• Title/Summary/Keyword: microscopic behavior

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Numerical Study on Hydrogen Absorption and Expansion Behavior on Palladium (팔라듐에 관한 수소저장과 팽창거동에 관한 수치해석)

  • Kim, S.W.;Hwang, C.M.;Jang, T.I.;Jung, Y.G.
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.3
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    • pp.256-264
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    • 2007
  • In order to calculate the relation between the hydrogen and the hydrogen absorption metals in the atomic level, Embedded Atom Method(EAM) is recommended. In this study, we had constructed the EAM programs from constitutive formulas and parameters of the hydrogen and palladium for the purpose of predicting the expansion behavior on hydrogen absorbing in the geometric shape of hydrogen absorption metals, as palladium bars and plates. And the EAM analyses data were compared with the experiment data by using electrochemical method. As results, it is note that the expansion rate in thickness of the palladium plate model by EAM analyses is about 4 times larger than width and length, be similar to experiment results. Also, in the microscopic and macroscopic level the expansion behavior through EAM analyses show good agreement with experiment data.

Spinodal Phase Separation and Isothermal Crystallization Behavior in Blends of VDF/TrFE(75/25) Copolymer and Poly(1,4-butylene adipate) (I) -Spinodal Phase Separation Behavior-

  • Kim, Kap Jin;Kyu, Thein
    • Fibers and Polymers
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    • v.4 no.4
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    • pp.188-194
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    • 2003
  • Phase behavior and spinodal phase separation kinetics in binary blends of a random copolymer of vinylidene fluoride and trifluoroethylene (75/25) [P(VDF/TrFE)] and poly(l,4-butylene adipate) (PBA) have been investigated by means of optical microscopic observation and time-resolved light scattering. The blends exhibited a typical lower critical solution temperature (LCST)∼${34}^{\circ}C$ above the melting temperature of the P(VDF/TrFE) crystals over the entire blend composition range. P(VDF/TrFE) and PBA were totally miscible in the temperature gap between the melting point of P(VDF/TrFE) and the LCST. Temperature jump experiments of the 3/7 P(VDF/TrFE)/PBA blend were carried out on a light-scattering apparatus from a single-phase melt state (${180}^{\circ}C$) to a two-phase region (205∼${215}^{\circ}C$). Since the late stage of spinodal decomposition (SD) is prevalent in the 3/7 blend, SD was analyzed using a power law scheme. Self-similarity was preserved well in the late stage of SD in the 3/7 blend.

A Study on Spray Behavior of DME-LPG Blended Fuels in a Common-rail Injection System (커먼레일 분사 시스템에서 DME-LPG 혼합연료의 분무거동에 관한 연구)

  • Kim, W.I.;Woo, S.C.;Lee, C.S.;Lee, K.H.
    • Journal of ILASS-Korea
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    • v.20 no.1
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    • pp.35-42
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    • 2015
  • This study is to investigate the spray behavior of DME-LPG blended fuels in common rail injection system for diesel engines. The visualization experiment was performed to analyze the macroscopic spray behavior of test fuels. In addition, the experiment using BOS(Background Oriented Schlieren) method is performed to compare liquid phase and gas phase. The test fuels are injected in high pressure chamber. The ambient pressure of high pressure chamber was formed by nitrogen gas. Spray tip penetration, spray cone angle and spray area were measured using high speed camera. SMD(Sauter Mean Diameter) and spray particle velocity were measured using the PDPA(Phase Doppler Particle Analyzer) system to analyze the microscopic properties of test fuels. The results of this experiment showed that spray tip penetration, spray cone angle and spray area of DME-LPG fuels are similar to those of DME fuel. When compared to results of experiment using BOS, significant differences of spray tip penetrations, spray cone angle and spray area are showed because of gas phase. The results of experiment using BOS method showed higher values. SMD of DME-LPG blended fuels is smaller than that of DME fuel. Velocity of DME-LPG blended fuels is faster than that of DME fuel.

