• Title/Summary/Keyword: microscopic behavior

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Spectroscopic Study on Three States of Water in the Reverse Micelle Using Methylene Blue as a Probe (Methylene Blue를 이용한 역미셀에서 물의 세 가지 상태에 대한 분광학적 연구)

  • Bum Young Park;Kab Sang Jung;Soo-Chang Yu;Ho Seob Choi
    • Journal of the Korean Chemical Society
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    • v.47 no.4
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    • pp.309-314
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    • 2003
  • In order to find out the microscopic environmental information on the nonionic reverse micelle of Triton X-100/n-hexanol/water in cyclohexane, an absorption and fluorescence spectroscopic study has been conducted using a methylene blue(MB). The information on the microscopic states of water in the polar core of the reverse micelle has been found by investigating complex formation and solvatochromic behavior between MB and Triton X-100. As a result, it was found that there exist three states in the polar core of the reverse micelle. The measured values of $W(=[H_2O]/[Surf])$ for the three states of water are 0.71, 4.98, and 7.26, and the corresponding lifetimes of MB are $15.45 ns{\pm}0.56$, $12.27 ns{\pm}0.79$, and $8.28 ns{\pm}0.82$, respectively.

Feasibility Analysis of Traffic Policy Alternatives for the Depreciation Effect Analysis of Automotive Exhaust Gas using Microscopic Simulation (미시적 시뮬레이션을 이용한 교통정책 대안별 자동차 배출가스 저감 효과 분석)

  • Seo, Im-Gi;Wang, Wi-Geol;NamGung, Mun;Lee, Byeong-Ju
    • Journal of Korean Society of Transportation
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    • v.25 no.6
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    • pp.89-97
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    • 2007
  • The car-dependent traffic system based on highly advanced industrialization and economic growth causes various urban problems including traffic jams, energy consumption, air pollution, noise, car accidents and other issues. Particularly in urban areas, air pollution from motor vehicles is worse than pollution from past industrialization. In this study, therefore, the authors grasped car exhaust reduction effects by using microsimulation and those traffic policies that could make cars flow smoothly, reducing the air pollution in urban areas through analysis on profitability. As a result, the weekday-based car using system has been found most effective as it does not need investment cost. However, this system may be socially unacceptable, as it requires the government to change driver behavior. Therefore, the government needs to first reach a consensus with the citizens regarding this system. This system will also be effective with other alternatives. As a follow-up study, the authors will research citizens' perceived impacts of car exhaust on air pollution through a study on preference and grasp the possibility of applying these study results to real traffic policies.

A Review of Emissions Studies for Transportation Engineering (교통환경분야의 국내외 연구동향 및 시사점 (차량배출량 관련 연구를 중심으로))

  • Gang, Jong-Ho;Lee, Cheong-Won
    • Journal of Korean Society of Transportation
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    • v.25 no.6
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    • pp.7-18
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    • 2007
  • There are few studies on air pollution due to vehicle emissions in spite of the importance of this field. Therefore, this study describes trends and suggests implications through analysis relating to existing emissions research. This study has been divided into three areas. The first part is about estimating vehicle emissions. In this part, the authors analyze limits in ways of calculating emissions in the existing macroscopic view and then suggest the development of a model for calculating emissions considering velocity and acceleration. These variables are a function of traffic and individual driving behavior in the microscopic view. The second part is about management techniques for reducing vehicle emissions. The traffic management techniques for reducing vehicle emissions should conform to regional characteristics. The final part is about traffic operation for reducing vehicle emissions. The authors suggest the development of a micro-simulator and then the development of strategies for traffic operation. It is necessary to design better models estimating emissions and then, using real time data, to make a monitoring system simulating emission rates. This study serves as a literature review to make a foundation for further research about emissions research for transportation engineering.

Plasticity Model for Directionality of Concrete Crack Damages (콘크리트 균열 손상의 방향성을 고려한 다중파괴기준 소성 모델)

  • Kim, Jae-Yo;Park, Hong-Gun
    • Journal of the Korea Concrete Institute
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    • v.19 no.5
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    • pp.655-664
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    • 2007
  • The inherent characteristic of concrete tensile cracks, directional nonlocal crack damage, causes so-called rotating tensile crack damage and softening of compressive strength. In the present study, a plasticity model was developed to describe the behavior of reinforced concrete planar members In tension-compression. To describe the effect of directional nonlocal crack damage, the concept of microplane model was combined with the plasticity model. Unlike existing models, in the proposed model, softening of compressive strength as well as the tensile crack damage were defined by the directional nonlocal crack damage. Once a tensile cracking occurs, the microplanes of concrete are affected by the nonlocal crack damage. In the microplanes, microscopic tension and compression failure surfaces are calculated. By integrating the microscopic failure surfaces, the macroscopic failure surface is calculated. The proposed model was implemented to finite element analysis, and it was verified by comparisons with the results of existing shear panel tests.

