century were slightly higher than those in the late Holocene. The present-day rates of sea level rise, known as the 'rapid' rise, are in fact much lower or similar, compared to the early to mid Holocene sea levels in the study area. Recent tide-gauge data show that sea level rise in the eastern Yellow Sea has been accelerating toward the 21st century. These rising trends coincide well with global rising patterns in sea level. Additionally, the present-day rising trends of sea level in this study are correlated with increased rates of carbon dioxide concentrations and sea surface temperatures, further indicating a signal to global warming associated with the human effect. Thus, the sea level changes induced by current global warming observed in the eastern Yellow Sea and world's oceans can be considered as 'Anthropocene' sea level changes. The changes in sea level are based on instrumental measurements such as tide-gauges and satellite altimetry, meaning the instrumental era. The Holocene changes in sea level can thus be reconstructed from geological proxy records, whereas the Anthropocene sea-level changes can be solely based on instrumental measurements.