• Journal of the Korean Society for Heat Treatment
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• v.9 no.1
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• pp.12-18
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• 1996

Austenite(${\gamma}$) grain size, ${\varepsilon}$ martensite volume fraction and damping capacity of Fe-17%Mn alloy have been investigated as a function of solution treatment temperature of $600^{\circ}C$ to $1100^{\circ}C$. With increasing the solution temperature, ${\gamma}$ grain size, ${\varepsilon}$ martensite content and damping capacity are increased, while the hardness is decreased. When ${\gamma}$ grains are small, ${\varepsilon}$ plates grow in only one direction in each ${\gamma}$ grain. However, if the ${\gamma}$ grains are large in accordance with high solution treating temperature, several ${\varepsilon}$ variants with different orientations are formed and intersected each other in each ${\gamma}$ grain. In spite of small ${\varepsilon}$ martensite content, the damping capacity of the specimen which was annealed at $700^{\circ}C$, followed by subzero treatment at $-196^{\circ}C$, is almost equal to that of the specimen annealed at $1000^{\circ}C$ and subsequently quenched to room temperature. From this result it is suggested that the damping capacity of Fe-17%Mn alloy having fine ${\gamma}$ grains is mainly attributed to the movement of ${\gamma}/{\varepsilon}$ interface without the operation of other damping sources such as ${\varepsilon}/{\varepsilon}$ boundaries and stacking faults in ${\varepsilon}$ reported previously.

• Journal of the Korean Society for Heat Treatment
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• v.23 no.4
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• pp.198-204
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• 2010

Modified 9Cr-1Mo steels possess excellent high-temperature mechanical properties and are widely used in energy conversion industries. However, in-service materials degradation, such as softening, carbide-induced embrittlement, temper embrittlement, etc., can take place during long-term operation. Evolution of microstructure due to service exposure to high temperature has a strong effect on the performance of heat resistant steels. In case of modified 9Cr-1Mo steels, precipitation of $Fe_2Mo$-type laves phases and coarsening of $M_{23}C_6$-type carbides are the primary cause of degradation of mechanical properties such as toughness, hardness, tensile strength and creep resistance. This study was aimed at finding reliable parameter for assessing the integrity of modified 9Cr-1Mo steels. Characteristic parameters were attained between mechanical and ultrasonic properties.

• Journal of the Korean Society for Heat Treatment
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• v.12 no.3
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• pp.221-230
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• 1999

The surface nitrogen permeation of Al alloyed 0.14%C-13%Cr stainless steels was investigated after heat treating at $1050^{\circ}C{\sim}1150^{\circ}C$ in the nitrogen gas atmosphere. The strong affinity between Al and nitrogen permeates the nitrogen through the interior of the steels. Two precipitates of round type and needle type are observed at the surface layer. These precipitates mainly consist of AlN containing plenty of aluminum. The surface layer of 0.53%Al alloyed specimen shows ferrite phase, while the surface layers of 1.65%Al and 2.27%Al alloyed specimens appear ${\gamma}$ plus ${\alpha}$ phases. The depth of nitrogen permeation depends upon the Al content and microstructure of the matrix. The 1.65%Al alloyed specimen representing ${\alpha}+{\gamma}$ matrix phases at the nitrogen permeation temperature shows the maximum case depth in this experiment. Although the surface hardness increases by raising the Al content of the specimen owing to the increase of nitride precipitation density, the nitride precipitation deteriorates the corrosion resistance in the solution of HCl, $H_2SO_4$, and $FeCl_3$.

• Journal of the Korean Society for Heat Treatment
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• v.17 no.1
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• pp.23-28
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• 2004

In this work, the effect of Sc and Mm(misch metal) on the high temperature behavior of Al-Mg alloys was observed. Hardness was increased due to appearance of fine $Al_3Sc$ precipitates. The elongation of Al-Mg-Sc alloy at high temperature was higher than that of Al-Mg-Sc-Mm alloy because Al-Mg-Sc alloy has finer grain sizes than Al-Mg-Sc-Mm alloy. The strain rate sensitivity factor, "m" of Al-Mg-Sc and Al-Mg-Sc-Mm at $475^{\circ}C$ and $1{\times}10^{-2}s^{-1}$ were 0.33 and 0.46, respectively. The activation energy of Al-Mg-Sc and Al-Mg-Sc-Mm alloy for superplastic deformation was 133KJ/mol and 103KJ/mol respectively. The elongation of Al-Mg-Sc alloy at high temperature was decreased by the addition of Mm, but the strength at high temperatures and low strain rate was improved.