Investigating the Morphology and Kinetics of Three-Dimensional Neuronal Networks on Electro-Spun Microstructured Scaffolds

  • Kim, Dongyoon;Kim, Seong-Min;Kang, Donghee;Baek, Goeun;Yoon, Myung-Han
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.277.2-277.2
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    • 2013
  • Petri dishes and glass slides have been widely used as general substrates for in vitro mammalian cell cultures due to their culture viability, optical transparency, experimental convenience, and relatively low cost. Despite the aforementioned benefit, however, the flat two-dimensional substrates exhibit limited capability in terms of realistically mimicking cellular polarization, intercellular interaction, and differentiation in the non-physiological culture environment. Here, we report a protocol of culturing embryonic rat hippocampal neurons on the electro-spun polymeric network and the results from examination of neuronal cell behavior and network formation on this culture platform. A combinatorial method of laser-scanning confocal fluorescence microscopy and live-cell imaging technique was employed to track axonal outgrowth and synaptic connectivity of the neuronal cells deposited on this model culture environment. The present microfiber-based scaffold supports the prolonged viability of three-dimensionally-formed neuronal networks and their microscopic geometric parameters (i.e., microfiber diameter) strongly influence the axonal outgrowth and synaptic connection pattern. These results implies that electro-spun fiber scaffolds with fine control over surface chemistry and nano/microscopic geometry may be used as an economic and general platform for three-dimensional mammalian culture systems, particularly, neuronal lineage and other network forming cell lines.

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Direct Numerical Simulation of Composite laminates Under low velocity Impact (저속충격을 받는 적층복합재료 평판의 직접 수치모사)

  • Ji, Kuk-Hyun;Kim, Seung-Jo
    • Composites Research
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    • v.19 no.1
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    • pp.1-8
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    • 2006
  • Prediction of damage caused by low-velocity impact in laminated composite plate is an important problem faced by designers using composites. Not only the inplane stresses but also the interlaminar normal and shear stresses playa role in estimating the damage caused. But it is well known that the conventional approach based on the homogenization has the limit in description of damage. The work reported here is an effort in getting better predictions of dynamic behavior and damage in composite plate using DNS approach. In the DNS model, we discretize the composite plates through separate modeling of fiber and matrix for the local microscopic analysis. In the view of microscopic mechanics with DNS model, interlaminar stress behaviors in the inside of composite materials are investigated and compared with the results of the homogenized model which has been used in the conventional approach to impact analysis. Also the multiscale model based on DNS concept is developed in order to enhance the effectiveness of impact analysis, and we present the results of multiscale analysis considering micro and macro structures simultaneously.

Evaluation of Microscopic Deformation Behaviors of Metal Matrix Composite due to Heat Treatment by means of SFC Test and Acoustic Emission (음향방출과 SFC 시험법에 의한 금속복합재료의 기지재 열처리 효과에 따른 미시적 변형기구 특성 평가)

  • Kang, Moon-Phil;Lee, Joon-Hyun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.20 no.5
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    • pp.381-389
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    • 2000
  • Metal matrix composite(MMCs) have been rapidly becoming one of the strongest candidates for structural materials for high temperature application. It is well recognized that MMCs always experience at least one large cool-down from processing temperature before my significant applied service loading. Due to the large difference in thermal expansion coefficient between the fiber and matrix, large thermal residual stresses generally develop in composites. It was reported from many previous studies that the effects of thermal residual stress on mechanical properties and fracture behavior were much more complex and dramatic than conventional engineering materials. Therefore it is crucial to evaluate the effect of heat treatment which changes the characteristic of distribution of thermal residual stress in MMCs. Single fiber composite(SFC) test based on the balance in a micromechanical model is a quite convenient method to evaluate interfacial shear strength(IFSS) and the failure mode of composite. In this study the effect of heat treatment on IFSS and the microscopic failure mechanism of MMC is investigated by combining acoustic emission(AE) technique with SFC test. The characteristic of AE signal, IFSS and microscopic failure mechanism due to heat treatment condition is discussed.