Evaluation methods for Void Closing Behavior in Large Ingot (기공닫힘부 폐쇄정도 결정을 위한 평가방법 연구)

  • Choi, I.J.;Choi, H.J.;Yoon, D.J.;Lee, G.A.;Lim, S.J.
    • Transactions of Materials Processing
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    • v.20 no.5
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    • pp.339-343
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    • 2011
  • This paper presents methods for analyzing the extent of cylindrical-shaped void closure. In addition, a quantitative relationship between change in void fraction and height reduction ratio of a compressed specimen is proposed. The height reduction ratio, number of deformation steps and billet rotation were chosen as key process parameters influencing the void closing behavior, namely, the changes in void shape and size during hot open die forging of a large ingot. The extent of void closure was analyzed from microscopic observations and estimated from tensile test results. The tensile strengths of specimens with closed voids and those without were compared for various reduction ratios in height. The results confirmed that void closure occurs at reduction ratios greater than 30 %. The void closing behavior could be expressed as a hyperbolic tangent function of reduction ratio in height, number of paths, and billet rotation. The knowledge presented in this paper could be helpful for optimizing deformation paths in open die forging processes.

Influence of pre-compression on crack propagation in steel fiber reinforced concrete

  • Abubakar, Abdulhameed U.;Akcaoglu, Tulin
    • Advances in concrete construction
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    • v.11 no.3
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    • pp.261-270
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    • 2021
  • In this study, a new understanding is presented on the microcracking behavior of high strength concrete (HSC) with steel fiber addition having prior compressive loading history. Microcracking behavior at critical stress (σcr) region, using seven fiber addition volume of 0.5, 0.75, 1.0, 1.25, 1.5, 1.75, and 2.0% was evaluated, at two aspect ratios (60 and 75). The specimens were loaded up to a specified compressive stress levels (0.70fc-0.96fc), and subsequently subjected to split tensile tests. This was followed by microscopic analyses afterwards. Four compressive stress levels as percentage of fc were selected according to the linearity end point based on stress-time (σ-t) diagram under uniaxial compression. It was seen that pre-compression has an effect on the linearity end point as well as fiber addition where it lies within 85-91% of fc. Tensile strength gain was observed in some cases with respect to the 'maiden' tensile strength as oppose to tensile strength loss due to the fiber addition with teething effect. Aggregate cracking was the dominant failure mode instead of bond cracks due to improved matrix quality. The presence of the steel fiber improved the extensive failure pattern of cracks where it changes from 'macrocracks' to a branched network of microcracks especially at higher fiber dosages. The applied pre-compression resulted in hardening effect, but the cracking process is similar to that in concrete without fiber addition.

Effect of pH and Concentration on Electrochemical Corrosion Behavior of Aluminum Al-7075 T6 Alloy in NaCl Aqueous Environment

  • Raza, Syed Abbas;Karim, Muhammad Ramzan Abdul;Shehbaz, Tauheed;Taimoor, Aqeel Ahmad;Ali, Rashid;Khan, Muhammad Imran
    • Journal of Electrochemical Science and Technology
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    • v.13 no.2
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    • pp.213-226
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    • 2022
  • In the present study, the corrosion behavior of aluminum Al-7075 tempered (T-6 condition) alloy was evaluated by immersion testing and electrochemical testing in 1.75% and 3.5% NaCl environment at acidic, neutral and basic pH. The data obtained by both immersion tests and electrochemical corrosion tests (potentiodynamic polarization and electrochemical impedance spectroscopy tests) present that the corrosion rate of the alloy specimens is minimum for the pH=7 condition of the solution due to the formation of dense and well adherent thin protective oxide layer. Whereas the solutions with acidic and alkaline pH cause shift in the corrosion behavior of aluminum alloy to more active domains aggravated by the constant flux of acidic and alkaline ions (Cl- and OH-) in the media which anodically dissolve the Al matrix in comparison to precipitated intermetallic phases (cathodic in nature) formed due to T6 treatment. Consequently, the pitting behavior of the alloy, as observed by cyclic polarization tests, shifts to more active regions when pH of the solutions changes from neutral to alkaline environment due to localized dissolution of the matrix in alkaline environment that ingress by diffusion through the pores in the oxide film. Microscopic analysis also strengthens the results obtained by immersion corrosion testing and electrochemical corrosion testing as the study examines the corrosion behavior of this alloy under a systematic evaluation in marine environment.