• Journal of Korea Foundry Society
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• v.15 no.5
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• pp.469-476
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• 1995

The effects of Cr, Mo or B additions were investigated on $B2{\leftrightarrow}DO_3$ structural transition temperature $(T_C)$ and mechanical properties of Fe-28at.%Al. The raw materials were arc-melted in vacuum and then subjected to the following heat-treatments to maximize the $DO_3$ ordered structure : $1000^{\circ}C/7days$, slowly cooled to $500^{\circ}C$ and then held for 5 days. In the effect on the grain refinment, the addition of alloying element B was the most effective. The addition of Cr or Mo had little effect. When 1at.%Mo was added, $T_c$ increase about $30^{\circ}C$, but Cr had a very little effect on $T_c$. On the contrary, when B was added, $T_c$ was apt to come down minutely. In the additional effect of alloying element on the mechanical properties, Cr was apt to decrease the microvickers hardness and yield strength, Mo and B didn't have much effect. In the case of compressure strength test, the effect of the environment on the yield strength was contrary to the result of the tensile strength test.

• Korean Journal of Materials Research
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• v.23 no.11
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• pp.607-612
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• 2013

A powder in sheath rolling method was applied to the fabrication of a carbon nano tube (CNT) reinforced aluminum composite. A 6061 aluminum alloy tube with outer diameter of 31 mm and wall thickness of 2 mm was used as a sheath material. A mixture of pure aluminum powder and CNTs with a volume content of 5% was filled in the tube by tap filling and then processed to an 85% reduction using multi-pass rolling after heating for 0.5 h at $400^{\circ}C$. The specimen was then further processed at $400^{\circ}C$ by multi-pass hot rolling. The specimen was then annealed for 1 h at various temperatures that ranged from 100 to $500^{\circ}C$. The relative density of the 5vol%CNT/Al composite fabricated using powder in sheath rolling increased with increasing of the rolling reduction, becoming about 97% after hot rolling under 96 % total reduction. The relative density of the composite hardly changed regardless of the increasing of the annealing temperature. The average hardness also had only slight dependence on the annealing temperature. However, the tensile strength of the composite containing the 6061 aluminum sheath decreased and the fracture elongation increased with increasing of the annealing temperature. It is concluded that the powder in sheath rolling method is an effective process for fabrication of CNT reinforced Al matrix composites.

• Korean Journal of Materials Research
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• v.16 no.8
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• pp.516-523
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• 2006

In recent years, Magnesium (Mg) and its alloys have become a center of special interest in the automobile industry. Due to their high specific mechanical properties, they offer a significant weight saving potential in modern vehicle constructions. Most Mg alloys show very good machinability and processability, and even the most complicated die-casting parts can be easily produced. The die casting process is a fast production method capable of a high degree of automation for which certain Mg alloys are ideally suited. In this study, step-dies and flowability tests for AM50 were performed by die-casting process according to various combination of casting pressure and plunger velocity. We were discussed to velocity effect of forming conditions followed by results of microstructure, FESEM-EDX, hardness and tensile strength. Experimental results represented that the conditions of complete filling measured die-casting pressure 400 bar, 1st plunger velocity 1.0 m/s and 2nd plunger velocity 6.0 m/s. The increasing of 2nd plunger velocity 4.0 to 7.0 m/s decreased average grain size of $\alpha$ phase and pore. It was due to rapid filling of molten metal, increasing of cooling rate and pressure followed by increased 2nd plunger velocity. The pressure should maintain until complete solidification to make castings of good quality, however, the cracks were appeared at pressure 800bar over.