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EFFECTS OF ALLOYING ELEMENTS ON VARIOUS PROPERTIES OF DENTAL SILVER-PALLADIUM ALLOYS (치과용(齒科用) 은(銀)-파라디움합금(合金)의 합금원소(合金元素)가 제성질(諸性質)에 미치는 영향(影響)에 관(關)한 연구(硏究))

  • Kim, Chun-Jin;Park, Nam-Soo
    • The Journal of Korean Academy of Prosthodontics
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    • v.22 no.1
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    • pp.95-108
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    • 1984
  • Even though the tarnishing and corrosion problems characteristic with dental silver-palladium alloy are not yet fully solved, it is recently widely used because of its low cost. However the effects of major alloying elements on the various properties of this system are not fully understood. The object of this research is to clarify the effects of In and Zn additives on the corrosion and tarnishing resistances and precipitation hardening behavior of this sytem, using electrodynamic polarization, immersion, and Vicker's microhardness test and X-ray diffraction and electron probe micro analysis methods. The obtained results were as follows: I. As indium content is increased, both the corrosion resistance in Cl-solution and microhardness are also increased while the tarnishing resistance is decreased. 2. As Zinc content is increased, the corrosion resistance is decreased, but tarnishing resistance is increased 3. At 70Ag-25Pd-2.5Zn-2.5In composition, the precipitation harding behavior was mot significant. The optimum aging temperature was $450^{\circ}C$ and the time was 2 hrs. The resulting specimen of this work carried 180VHN. 4. Under the heat treatment, the changes in the mechanical property are due to the changes in the shape and composition of dendrite matrix, namely, it is because of the precipitation hardening behavior which has been proved by electron probe micro analysis and optical microscopic finding.

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Behavior of the insecticide imidacloprid in crucian carp (Carassius auratus L.) and its toxic effects on organs (살충제 imidacloprid의 붕어(Carassius auratus L.)중 행적 및 장기에 대한 독성)

  • Ihm, Yang-Bin;Kim, Chan-Sub;Lee, Hee-Dong;Kim, Dae-Kyu;Kyung, Kee-Sung
    • The Korean Journal of Pesticide Science
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    • v.10 no.4
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    • pp.289-295
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    • 2006
  • In order to elucidate the behavior of the insecticide imidacloprid (1-(6-chloro-3-pyridylmethyl)-N-nitroimidazolidin-2-ylideneamine) in crucian carp (Carassius auratus L.) and its effects on the internal organs of crucian carp, the crucian carps were exposed to [$^{14}C$]imidacloprid at a predicted environmental concentration of 0.064 mg/L for 4 days. Imidacloprid in water was absorbed into crucian carps to reach the maximum concentration at 2 days after exposure. Unknown major metabolite and imidacloprid urea, minor metabolite, were detected in test water. The amounts of the [$^{14}C$]imidacloprid and its metabolites absorbed in gall were much higher than those in the other parts, strongly suggesting that biliary excretion involving enterohepatic recirculation could be an import route for the elimination of imidacloprid absorbed in crucian carps. Meanwhile, no toxic effects of imidacloprid on liver and kidney as well as the genital organs such as testis and ovary were observed by microscopic inspection.

AE Characteristics on the Damage Behavior of TiNi/A16061 Shape Memory Alloy Composites at High Temperature (TiNi/A16061 형상기억복합재료의 고온에서의 손상거동에 대한 AE 특성)

  • Lee, Jin-Kyung;Park, Young-Chul;Ku, Hoo-Taek
    • Journal of the Korean Society for Nondestructive Testing
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    • v.22 no.1
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    • pp.45-52
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    • 2002
  • It has been known that tensile residual stresses occurring by the thermal expansion coefficient mismatch between fiber and matrix is a cause of the weak strength of metal matrix composites(MMCs). In order to solve this problem, TiNi alloy fiber was used as a reinforced material in TiNi/A16001 shape memory alloy composite in this study. TiNi alloy fiber improves the tensile strength of the composite by causing compressive residual stress in matrix on the basis of its shape memory effect. Pre-strain was imposed to generate the compressive residual stresses inside the TiNi/A16001 shape memory alloy composites. AE technique was used to quantify the microscopic damage behavior of the composite at high temperature. The effect of applied pre-strains on the AE behavior was also evaluated.