The Effect of Initial α' on Low and High Cycle Fatigue Behavior of STS 304 Stainless Steel (STS 304 강의 저주기 및 고주기 피로에 있어 초기 마르텐사이트의 영향)

  • Lee, Hyun-Seung;Sin, Hyung-Ju;Kim, Song-Hee
    • Journal of Industrial Technology
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    • v.21 no.B
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    • pp.331-339
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    • 2001
  • Zero to tension fatigue tests and strain controlled fatigue tests were carried out to find how initial strain induced martensite, ${\alpha}^{\prime}$ affects low and high cycle fatigue behavior and fatigue crack growth mechanisms. Microscopic study and phase analysis were carried out with TEM, SEM, EDAX, Optical Microscope, Ferriscope, and X-ray diffractometry. The amount of Initial ${\alpha}^{\prime}$ was controlled from 0% to 33% by controlling the temperatures for cold working and heat treatment. Lower contents of initial ${\alpha}^{\prime}$ showed higher fatigue resistance in low cycle fatigue but lower fatigue resistance in high cycle fatigue because it is ascribed to the more transformation of ${\alpha}^{\prime}$ martensite during low cycle fatigue and higher ductility. In high cycle fatigue, fatigue life is attributed to the strength and phase transformation of austenite into ${\alpha}^{\prime}$ during fatigue was negligible. ${\gamma}$ boundary, ${\gamma}/twin$ boundary, and ${\gamma}/{\alpha}^{\prime}$ boundary were found to be the preferred site of fatigue crack initiation.

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Nondestructive Evaluation on Strength Characteristic and Damage Behavior of Al 7075/CFRP Sandwich Composite (Al 7075/CFRP 샌드위치 복합재료의 강도 및 손상특성에 대한 비파괴 평가)

  • Lee, Jin-Kyung;Yoon, Han-Ki;Lee, Joon-Hyun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.11
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    • pp.2328-2335
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    • 2002
  • A hybrid composite material has many potential usage due to the high specific strength and the resistance to fatigue, when compared to other composite materials such as fiber reinforced plastic(FRP) and metal matrix composite(MMC). However, the fracture mechanism of hybrid composite material is extremely complicated because of the bonding structure of metals and FRP. In this study, Al 7075 sheets and carbon epoxy preprags were used to fabricate the hybrid composite. Recently, nondestructive technique has been used to evaluate the fracture mechanism of these composite materials. AE technique was used to clarify the microscopic damage behavior and failure mechanism of A17075/CFRP hybrid composite. It was found that AE paralneters such as AE event, energy and amplitude were effective to evaluate the failure process of Al 7075/CFRP composite. In addition, the relationship between the AE signal and the characteristics of fracture surface using optical microscope was discussed.

EFFECTS OF A SPLIT INJECTION ON SPRAY CHARACTERISTICS FOR A COMMON-RAIL TYPE DIESEL INJECTION SYSTEM

  • PARK S. W.;SUH H. K.;LEE C. S.
    • International Journal of Automotive Technology
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    • v.6 no.4
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    • pp.315-322
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    • 2005
  • This work was performed to investigate the effect of a split injection on spray characteristics of fuel sprays injected from a common rail system. In order to analyze the spray behavior and atomization characteristics at various rates of split injections, the injection durations of pilot and main injections were varied in experiments. The injection rate of split injection was measured to study the effect of the pilot injection on the main injection. By using a Nd:YAG laser and an ICCD camera, the development of the injected spray was visualized at various elapsed time from the start of injection. The microscopic characteristics such as SMD and axial velocity were analyzed by using a phase Doppler particle analyzer system. The results indicate that the ambient gas flow generated by the pilot injection affects the behavior of main spray, whereas the effect of pressure variation on the main spray is little. The spray tip penetration of a main spray with pilot injection is longer than that of the single injection by the effect of ambient gas flow. Also the main spray produces larger droplets than the pilot spray due to a small relative velocity between the droplets and ambient gas.

Frictional Instabilities of Polymer Composite Containing Barite or Potassium Titanate for Brake Linings

  • Kim, Seong-Jin;Jang, Ho
    • KSTLE International Journal
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    • v.4 no.2
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    • pp.60-65
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    • 2003
  • Tribological properties of novolac resin composites containing particulate barite (BaSO$_4$) or potassium titanate (K$_2$Oㆍ6(TiO$_2$))whiskers (two typical space fillers for commercial automotive brake linings) were investigated. The emphasis of the current investigation was given to the effect of the two fillers on the propensity of the stick-slip phenomena and formation of stable rubbing surface. A block-on-disk type tribometer was used for friction assessment. Results showed that the BaSO$_4$-filled composite produced large friction force oscillations at slow sliding speeds and created severe damage on the gray iron counter surface. On the other hand, the composite with $K_2$Oㆍ6(TiO$_2$) whiskers formed a stable rubbing surface and showed smooth sliding behavior without large friction force fluctuation. The microscopic observation of the rubbing surface revealed that the $K_2$Oㆍ6(TiO$_2$)whiskers played a key role in the formation of stable rubbing surface and smooth sliding behavior by effectively reinforcing the resin.