• Korean Journal of Materials Research
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• v.24 no.2
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• pp.111-115
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• 2014

Titanium and its alloys are useful for implant materials. In this study, porous Ti-Nb-Zr biomaterials were successfully synthesized by powder metallurgy using a $NH_4HCO_3$ as space holder and $TiH_2$ as foaming agent. Consolidation of powder was accomplished by spark plasma sintering process(SPS) at $850^{\circ}C$ under 30 MPa condition. The effect of high energy milling time on pore size and distribution in Ti-Nb-Zr alloys with space holder($NH_4HCO_3$) was investigated by optical microscope(OM), scanning electron microscope(SEM) & energy dispersive spectroscopy(EDS) and X-ray diffraction(XRD). Microstructure observation revealed that, a lot of pores were uniformly distributed in the Ti-Nb-Zr alloys as size of about $30-100{\mu}m$ using mixed powder and milled powders. In addition, the pore ratio was found to be about 5-20% by image analysis, using an image analyzer(Image Pro Plus). Furthermore, the physical properties of specimens were improved with increasing milling time as results of hardness, relative density, compressive strength and Young's modulus. Particularly Young's modulus of the sintered alloy using 4h milled powder reached 52 GPa which is similar to bone elastic modulus.

• Korean Journal of Materials Research
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• v.23 no.1
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• pp.18-23
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• 2013

In this study, the effects of cryogenic treatment cycles on the residual stress and mechanical properties of 7075 aluminum alloy (Al7075) samples, in the form of a tube-shaped product with a diameter of 500 nm, were investigated. Samples were first subjected to solution treatment at $470^{\circ}C$, followed by cryogenic treatment and aging treatment. The residual stress and mechanical properties of the samples were systematically characterized. Residual stress was measured with a cutting method using strain gauges attached on the surface of the samples; in addition, tensile strength and Vickers hardness tests were performed. The detailed microstructure of the samples was investigated by transmission electron microscopy. Results showed that samples with 85 % relief in residual stress and 8% increase in tensile strength were achieved after undergoing three cycles of cryogenic treatments; this is in contrast to the samples processed by conventional solution treatment and natural aging (T4). The major reasons for the smaller residual stress and relatively high tensile strength for the samples fabricated by cryogenic treatment are the formation of very small-sized precipitates and the relaxation of residual stress during the low temperature process in uphill quenching. In addition, samples subjected to three cycles of cryogenic treatment demonstrated much lower residual stress than, and similar tensile strength compared to, those samples subjected to one cycle of cryogenic treatment or artificial aging treatment.

• Journal of Welding and Joining
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• v.27 no.4
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• pp.73-78
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• 2009

Characterization of the microweld CCFL electrode for the TFT-LCD backlight unit was carried out in terms of the glass beading heat treatment conditions. We evaluate the weld zone and parent metal of the microweld CCFL electrodes that were exposed to simulated glass beading heat treatment. The CCFL electrode was composed of the cup made with pure Ni, the pin made with pure Mo and the lead wire made with Ni-Mn alloy. Each part of the electrode was assembled together by micro spot welding process and then the assembled electrodes were exposed to simulated glass beading temperatures of $700^{\circ}C,\;750^{\circ}C$ and $800^{\circ}C$. The microstructures of the microweld CCFL electrode were observed by using optical microscope, scanning electron microscope and EDS. Micro-tensile and microhardness test were also carried out. The results indicated that the grain coarsening in the HAZs(heat affected zones) for both the cup-pin weld and pin-lead wire were exhibited and the grain coarsening of the HAZ for the cup and the lead wire was more obvious than the HAZ of the pin. The micro-tensile test revealed that the fracture occurred at the cup-pin weld zone for all test conditions. The fracture surface could be classified into two parts such as pin portion and cup portion including weld nugget. The failure was seemed to be initiated from the boundary between nugget and pin through the weld joint. The result of the microhardness measurement exhibited that the relatively low hardness value, about 105HV was recorded at the HAZ of the cup. This value was about 50% less than that of the original value of the cup. The reduction of the microhardness was considered as the cause of the grain coarsening due to welding process. It was also appeared that there was no change in electric resistance for the standard electrodes and heat treated electrodes.